This paper attempts to explore the decoupling relationship and its drivers between industrial economic increase and energy-related CO_(2) emissions(ICE). Firstly, the decoupling relationship was evaluated by Tapio ind...This paper attempts to explore the decoupling relationship and its drivers between industrial economic increase and energy-related CO_(2) emissions(ICE). Firstly, the decoupling relationship was evaluated by Tapio index. Then, based on the DEA meta-frontier theory framework which taking into account the regional and industrial heterogeneity and index decomposition method, the driving factors of decoupling process were explored mainly from the view of technology and efficiency. The results show that during2000-2019, weak decoupling was the primary state. Investment scale expansion was the largest reason hindering decoupling process of industrial increase from ICE. Both energy saving and production technology achieved significant progress, which facilitated the decoupling process. Simultaneously, the energy technology gap and production technology gap among regions have been narrowed, and played a role in promoting decoupling process. On the contrary, both scale economy efficiency and pure technical efficiency have inhibiting effects on decoupling process. The former indicates that the scale economy of China's industry was not conducive to improve energy efficiency and production efficiency, while the latter indicates that resource misallocation problem may exist in both energy market and product market.展开更多
Currently,deep drilling operates under extreme conditions of high temperature and high pressure,demanding more from subterranean power motors.The all-metal positive displacement motor,known for its robust performance,...Currently,deep drilling operates under extreme conditions of high temperature and high pressure,demanding more from subterranean power motors.The all-metal positive displacement motor,known for its robust performance,is a critical choice for such drilling.The dimensions of the PDM are crucial for its performance output.To enhance this,optimization of the motor's profile using a genetic algorithm has been undertaken.The design process begins with the computation of the initial stator and rotor curves based on the equations for a screw cycloid.These curves are then refined using the least squares method for a precise fit.Following this,the PDM's mathematical model is optimized,and motor friction is assessed.The genetic algorithm process involves encoding variations and managing crossovers to optimize objective functions,including the isometric radius coefficient,eccentricity distance parameter,overflow area,and maximum slip speed.This optimization yields the ideal profile parameters that enhance the motor's output.Comparative analyses of the initial and optimized output characteristics were conducted,focusing on the effects of the isometric radius coefficient and overflow area on the motor's performance.Results indicate that the optimized motor's overflow area increased by 6.9%,while its rotational speed reduced by 6.58%.The torque,as tested by Infocus,saw substantial improvements of38.8%.This optimization provides a theoretical foundation for improving the output characteristics of allmetal PDMs and supports the ongoing development and research of PDM technology.展开更多
Electrochemical co-reduction of nitrate(NO_(3)^(-))and carbon dioxide(CO_(2))has been widely regarded as a promising route to produce urea under ambient conditions,however the yield rate of urea has remained limited.H...Electrochemical co-reduction of nitrate(NO_(3)^(-))and carbon dioxide(CO_(2))has been widely regarded as a promising route to produce urea under ambient conditions,however the yield rate of urea has remained limited.Here,we report an atomically ordered intermetallic pallium-zinc(PdZn)electrocatalyst comprising a high density of PdZn pairs for boosting urea electrosynthesis.It is found that Pd and Zn are responsible for the adsorption and activation of NO_(3)^(-)and CO_(2),respectively,and thus the co-adsorption and co-activation NO_(3)^(-)and CO_(2) are achieved in ordered PdZn pairs.More importantly,the ordered and well-defined PdZn pairs provide a dual-site geometric structure conducive to the key C-N coupling with a low kinetical barrier,as demonstrated on both operando measurements and theoretical calculations.Consequently,the PdZn electrocatalyst displays excellent performance for the co-reduction to generate urea with a maximum urea Faradaic efficiency of 62.78%and a urea yield rate of 1274.42μg mg^(-1) h^(-1),and the latter is 1.5-fold larger than disordered pairs in PdZn alloys.This work paves new pathways to boost urea electrosynthesis via constructing ordered dual-metal pairs.展开更多
