To effectively reuse high-titanium blast furnace slag (TS), foam glass-ceramics were successfully prepared by powder sintering at 1000℃. TS and waste glass were used as the main raw materials, aluminium nitride (...To effectively reuse high-titanium blast furnace slag (TS), foam glass-ceramics were successfully prepared by powder sintering at 1000℃. TS and waste glass were used as the main raw materials, aluminium nitride (AIN) as the foaming agent, and borax as the fluxing agent. The influence of the amount of A1N added (lwt%-5wt%) on the crystalline phases, microstructure, and properties of the produced foam glass-ceramics was studied. The results showed that the main crystal phases were perovskite, diopside, and augite. With increasing A1N content, a transformation from diopside to augite occurred and the crystallinity of the pyroxene phases slightly decreased. Initially, the aver- age pore size and porosity of the foam glass-ceramics increased and subsequently decreased; similarly, their bulk density and compressive strength decreased and subsequently increased. The optimal properties were obtained when the foam glass-ceramics were prepared by adding 4wt% AIN.展开更多
Foamed glass-ceramics were prepared via a single-step sintering method using high-titanium blast furnace slag and waste glass as the main raw materials The influence of sintering temperature(900–1060℃) on the micros...Foamed glass-ceramics were prepared via a single-step sintering method using high-titanium blast furnace slag and waste glass as the main raw materials The influence of sintering temperature(900–1060℃) on the microstructure and properties of foamed glass-ceramics was studied. The results show that the crystal shape changed from grainy to rod-shaped and finally turned to multiple shapes as the sintering temperature was increased from 900 to 1060℃. With increasing sintering temperature, the average pore size of the foamed glass-ceramics increased and subsequently decreased. By contrast, the compressive strength and the bulk density decreased and subsequently increased. An excessively high temperature, however, induced the coalescence of pores and decreased the compressive strength. The optimal properties, including the highest compressive strength(16.64 MPa) among the investigated samples and a relatively low bulk density(0.83 g/cm^3), were attained in the case of the foamed glass-ceramics sintered at 1000℃.展开更多
Foamed glass-ceramics doped with cerium oxide(CeO_2)were successfully prepared from high-titanium blast furnace slag by one-step sintering.The influence of CeO_2 addition(1.5wt%–3.5wt%)on the crystalline phases,m...Foamed glass-ceramics doped with cerium oxide(CeO_2)were successfully prepared from high-titanium blast furnace slag by one-step sintering.The influence of CeO_2 addition(1.5wt%–3.5wt%)on the crystalline phases,microstructure,and properties of foamed glass-ceramics was studied.Results show that CeO_2 improves the stability of the glass phase and changes the two-dimensional crystallization mechanism into three-dimensional one.XRD analysis indicates the presence of Ca(Mg,Fe)Si_2O_6 and Ca(Ti,Mg,Al)(Si,Al)_2O_(6 )in all sintered samples.Added with CeO_2,Ti CeO_4 precipitates,and crystallinity increases,leading to increased thickness of pore walls and uniform pores.The comprehensive properties of foamed glass-ceramics are better than that of samples without CeO_2.In particular,the sample added with a suitable amount of CeO_2(2.5wt%)exhibits bulk density that is similar to and compressive strength(14.9 MPa)that is more than twice of foamed glass-ceramics without CeO_2.展开更多
Objective To investigate the effect of ambient air pollution on human health and the subsequent disabillty-adjusted life years (DALYs) lost in Shanghai. Methods We used epidemiology-based exposure-response functions...Objective To investigate the effect of ambient air pollution on human health and the subsequent disabillty-adjusted life years (DALYs) lost in Shanghai. Methods We used epidemiology-based exposure-response functions to calculate the attributable number of cases due to air pollution in Shanghai in 2000, and then we estimated the corresponding DALYs lost in Shanghai based on unit DALYs values of the health consequences. Results Ambient air pollution caused 103 064 DALYs lost in Shanghai in 2000. Among all the health endpoints, premature deaths and chronic bronchitis predominated in the value of total DALYs lost. Conclusion The air pollution levels have an adverse effect on the general population health and strengthen the rationale for limiting the levels of air pollution in outdoor air in Shanghai.展开更多
Objective To investigate the potential impact of ambient air pollution on public health under various traffic policies in Shanghai. Methods The exposure level of Shanghai residents to air pollution under various plann...Objective To investigate the potential impact of ambient air pollution on public health under various traffic policies in Shanghai. Methods The exposure level of Shanghai residents to air pollution under various planned traffic scenarios was estimated, and the public health impact was assessed using concentration-response functions derived from available epidemiological studies. Results Our results showed that ambient air pollution in relation to traffic scenarios had a significant impact on the future health status of Shanghai residents. Compared with the base case scenario, implementation of various traffic scenarios could prevent 759-1574, 1885-2420, and 2277-2650 PM10-related avoidable deaths (mean-value) in 2010, 2015, and 2020, respectively. It could also decrease the incidence of several relevant diseases. Conclusion Our findings emphasize the need to consider air pollution-related health effects as an important impact of traffic policy in Shanghai.展开更多
基金the Science and Technology Support Projects of Sichuan Province (No. 2014GZ0011)the Industry Promotion Projects of Panzhihua in China (No.2013CY-C-2) for their financial support
文摘To effectively reuse high-titanium blast furnace slag (TS), foam glass-ceramics were successfully prepared by powder sintering at 1000℃. TS and waste glass were used as the main raw materials, aluminium nitride (AIN) as the foaming agent, and borax as the fluxing agent. The influence of the amount of A1N added (lwt%-5wt%) on the crystalline phases, microstructure, and properties of the produced foam glass-ceramics was studied. The results showed that the main crystal phases were perovskite, diopside, and augite. With increasing A1N content, a transformation from diopside to augite occurred and the crystallinity of the pyroxene phases slightly decreased. Initially, the aver- age pore size and porosity of the foam glass-ceramics increased and subsequently decreased; similarly, their bulk density and compressive strength decreased and subsequently increased. The optimal properties were obtained when the foam glass-ceramics were prepared by adding 4wt% AIN.
