This paper reports a newly discovered Late Mesoproterozoic-Early Neoproterozoic stromatolite assemblage, named here the "Jiawengmen stromatolite assemblage", represented by a Conophyton-Baicalia association in the J...This paper reports a newly discovered Late Mesoproterozoic-Early Neoproterozoic stromatolite assemblage, named here the "Jiawengmen stromatolite assemblage", represented by a Conophyton-Baicalia association in the Jiawenmen area in the southern belt of the Eastern Kunlun. This stromatolite assemblage is dominated by large-scale conical stromatolites and related elements, i.e., Conophyton garganicus var. inkeni, C. cf. ressoti Menchikov, Jacutophyton cf., Conicodomenia f., which commonly co-exist with elements of the group of Baicalia. This assemblage can be correlated with that of the middle Jixian-middle Qingbaikou System in North and Northwest China, but is different from that in South China. Correlation can also be made with that in the upper horizon of the Middle Riphean-lower horizon of the Upper Riphean in the South Ural Mountains and Siberia of Russia, in North Africa, and in the Alaskan Peninsula of North America. These facts suggest that the Jiawengmen stromatolite assemblage probably colonized during 1300-850 Ma ago. Accordingly, the stromatolite-bearing carbonate rocks are then proposed to correspond to the middle Jixian System-middle Qingbaikou System or the upper Middle Riphean-lower Upper Riphean. Our stromatolite data further suggest that a Precambrian microblock, named the Xialawen microblock here, occurred in the southern belt of Eastern Kunlun, the western part of the Maqên microblock. Similar stromatolite assemblages in the Maqên microblock and those blocks that occurred in North China, Siberia and North Africa point to similar paleogeographic and paleoenvironmental conditions. These microblock and blocks were probably located at low latitudes and on the continental margins of the Rodinian supercontinent, where warm epicontinental seas were favorable to widespread colonization of stromatolites during the Late Mesoproterozoic-Eady Neoproterozoic. However, these stromatolite assemblages are quite different from those of the South China block, which is suggestive of different paleogeographic contexts, and probably also of a different tectonic affinity.展开更多
Late Cambrian to Early Ordovician sedimentary rocks in the western Tarim Basin, Northwest China, are composed of shallow-marine platform carbonates. The Keping Uplift is located in the northwest region of this basin. ...Late Cambrian to Early Ordovician sedimentary rocks in the western Tarim Basin, Northwest China, are composed of shallow-marine platform carbonates. The Keping Uplift is located in the northwest region of this basin. On the basis of petrographic and geochemical features, four matrix replacement dolomites and one type of cement dolomite are identified. Matrix replacement dolomites include (1) micritic dolomites (MD1); (2) fine-coarse euhedral floating dolomites (MD2); (3) fine-coarse euhedral dolomites (MD3); and (4) medium-very coarse anhedral mosaic dolomites (MD4). Dolomite cement occurs in minor amounts as coarse saddle dolomite cement (CD1) that mostly fills vugs and fractures in the matrix dolomites. These matrix dolomites have δ18O values of ?9.7‰ to ?3.0‰ VPDB (Vienna Pee Dee Belemnite); δ13C values of ?0.8‰ to 3.5‰ VPDB; 87Sr/86Sr ratios of 0.708516 to 0.709643; Sr concentrations of 50 to 257 ppm; Fe contents of 425 to 16878 ppm; and Mn contents of 28 to 144 ppm. Petrographic and geochemical data suggest that the matrix replacement dolomites were likely formed by normal and evaporative seawater in early stages prior to chemical compaction at shallow burial depths. Compared with matrix dolomites, dolomite cement yields lower δ18O values (?12.9‰ to ?9.1‰ VPDB); slightly lower δ13C values (?1.6‰-0.6‰ VPDB); higher 87Sr/86Sr ratios (0.709165-0.709764); and high homogenization temperature (Th) values (98°C-225°C) and salinities (6 wt%-24 wt% NaCl equivalent). Limited data from dolomite cement shows a low Sr concentration (58.6 ppm) and high Fe and Mn contents (1233 and 1250 ppm, respectively). These data imply that the dolomite cement precipitated from higher temperature hydrothermal salinity fluids. These fluids could be related to widespread igneous activities in the Tarim Basin occurring during Permian time when the host dolostones were deeply buried. Faults likely acted as important conduits that channeled dolomitizing fluids from the underlying strata into the basal carbonates, leading to intense dolomitization. Therefore, dolomitization, in the Keping Uplift area is likely related to evaporated seawater via seepage reflux in addition to burial processes and hydrothermal fluids.展开更多