In this work,a novel one-time-programmable memory unit based on a Schottky-type p-GaN diode is proposed.During the programming process,the junction switches from a high-resistance state to a low-resistance state throu...In this work,a novel one-time-programmable memory unit based on a Schottky-type p-GaN diode is proposed.During the programming process,the junction switches from a high-resistance state to a low-resistance state through Schottky junction breakdown,and the state is permanently preserved.The memory unit features a current ratio of more than 10^(3),a read voltage window of 6 V,a programming time of less than 10^(−4)s,a stability of more than 108 read cycles,and a lifetime of far more than 10 years.Besides,the fabrication of the device is fully compatible with commercial Si-based GaN process platforms,which is of great significance for the realization of low-cost read-only memory in all-GaN integration.展开更多
Pesticide-loaded flexible carriers that allow for deformation and adhesion on crop leaves is an effective way to improve pesticide utilization.In interfacial polymerization,the addition of octaphenyl polyoxyethylene(O...Pesticide-loaded flexible carriers that allow for deformation and adhesion on crop leaves is an effective way to improve pesticide utilization.In interfacial polymerization,the addition of octaphenyl polyoxyethylene(OP)with different hydrophile lipophilic balances(HLBs)into the oil phase can regulate the flexibility of pyraclostrobinloaded microcapsules(MCs).Due to differences in amphiphilicity and molecular structure,OP redistributed on the oil-water two-phases and oil-water interface.With increasing HLB,the proportion of OP entering the aqueous phase increased.Furthermore,more OP with low HLB remained in the oil phase and occupied the oil-water interface,and these OPs participated in and regulated the interfacial polymerization to increase the thickness,reduce the compactness of the shell,and increase the hydroxyl and ether bond contents in the shell.Therefore,pyraclostrobin-loaded MCs with low HLB(11.5-12.5)OP-7 exhibited flexible deformation,strong foliar adhesion,good scouring resistance,and a high control effect on peanut leaf spot,which the disease severity was 3.67.For high HLB(16),OP-21-prepared MCs with compact shells were safer to zebrafish,which the safety index was 23.81.Using the amphiphilicity of OP molecules to drive their redistribution in an encapsulation system to regulate interfacial polymerization is an effective way to control the structure and performance of pesticideloaded MCs.展开更多
As the elderly population continues to grow, the number of patients with low back pain is gradually increasing. Among them, Lumbar Degenerative Diseases (LDD) is one of the major contributors to low back pain. Biomech...As the elderly population continues to grow, the number of patients with low back pain is gradually increasing. Among them, Lumbar Degenerative Diseases (LDD) is one of the major contributors to low back pain. Biomechanical in vivo studies of the lumbar spine are mainly performed by implants or imaging data to record the real-time changes of form and stress on the intervertebral disc during motion. However, the current developments are slow due to the technological and ethical limitations. In vitro experiments include animal experiments and cadaver experiments, which are difficult to operate or differ greatly from normal human structures, and the results still need to be verified repeatedly to test their accuracy. As for finite element method, it is relatively low cost and can repeat the experimental results. Therefore, we believe that finite element analysis plays an extremely important role in biomechanical research, especially in analyzing the relationship between different surgical models and the degeneration caused by different mechanics.展开更多
Generation of intense, fully coherent radiation with wide spectral coverage has been a long-standing challenge for laser technologies. Several techniques have been developed in recent years to extend the spectral cove...Generation of intense, fully coherent radiation with wide spectral coverage has been a long-standing challenge for laser technologies. Several techniques have been developed in recent years to extend the spectral coverage in optical physics, but none of them hold the potential to produce X-ray laser pulses with very high-peak power. Urgent demands for intense X-ray light sources have prompted the development of free-electron lasers(FELs), which have been proved to be very useful tools in many scientific areas. In this paper, we give an overview of the basic principle of FELs, techniques for realizing fully coherent FELs, and the development of fully coherent FEL facilities in China.展开更多
A two-stage echo-enabled harmonic generation(EEHG)scheme is proposed for a superconducting linacdriven FEL to produce coherent hard X-rays.Electron beams of quite different bunch lengths are separately used in each st...A two-stage echo-enabled harmonic generation(EEHG)scheme is proposed for a superconducting linacdriven FEL to produce coherent hard X-rays.Electron beams of quite different bunch lengths are separately used in each stage of EEHG,and a monochromator is designed to purify the radiation from the first stage for seeding the second stage.Theoretical analysis and 3D simulations indicate that the proposed scheme can generate high-repetition-rate coherent hard X-ray pulses directly from a conventional UV seed laser.展开更多
AIM: To evaluate transjugular intrahepatic portosystemic shunt (TIPS) with covered stents for hepatocellular carcinoma (HCC) with main portal vein tumor thrombus (PVTT).
