Compounds with visible-light-induced photoluminescence are particularly attractive in acting as the emitting components of light-emitting diodes and fluorescent probes for biological applications. A new complex [Zn(NC...Compounds with visible-light-induced photoluminescence are particularly attractive in acting as the emitting components of light-emitting diodes and fluorescent probes for biological applications. A new complex [Zn(NCS)_3(MQ)](MQ^+ = N-methyl-4,4?-bipyridinium) with an isolated molecular structure has been hydrothermally synthesized and characterized by single-crystal X-ray diffraction, elemental analysis, IR spectroscopy and solid-state photoluminescent determination. Crystal data: C_(14)H_(11)N_5S_3Zn, M_r = 410.83, monoclinic, space group P2_1/c, a = 8.809(5), b = 13.138(7), c = 15.580(9) ?, b = 104.433(10)°, V = 1746.2(17) ?~3, Z = 4, D–c = 1.563 g×cm^3, μ = 1.769 mm^(–1), F(000) = 832, the final R = 0.0376 and wR = 0.1243 for 2850 observed reflections with I > 2s(I). In the crystal structure, the zinc atom is tetrahedrally coordinated by one MQ+ ligand and three NCS– groups to yield a tetrahedral configuration. The bond length of Zn–NMQ is clearly shorter than those found in reported Zn(Ⅱ) complexes of 4,4?-bipy. The isolated units are joined by C–H···S interactions to generate a 2D hydrogen-bonding network. This compound displays visible light-induced photoluminescence, which originates from both intraligand charge-transfer of the MQ+ ligand and NCS~–→MQ^+ charge-transfer according to a density of states(DOS) calculation. Moreover, its emission band shows a clear blue shift compared with those of halide compounds.展开更多
A new cyano-bridged Gadolinium^(Ⅲ)-Iron^(Ⅲ)complex{[Gd(DMF)_(3)(DMSO)(H_(2)O)_(3)]2H_(2)0(DMF=N,N·-dimethylformamide;DMSO=dimethylsulfoxidel}was synthesized by the grinding reaction method,.It crysta-]llizes in...A new cyano-bridged Gadolinium^(Ⅲ)-Iron^(Ⅲ)complex{[Gd(DMF)_(3)(DMSO)(H_(2)O)_(3)]2H_(2)0(DMF=N,N·-dimethylformamide;DMSO=dimethylsulfoxidel}was synthesized by the grinding reaction method,.It crysta-]llizes in the triclinic.,space group P1 with ceIl parameters:a=O.90363(2)nm,b=1.25078(3)nm,c=1.41303(1)nm,穋m^(-3),Z=2,Mr=756.72,F(000)=760,Ⅲ)and the approxi-mately oriented octahedrally sixfold-coordinated Fe(Ⅲ)are linked by a cyano-bridge group to construct a dinuclear compound.The{[Gd(DMF)_(3)(DMSO)(H_(2)O)_(3)](Ⅲ)-Fe(Ⅲ)interaction is antiferromagnetic.CCDC:223430.展开更多
A novel metalloviologen complex{[Cd(PhSQ)(HTBC)(H_(2)O)_(2)]·1.25 H_(2)O}n(1)based on N-(4-sulfophenyl)-4,4’-bipyridinium(PhSQ)and monoprotonated trimesic acid(HTBC)has been prepared and structurally characteriz...A novel metalloviologen complex{[Cd(PhSQ)(HTBC)(H_(2)O)_(2)]·1.25 H_(2)O}n(1)based on N-(4-sulfophenyl)-4,4’-bipyridinium(PhSQ)and monoprotonated trimesic acid(HTBC)has been prepared and structurally characterized.Complex 1 has been characterized by elemental analysis,IR,thermogravimetric analyses,UV-Vis spectra and X-ray crystallography.The coordination geometry of Cd(Ⅱ)ion is a pentagonal bipyramid.Complex 1 displays a zigzag chain along the b axis,and such chains are extended into a 2 D layer supramolecular network through hydrogen bonding and π…π interactions.Moreover,complex 1 exhibits reversible photochromic and switchable luminescent behaviors via UV light irradiation at room temperature induced by the photogenerated radicals via a photo-induced electron transfer(PET)mechanism.展开更多