Extensive organic-matter (OM) rich facies (black shales) occur in the Ordo-Silurian boundary successions in the Yangtze area, South China. To investigate the redox changes of the Yangtze Sea during the Ordo-Siluri...Extensive organic-matter (OM) rich facies (black shales) occur in the Ordo-Silurian boundary successions in the Yangtze area, South China. To investigate the redox changes of the Yangtze Sea during the Ordo-Silurian transition, two OM sections (Wangjiawan in Yichang, Hubei Province, and Sanjiaguan in Zhangjiajie, Hunan Province) straddling the Ordo-Silurian boundary are studied. The measurements finished in this study include contents of the total organic carbon (TOC), pyrite sulphur, and different species of Fe, including dithionite-extractable Fe (FED), pyrite Fe (FeP), HCl-extractable Fe (FeH), and total Fe (FeT), in black shales, as well as other redox proxies, such as the SIC ratio, the ratio between highly reactive Fe (FeHR = FeD + FeP) and FeT, and the FeP/(FeP + FeH) ratio, known as the degree of pyritization (DOP). In the Wangjiawan section, the Middle Ashgill sediments have high FeHR/FeT ratios (0.20-0.77; avg. 0.45), high DOP values (0.21-0.72; avg. 0.54), and a relatively constant sulfur content independent of the organic carbon content. By the contrast, the mid-early Hirnantian deposits generally have low FeHR/FeT ratios (0.10-0.35; avg. 0.21), low DOP values (0.11- 0.40; avg. 0.28), and SIC values are clustering on the normal marine value (SIC = 0.36). The late Hirnantian and early Rhuddanian deposits, similar to those of the Middle Ashgill deposits, are characterized by high FeHR/FeT ratios (0.32-0.49; avg. 0.41), high DOP values (0.46-0.68; avg. 0.53) and fairly constant sulfur contents. These data suggest the occurrences of marine anoxia on the Yangtze Sea shelf during intervals of the Mid Ashgill, Late Hirnantian and Early Rhuddanian, and ventilated and oxygenated marine conditions during the mid-early Hirnantian time. The mid-early Hirnantian ventilated event was concomitant with the global glacial period, likely resulted from the glacio-eustatic sea-level fall and subsequent circulation of cold, dense oxygenated waters upon the shelf seabed. Accordingly, the abrupt change from oxygenated to anoxic marine waters from the late Hirnantian and the early Rhuddanian were resulted from the post-glacial rise of eustatic sea level. Combined with the data from Sanjiaguan section near the subemergent highland, salinity stratification of water columns are strongly evidenced by very low S/C ratios ( 0.00-0.08, avg. 0.02), low FeHR/FeT ratios (0.10-0.37, avg. 0.27), low DOP values (0.01-0.27, avg. 0.10), and TOC contents (0.72%-4.27%, avg. 2.55%). Under this circumstance, the anoxic water columns could have formed beneath the halocline, above which desalinized waters formed. In the Wangjiawan section, TOC contents are generally high (0.94- 9.32%, avg. 4.44%), but low (0.35%-2.12%, avg. 1.29%) in the mid-early Hirnantian that is coincident with the oceanic oxic stage, together with relation of the organic contents to the stratal thickness, suggesting that the accumulation of the organic matter was mainly controlled by the oxygen levels of the water columns; on the other hand, productivity and depositional rate may also have played a role in the organic accumulation and preservation.展开更多