In this article, we present the promise of a new method generating double electron pulses in picosecondscale pulse length and tunable interpulse spacing at several picoseconds. This has witnessed an impressive potenti...In this article, we present the promise of a new method generating double electron pulses in picosecondscale pulse length and tunable interpulse spacing at several picoseconds. This has witnessed an impressive potential of application in pump–probe techniques, two-color X-ray free electron laser, high-gradient witness bunch acceleration in a plasma, etc. Three-dimensional simulations are carried out to analyze the dynamic of the electron beam in a linear accelerator. Comparisons are made between the new method and existing ways.展开更多
The Shanghai soft X-ray free-electron laser(SXFEL)user facility project started in 2016 and is expected to be open to users by 2022.It aims to deliver ultra-intense coherent femtosecond X-ray pulses to five endstation...The Shanghai soft X-ray free-electron laser(SXFEL)user facility project started in 2016 and is expected to be open to users by 2022.It aims to deliver ultra-intense coherent femtosecond X-ray pulses to five endstations covering a range of 100–620 eV for ultrafast X-ray science.Two undulator lines are designed and constructed,based on different lasing modes:self-amplified spontaneous emission and echo-enabled harmonic generation.The coherent scattering and imaging(CSI)endstation is the first of five endstations to be commissioned online.It focuses on high-resolution single-shot imaging and the study of ultrafast dynamic processes using coherent forward scattering techniques.Both the single-shot holograms and coherent diffraction patterns were recorded and reconstructed for nanoscale imaging,indicating the excellent coherence and high peak power of the SXFEL and the possibility of‘‘diffraction before destruction’’experiments at the CSI endstation.In this study,we report the first commissioning results of the CSI endstation.展开更多
基金financial support from the China Postdoctoral Science Foundation project(No.2023M733253)。
文摘This paper attempts to explore the decoupling relationship and its drivers between industrial economic increase and energy-related CO_(2) emissions(ICE). Firstly, the decoupling relationship was evaluated by Tapio index. Then, based on the DEA meta-frontier theory framework which taking into account the regional and industrial heterogeneity and index decomposition method, the driving factors of decoupling process were explored mainly from the view of technology and efficiency. The results show that during2000-2019, weak decoupling was the primary state. Investment scale expansion was the largest reason hindering decoupling process of industrial increase from ICE. Both energy saving and production technology achieved significant progress, which facilitated the decoupling process. Simultaneously, the energy technology gap and production technology gap among regions have been narrowed, and played a role in promoting decoupling process. On the contrary, both scale economy efficiency and pure technical efficiency have inhibiting effects on decoupling process. The former indicates that the scale economy of China's industry was not conducive to improve energy efficiency and production efficiency, while the latter indicates that resource misallocation problem may exist in both energy market and product market.
基金supported by the National Natural Science Foundation of China (No.42172343)。
文摘Currently,deep drilling operates under extreme conditions of high temperature and high pressure,demanding more from subterranean power motors.The all-metal positive displacement motor,known for its robust performance,is a critical choice for such drilling.The dimensions of the PDM are crucial for its performance output.To enhance this,optimization of the motor's profile using a genetic algorithm has been undertaken.The design process begins with the computation of the initial stator and rotor curves based on the equations for a screw cycloid.These curves are then refined using the least squares method for a precise fit.Following this,the PDM's mathematical model is optimized,and motor friction is assessed.The genetic algorithm process involves encoding variations and managing crossovers to optimize objective functions,including the isometric radius coefficient,eccentricity distance parameter,overflow area,and maximum slip speed.This optimization yields the ideal profile parameters that enhance the motor's output.Comparative analyses of the initial and optimized output characteristics were conducted,focusing on the effects of the isometric radius coefficient and overflow area on the motor's performance.Results indicate that the optimized motor's overflow area increased by 6.9%,while its rotational speed reduced by 6.58%.The torque,as tested by Infocus,saw substantial improvements of38.8%.This optimization provides a theoretical foundation for improving the output characteristics of allmetal PDMs and supports the ongoing development and research of PDM technology.
