以Ga-In-Sn三元合金为研究对象,研制了可用于现场及在线标定的微型Ga-In-Sn共晶点容器,开展了3种不同配比对相变温度和温坪复现影响的研究。结果表明:3种配比的共晶点温坪可持续1. 2~2 h,实验的复现性优于4. 5 m K,合成扩展不确定度为9...以Ga-In-Sn三元合金为研究对象,研制了可用于现场及在线标定的微型Ga-In-Sn共晶点容器,开展了3种不同配比对相变温度和温坪复现影响的研究。结果表明:3种配比的共晶点温坪可持续1. 2~2 h,实验的复现性优于4. 5 m K,合成扩展不确定度为9. 3 m K(k=2),3种配比的共晶点相变温度平均值为10. 748℃;在相同热工况下Ga-In-Sn合金发生共晶反应的相变温度不受配比的影响;改变合金熔体的降温速率可改变微型共晶点过冷度。展开更多
A precise and noninvasive method for the size and shape measurement of gold nanorods(GNRs) has been proposed based on depolarized dynamic light scattering(DDLS). A home-made DDLS apparatus has been established. By app...A precise and noninvasive method for the size and shape measurement of gold nanorods(GNRs) has been proposed based on depolarized dynamic light scattering(DDLS). A home-made DDLS apparatus has been established. By applying depolarized optical path with precise alignment method, the signal-to-noise ratio(SNR) of this apparatus is highly improved. GNRs with three different diameter and length has been precisely measured by using DDLS method as well as scanning electron microscopy(SEM). The thickness of adsorption layer of cetyltrimethylammonium bromide(CTAB) in solution has been taken into consideration. Results show that size measurement of GNRs by using DDLS method agrees very well with that by using SEM. In addition, it is shown that the extinction spectroscopy strongly limited the application of DDLS method by affecting the effective scattering light intensity. Proper laser wavelength should be chosen before the application of this method.展开更多
文摘以Ga-In-Sn三元合金为研究对象,研制了可用于现场及在线标定的微型Ga-In-Sn共晶点容器,开展了3种不同配比对相变温度和温坪复现影响的研究。结果表明:3种配比的共晶点温坪可持续1. 2~2 h,实验的复现性优于4. 5 m K,合成扩展不确定度为9. 3 m K(k=2),3种配比的共晶点相变温度平均值为10. 748℃;在相同热工况下Ga-In-Sn合金发生共晶反应的相变温度不受配比的影响;改变合金熔体的降温速率可改变微型共晶点过冷度。
基金This work has been supported by the National Natural Science Foundation of China(No.51805505)the Key R&D Projects of Science and Technology(No.2016YFA0200901)the Basic Science Research Operating Fund of NIM(No.AKY 1817)。
文摘A precise and noninvasive method for the size and shape measurement of gold nanorods(GNRs) has been proposed based on depolarized dynamic light scattering(DDLS). A home-made DDLS apparatus has been established. By applying depolarized optical path with precise alignment method, the signal-to-noise ratio(SNR) of this apparatus is highly improved. GNRs with three different diameter and length has been precisely measured by using DDLS method as well as scanning electron microscopy(SEM). The thickness of adsorption layer of cetyltrimethylammonium bromide(CTAB) in solution has been taken into consideration. Results show that size measurement of GNRs by using DDLS method agrees very well with that by using SEM. In addition, it is shown that the extinction spectroscopy strongly limited the application of DDLS method by affecting the effective scattering light intensity. Proper laser wavelength should be chosen before the application of this method.