The Upper Ediacaran microbial carbonates of the Tarim Basin are potential reservoir geobodies for future hydrocarbon exploration with rising interest in exploration for deeply-buried reserves.However,little knowledge ...The Upper Ediacaran microbial carbonates of the Tarim Basin are potential reservoir geobodies for future hydrocarbon exploration with rising interest in exploration for deeply-buried reserves.However,little knowledge has been acquired on the types of microbial carbonates that are present,the properties of the reservoir and the pore evolution,hampering predictions of high-quality reservoirs in these carbonates.Integrated with petrography and in-situ U-Pb dating geochronology analyses,this study aims to clarify the types of microbial carbonates present and to reconstruct the pore evolution processes of the potential reservoir rocks.The Upper Ediacaran microbial carbonates of the Tarim Basin can be divided into four types,based on their features in terms of different scales(macro-to micro-):microbial laminite,stromatolite,spongiomicrobialite and microbial-peloidal wackestone/mudstone.Petrophysical properties show that all these microbial carbonates have low porosity and very low permeability with poor connectivity.These carbonates were subject to long-term and complex diagenetic processes,mainly consisting of dissolution,compaction,pervasive dolomitization,cementation and fracturing.The most important reservoir spaces are contributed by vugs and dissolution-enlarged pores,which are likely to have been associated with the widespread uplift of the Aksu area in the terminal Ediacaran.In contrast,the cementation of the fine-to-medium crystalline dolomite greatly reduced the pre-existing pores.Pore types are closely related to different microbial fabrics,which played an important role in the pore evolution of the microbial carbonates.展开更多
The trace element and rare earth element(REE) variations across the Ordovician-Silurian succession are presented from two outcrop sections on the Yangtze Platform:the Nanbazi section,Guizhou Province,deposited in a sh...The trace element and rare earth element(REE) variations across the Ordovician-Silurian succession are presented from two outcrop sections on the Yangtze Platform:the Nanbazi section,Guizhou Province,deposited in a shallow platform interior setting,and the Wangjiawan section,Hubei Province,deposited in a deeper basinal environment.Geochemical analysis of closely spaced samples through three intervals,the Wufeng,Guanyinqiao and Longmaxi,revealed vast palaeoceanographic changes.Some geochemical proxies,including Th/U,Ni/Co,V/Cr,and V/(V+Ni) ratios,together with sedimentary facies and biotic data,indicate that an anoxic condition on the most of the Yangtze Platform during the Wufeng and Longmaxi intervals,but an oxic condition during the Guanyinqiao time.The shift of the anoxic to the oxic environment during the Guanyinqiao time coincided with a global sea-level lowstand,in parallel with the global glaciation.The Longmaxian anoxic environment was a result of a global sea-level rise,which may be synchronized with a mainly catastrophic event in the latest Ordovician.Although the two sections generally show similar variation patterns of trace and REE concentrations and some element ratios,a minor difference occurs between the Wangjiawan and Nanbazi sections,likely reflecting a difference in depositional setting during the accumulation.Such an oceanic oxygen-level variation may add a useful constraint to the current arguments on the cause and consequence of the latest Ordovician mass extinction.展开更多
Detailed characterization of diagenetic fluid behaviour and evolution is commonly hindered by shortage of appropriate and economic methods to carry out in situ analysis in the tiny diagenetic mineral crystals. Using m...Detailed characterization of diagenetic fluid behaviour and evolution is commonly hindered by shortage of appropriate and economic methods to carry out in situ analysis in the tiny diagenetic mineral crystals. Using micromill sampling method, this study presents in situ stable isotopic data for the growth zones of saddle dolomite crystals in the hydrothermally-altered dolostones of Upper Cambrian (Furongian) at Keping, Tarim Basin, NW China. These data show minor and large variations in δ13C ( 0.7‰ to 1.5‰ VPDB) and δ18O ( 8.3‰ to 13.8‰ VPDB), respectively, from the cores to outer rims of the dolomite crystals and suggest that saddle dolomites precipitated from dolomitizing fluids with similar carbon sources but oscillatory temperatures during different formation stages. This scenario is confirmed by microthermometry of fluid inclusions within the growth zones of dolomite crystals. This study indicates that in situ isotope analysis could provide more detailed information related to the source and pathway of dolomitizing fluids, facilitating better characterization of dolomitizing fluids and processes.展开更多