基金financially supported by the Science and Technology Support Program of Sichuan Province (No.2014GZ0011)the Industry Promotion Project of Panzhihua City, China (No.2012CY-C-2)
文摘Foamed glass-ceramics were prepared via a single-step sintering method using high-titanium blast furnace slag and waste glass as the main raw materials The influence of sintering temperature(900–1060℃) on the microstructure and properties of foamed glass-ceramics was studied. The results show that the crystal shape changed from grainy to rod-shaped and finally turned to multiple shapes as the sintering temperature was increased from 900 to 1060℃. With increasing sintering temperature, the average pore size of the foamed glass-ceramics increased and subsequently decreased. By contrast, the compressive strength and the bulk density decreased and subsequently increased. An excessively high temperature, however, induced the coalescence of pores and decreased the compressive strength. The optimal properties, including the highest compressive strength(16.64 MPa) among the investigated samples and a relatively low bulk density(0.83 g/cm^3), were attained in the case of the foamed glass-ceramics sintered at 1000℃.
基金the Science and Technology Support Projects of Sichuan (No.2014GZ0011)the Industry Promotion Projects of Panzhihua in China (No.2013CY-C-2) for their financial support
文摘Foamed glass-ceramics doped with cerium oxide(CeO_2)were successfully prepared from high-titanium blast furnace slag by one-step sintering.The influence of CeO_2 addition(1.5wt%–3.5wt%)on the crystalline phases,microstructure,and properties of foamed glass-ceramics was studied.Results show that CeO_2 improves the stability of the glass phase and changes the two-dimensional crystallization mechanism into three-dimensional one.XRD analysis indicates the presence of Ca(Mg,Fe)Si_2O_6 and Ca(Ti,Mg,Al)(Si,Al)_2O_(6 )in all sintered samples.Added with CeO_2,Ti CeO_4 precipitates,and crystallinity increases,leading to increased thickness of pore walls and uniform pores.The comprehensive properties of foamed glass-ceramics are better than that of samples without CeO_2.In particular,the sample added with a suitable amount of CeO_2(2.5wt%)exhibits bulk density that is similar to and compressive strength(14.9 MPa)that is more than twice of foamed glass-ceramics without CeO_2.
基金This work was supported by Energy Foundation through Grant G-0309-07094 and Shanghai Municipal Committee of Science and Technology through Grant 03DZ05052. Hai-Dong KAN was personally supported by Shanghai Rising-Star Program for Young Investigators (04QMX1402).
文摘Objective To investigate the effect of ambient air pollution on human health and the subsequent disabillty-adjusted life years (DALYs) lost in Shanghai. Methods We used epidemiology-based exposure-response functions to calculate the attributable number of cases due to air pollution in Shanghai in 2000, and then we estimated the corresponding DALYs lost in Shanghai based on unit DALYs values of the health consequences. Results Ambient air pollution caused 103 064 DALYs lost in Shanghai in 2000. Among all the health endpoints, premature deaths and chronic bronchitis predominated in the value of total DALYs lost. Conclusion The air pollution levels have an adverse effect on the general population health and strengthen the rationale for limiting the levels of air pollution in outdoor air in Shanghai.
基金supported by the Energy Foundation,Grant G-0309-07094Gong-Yi Program of China Ministry of Environmental Protection (No. 200809109)
文摘Objective To investigate the potential impact of ambient air pollution on public health under various traffic policies in Shanghai. Methods The exposure level of Shanghai residents to air pollution under various planned traffic scenarios was estimated, and the public health impact was assessed using concentration-response functions derived from available epidemiological studies. Results Our results showed that ambient air pollution in relation to traffic scenarios had a significant impact on the future health status of Shanghai residents. Compared with the base case scenario, implementation of various traffic scenarios could prevent 759-1574, 1885-2420, and 2277-2650 PM10-related avoidable deaths (mean-value) in 2010, 2015, and 2020, respectively. It could also decrease the incidence of several relevant diseases. Conclusion Our findings emphasize the need to consider air pollution-related health effects as an important impact of traffic policy in Shanghai.