基金supported by the National Natural Science Foundation of China(22379100,U21A20312)the Shenzhen Science and Technology Program(Grant No.20231121200418001)+1 种基金the Guangdong Basic and Applied Basic Research Foundation(2022B1515120084)the Key Project of Department of Education of Guangdong Province(2023ZDZX3020)。
文摘Electrochemical co-reduction of nitrate(NO_(3)^(-))and carbon dioxide(CO_(2))has been widely regarded as a promising route to produce urea under ambient conditions,however the yield rate of urea has remained limited.Here,we report an atomically ordered intermetallic pallium-zinc(PdZn)electrocatalyst comprising a high density of PdZn pairs for boosting urea electrosynthesis.It is found that Pd and Zn are responsible for the adsorption and activation of NO_(3)^(-)and CO_(2),respectively,and thus the co-adsorption and co-activation NO_(3)^(-)and CO_(2) are achieved in ordered PdZn pairs.More importantly,the ordered and well-defined PdZn pairs provide a dual-site geometric structure conducive to the key C-N coupling with a low kinetical barrier,as demonstrated on both operando measurements and theoretical calculations.Consequently,the PdZn electrocatalyst displays excellent performance for the co-reduction to generate urea with a maximum urea Faradaic efficiency of 62.78%and a urea yield rate of 1274.42μg mg^(-1) h^(-1),and the latter is 1.5-fold larger than disordered pairs in PdZn alloys.This work paves new pathways to boost urea electrosynthesis via constructing ordered dual-metal pairs.
基金supported in part by the National Key Research and Development Program of China under Grant 2022YFB3604400in part by the Youth Innovation Promotion Association of Chinese Academy Sciences (CAS)+4 种基金in part by the CAS-Croucher Funding Scheme under Grant CAS22801in part by National Natural Science Foundation of China under Grant 62334012, Grant 62074161, Grant 62004213, Grant U20A20208, and Grant 62304252in part by the Beijing Municipal Science and Technology Commission project under Grant Z201100008420009 and Grant Z211100007921018in part by the University of CASin part by the IMECAS-HKUST-Joint Laboratory of Microelectronics
文摘In this work,a novel one-time-programmable memory unit based on a Schottky-type p-GaN diode is proposed.During the programming process,the junction switches from a high-resistance state to a low-resistance state through Schottky junction breakdown,and the state is permanently preserved.The memory unit features a current ratio of more than 10^(3),a read voltage window of 6 V,a programming time of less than 10^(−4)s,a stability of more than 108 read cycles,and a lifetime of far more than 10 years.Besides,the fabrication of the device is fully compatible with commercial Si-based GaN process platforms,which is of great significance for the realization of low-cost read-only memory in all-GaN integration.
基金supported by the National Natural Science of China(32272596)Key Research Development Program of Shandong Province(2022CXGC020710)+2 种基金Shandong Province Agricultural Major Technology Collaborative Promotion Plan(SDNYXTTG-2023-20)Central Publicinterest Scientific Institution Basal Research Fund(No.1610232023005)Major technology projects[110202201029(LS-13)].
文摘Pesticide-loaded flexible carriers that allow for deformation and adhesion on crop leaves is an effective way to improve pesticide utilization.In interfacial polymerization,the addition of octaphenyl polyoxyethylene(OP)with different hydrophile lipophilic balances(HLBs)into the oil phase can regulate the flexibility of pyraclostrobinloaded microcapsules(MCs).Due to differences in amphiphilicity and molecular structure,OP redistributed on the oil-water two-phases and oil-water interface.With increasing HLB,the proportion of OP entering the aqueous phase increased.Furthermore,more OP with low HLB remained in the oil phase and occupied the oil-water interface,and these OPs participated in and regulated the interfacial polymerization to increase the thickness,reduce the compactness of the shell,and increase the hydroxyl and ether bond contents in the shell.Therefore,pyraclostrobin-loaded MCs with low HLB(11.5-12.5)OP-7 exhibited flexible deformation,strong foliar adhesion,good scouring resistance,and a high control effect on peanut leaf spot,which the disease severity was 3.67.For high HLB(16),OP-21-prepared MCs with compact shells were safer to zebrafish,which the safety index was 23.81.Using the amphiphilicity of OP molecules to drive their redistribution in an encapsulation system to regulate interfacial polymerization is an effective way to control the structure and performance of pesticideloaded MCs.