The end-Paleozoic biotic crisis is characterized by two-phase mass extinctions;the first strike,resulting in a large decline of sessile benthos in shallow marine environments,occurred at the end-Guadalupian time.In or...The end-Paleozoic biotic crisis is characterized by two-phase mass extinctions;the first strike,resulting in a large decline of sessile benthos in shallow marine environments,occurred at the end-Guadalupian time.In order to explore the mechanism of organisms' demise,detailed analyses of depositional facies,fossil record,and carbonate carbon isotopic variations were carried out on a Maokou-Wujiaping boundary succession in northwestern Sichuan,SW China.Our data reveal a negative carbon isotopic excursion across the boundary;the gradual excursion with relatively low amplitude(2.15‰) favors a long-term influx of isotopically light 12 C sourced by the Emeishan basalt trap,rather than by rapid releasing of gas hydrate.The temporal coincidence of the beginning of accelerated negative carbon isotopic excursion with onsets of sea-level fall and massive biotic demise suggests a cause-effect link between them.Intensive volcanic activity of the Emeishan trap and sea-level fall could have resulted in detrimental environmental stresses and habitat loss for organisms,particularly for those benthic dwellers,leading to their subsequent massive extinction.展开更多
High-frequency metre-scale cycles are present within the Lower-Middle Ordovician carbonate successions in northern Tarim Basin, NW China. These metre-scale cycles were variably dolomitised from top to bottom. Three ty...High-frequency metre-scale cycles are present within the Lower-Middle Ordovician carbonate successions in northern Tarim Basin, NW China. These metre-scale cycles were variably dolomitised from top to bottom. Three types of replacive dolomites were recognised, including dololaminite(very finely to finely crystalline, planar-s to nonplanar-a dolomite;type-1), patterned dolomite(finely crystalline, planar-s dolomite; type-2), and mottled dolomite(finely to medium crystalline,nonplanar-a(s) dolomite; type-3). Petrographic evidence indicate these dolomites were primarily deposited in supratidal to restricted subtidal environments, and formed in near-surface to shallow burial realms. Geochemically, all types of dolomites have similar δ13C and 87Sr/86 Sr ratios comparable to calcite precipitated in equilibrium with the Early-Middle Ordovician seawater. These geochemical attributes indicate that these dolomites were genetically associated and likely formed from connate seawater-derived brines. Of these, type-1 dolomite has δ18O values(.4.97‰ to.4.04‰ VPDB) slightly higher than those of normal seawater dolomite of the Early-Middle Ordovician age. Considering the absence of associated evaporites within type-1 dolomite, its parental fluids were likely represented by slightly evaporated(i.e., mesosaline to penesaline) seawater with salinity below that of gypsum precipitation. More depleted δ18O values(.7.74‰ to.5.20‰ VPDB) of type-2 dolomite and its stratigraphic position below type-1 dolomite indicate the generation of this dolomite from mesosaline to penesaline brines at higher temperatures in near-surface to shallow burial domains. Type-3 dolomite yields the most depleted δ18O values(–9.30‰to –7.28‰ VPDB), pointing to that it was most likely formed from coeval seawater-derived brines at highest temperatures in a shallow burial setting. There is a downward decreasing trend in δ18O values from type-1 through type-2 to type-3 dolomites, and in abundance of dolomites, indicating that the dolomitising fluids probably migrated downward from above and persisted into shallow burial conditions.展开更多
基金This work was supported by the KIP Key Project of the Chinese Academy of Sciences(KZCX3-SW-143)the KIP Key Project of the Chinese Academy of Sciences(KZCX2-SW-119)+3 种基金the Key Project of the National Natural Science Foundation of China(Grant No.40334044)the Chinese National Key Basic Research Project(2002CB4 12600)the National Natural Science Foundation of China(Grant No.49872077)the Lu Jiaxi Foundation of the Chinese Academy of Sciences.