基金supported by the National Natural Science Foundation of China(21221001,and 21471149)Key Research Program of Frontier Science,CAS(QYZDJ-SSW-SLH028)
文摘Compounds with visible-light-induced photoluminescence are particularly attractive in acting as the emitting components of light-emitting diodes and fluorescent probes for biological applications. A new complex [Zn(NCS)_3(MQ)](MQ^+ = N-methyl-4,4?-bipyridinium) with an isolated molecular structure has been hydrothermally synthesized and characterized by single-crystal X-ray diffraction, elemental analysis, IR spectroscopy and solid-state photoluminescent determination. Crystal data: C_(14)H_(11)N_5S_3Zn, M_r = 410.83, monoclinic, space group P2_1/c, a = 8.809(5), b = 13.138(7), c = 15.580(9) ?, b = 104.433(10)°, V = 1746.2(17) ?~3, Z = 4, D–c = 1.563 g×cm^3, μ = 1.769 mm^(–1), F(000) = 832, the final R = 0.0376 and wR = 0.1243 for 2850 observed reflections with I > 2s(I). In the crystal structure, the zinc atom is tetrahedrally coordinated by one MQ+ ligand and three NCS– groups to yield a tetrahedral configuration. The bond length of Zn–NMQ is clearly shorter than those found in reported Zn(Ⅱ) complexes of 4,4?-bipy. The isolated units are joined by C–H···S interactions to generate a 2D hydrogen-bonding network. This compound displays visible light-induced photoluminescence, which originates from both intraligand charge-transfer of the MQ+ ligand and NCS~–→MQ^+ charge-transfer according to a density of states(DOS) calculation. Moreover, its emission band shows a clear blue shift compared with those of halide compounds.
文摘A new cyano-bridged Gadolinium^(Ⅲ)-Iron^(Ⅲ)complex{[Gd(DMF)_(3)(DMSO)(H_(2)O)_(3)]2H_(2)0(DMF=N,N·-dimethylformamide;DMSO=dimethylsulfoxidel}was synthesized by the grinding reaction method,.It crysta-]llizes in the triclinic.,space group P1 with ceIl parameters:a=O.90363(2)nm,b=1.25078(3)nm,c=1.41303(1)nm,穋m^(-3),Z=2,Mr=756.72,F(000)=760,Ⅲ)and the approxi-mately oriented octahedrally sixfold-coordinated Fe(Ⅲ)are linked by a cyano-bridge group to construct a dinuclear compound.The{[Gd(DMF)_(3)(DMSO)(H_(2)O)_(3)](Ⅲ)-Fe(Ⅲ)interaction is antiferromagnetic.CCDC:223430.
基金the program of the Chinese Academy of Sciences(XDB20010100,QYZDB-SSW-SLH020)the NSF of China(21827813,21871264)the NSF of Fujian Province(2018J05036,2018J01028)。
文摘A novel metalloviologen complex{[Cd(PhSQ)(HTBC)(H_(2)O)_(2)]·1.25 H_(2)O}n(1)based on N-(4-sulfophenyl)-4,4’-bipyridinium(PhSQ)and monoprotonated trimesic acid(HTBC)has been prepared and structurally characterized.Complex 1 has been characterized by elemental analysis,IR,thermogravimetric analyses,UV-Vis spectra and X-ray crystallography.The coordination geometry of Cd(Ⅱ)ion is a pentagonal bipyramid.Complex 1 displays a zigzag chain along the b axis,and such chains are extended into a 2 D layer supramolecular network through hydrogen bonding and π…π interactions.Moreover,complex 1 exhibits reversible photochromic and switchable luminescent behaviors via UV light irradiation at room temperature induced by the photogenerated radicals via a photo-induced electron transfer(PET)mechanism.