文摘As the elderly population continues to grow, the number of patients with low back pain is gradually increasing. Among them, Lumbar Degenerative Diseases (LDD) is one of the major contributors to low back pain. Biomechanical in vivo studies of the lumbar spine are mainly performed by implants or imaging data to record the real-time changes of form and stress on the intervertebral disc during motion. However, the current developments are slow due to the technological and ethical limitations. In vitro experiments include animal experiments and cadaver experiments, which are difficult to operate or differ greatly from normal human structures, and the results still need to be verified repeatedly to test their accuracy. As for finite element method, it is relatively low cost and can repeat the experimental results. Therefore, we believe that finite element analysis plays an extremely important role in biomechanical research, especially in analyzing the relationship between different surgical models and the degeneration caused by different mechanics.
基金supported by the National Key Research and Development Program of China(No.2016YFA0401900)the National Natural Science Foundation of China(Nos.11475250 and11775293)+1 种基金the Young Elite Scientist Sponsorship Program of CAST(2015QNRC001)the Ten Thousand Talent Program
文摘Generation of intense, fully coherent radiation with wide spectral coverage has been a long-standing challenge for laser technologies. Several techniques have been developed in recent years to extend the spectral coverage in optical physics, but none of them hold the potential to produce X-ray laser pulses with very high-peak power. Urgent demands for intense X-ray light sources have prompted the development of free-electron lasers(FELs), which have been proved to be very useful tools in many scientific areas. In this paper, we give an overview of the basic principle of FELs, techniques for realizing fully coherent FELs, and the development of fully coherent FEL facilities in China.
基金partially supported by the National Development and Reform Commission([2013]2347)National Natural Science Foundation of China(No.11475250)the Youth Innovation Promotion Association CAS(2015209)
文摘A two-stage echo-enabled harmonic generation(EEHG)scheme is proposed for a superconducting linacdriven FEL to produce coherent hard X-rays.Electron beams of quite different bunch lengths are separately used in each stage of EEHG,and a monochromator is designed to purify the radiation from the first stage for seeding the second stage.Theoretical analysis and 3D simulations indicate that the proposed scheme can generate high-repetition-rate coherent hard X-ray pulses directly from a conventional UV seed laser.
基金Supported by Science and Technology Planning Project of Guangdong Province,China,No.2012B010200027The Key Technologies RD Program of Guangzhou,ChinaThe Presidential Foundation of the Nanfang Hospital,Southern Medical University,Guangzhou,China,No.2011B006
文摘AIM: To evaluate transjugular intrahepatic portosystemic shunt (TIPS) with covered stents for hepatocellular carcinoma (HCC) with main portal vein tumor thrombus (PVTT).
基金partially supported by the Major State Basic Research Development Program of China(No.2011CB808300)the National Natural Science Foundation of China(Nos.11175240,11205234 and 11322550)
文摘In this article, we present the promise of a new method generating double electron pulses in picosecondscale pulse length and tunable interpulse spacing at several picoseconds. This has witnessed an impressive potential of application in pump–probe techniques, two-color X-ray free electron laser, high-gradient witness bunch acceleration in a plasma, etc. Three-dimensional simulations are carried out to analyze the dynamic of the electron beam in a linear accelerator. Comparisons are made between the new method and existing ways.
基金the Shanghai Soft X-ray Free-Electron Laser Facility beamline projectionfunded by the Major State Basic Research Development Program of China(No.2017YFA0504802)+1 种基金Strategic Priority Research Program of the Chinese Academy of Sciences(No.XDB 37040303)National Natural Science Foundation of China(No.21727817).
文摘The Shanghai soft X-ray free-electron laser(SXFEL)user facility project started in 2016 and is expected to be open to users by 2022.It aims to deliver ultra-intense coherent femtosecond X-ray pulses to five endstations covering a range of 100–620 eV for ultrafast X-ray science.Two undulator lines are designed and constructed,based on different lasing modes:self-amplified spontaneous emission and echo-enabled harmonic generation.The coherent scattering and imaging(CSI)endstation is the first of five endstations to be commissioned online.It focuses on high-resolution single-shot imaging and the study of ultrafast dynamic processes using coherent forward scattering techniques.Both the single-shot holograms and coherent diffraction patterns were recorded and reconstructed for nanoscale imaging,indicating the excellent coherence and high peak power of the SXFEL and the possibility of‘‘diffraction before destruction’’experiments at the CSI endstation.In this study,we report the first commissioning results of the CSI endstation.