文摘This paper reports a newly discovered Late Mesoproterozoic-Early Neoproterozoic stromatolite assemblage, named here the "Jiawengmen stromatolite assemblage", represented by a Conophyton-Baicalia association in the Jiawenmen area in the southern belt of the Eastern Kunlun. This stromatolite assemblage is dominated by large-scale conical stromatolites and related elements, i.e., Conophyton garganicus var. inkeni, C. cf. ressoti Menchikov, Jacutophyton cf., Conicodomenia f., which commonly co-exist with elements of the group of Baicalia. This assemblage can be correlated with that of the middle Jixian-middle Qingbaikou System in North and Northwest China, but is different from that in South China. Correlation can also be made with that in the upper horizon of the Middle Riphean-lower horizon of the Upper Riphean in the South Ural Mountains and Siberia of Russia, in North Africa, and in the Alaskan Peninsula of North America. These facts suggest that the Jiawengmen stromatolite assemblage probably colonized during 1300-850 Ma ago. Accordingly, the stromatolite-bearing carbonate rocks are then proposed to correspond to the middle Jixian System-middle Qingbaikou System or the upper Middle Riphean-lower Upper Riphean. Our stromatolite data further suggest that a Precambrian microblock, named the Xialawen microblock here, occurred in the southern belt of Eastern Kunlun, the western part of the Maqên microblock. Similar stromatolite assemblages in the Maqên microblock and those blocks that occurred in North China, Siberia and North Africa point to similar paleogeographic and paleoenvironmental conditions. These microblock and blocks were probably located at low latitudes and on the continental margins of the Rodinian supercontinent, where warm epicontinental seas were favorable to widespread colonization of stromatolites during the Late Mesoproterozoic-Eady Neoproterozoic. However, these stromatolite assemblages are quite different from those of the South China block, which is suggestive of different paleogeographic contexts, and probably also of a different tectonic affinity.
基金in part provided by Petro China(Grant No.09HT10500000068)Sinopec(Grant No.G5800-07-ZS-WX032)the State Key Lab of Oil/Gas Reservoir Geology and Exploitation at CDUT(Grant No.PLC200801)to H.Qing
文摘Late Cambrian to Early Ordovician sedimentary rocks in the western Tarim Basin, Northwest China, are composed of shallow-marine platform carbonates. The Keping Uplift is located in the northwest region of this basin. On the basis of petrographic and geochemical features, four matrix replacement dolomites and one type of cement dolomite are identified. Matrix replacement dolomites include (1) micritic dolomites (MD1); (2) fine-coarse euhedral floating dolomites (MD2); (3) fine-coarse euhedral dolomites (MD3); and (4) medium-very coarse anhedral mosaic dolomites (MD4). Dolomite cement occurs in minor amounts as coarse saddle dolomite cement (CD1) that mostly fills vugs and fractures in the matrix dolomites. These matrix dolomites have δ18O values of ?9.7‰ to ?3.0‰ VPDB (Vienna Pee Dee Belemnite); δ13C values of ?0.8‰ to 3.5‰ VPDB; 87Sr/86Sr ratios of 0.708516 to 0.709643; Sr concentrations of 50 to 257 ppm; Fe contents of 425 to 16878 ppm; and Mn contents of 28 to 144 ppm. Petrographic and geochemical data suggest that the matrix replacement dolomites were likely formed by normal and evaporative seawater in early stages prior to chemical compaction at shallow burial depths. Compared with matrix dolomites, dolomite cement yields lower δ18O values (?12.9‰ to ?9.1‰ VPDB); slightly lower δ13C values (?1.6‰-0.6‰ VPDB); higher 87Sr/86Sr ratios (0.709165-0.709764); and high homogenization temperature (Th) values (98°C-225°C) and salinities (6 wt%-24 wt% NaCl equivalent). Limited data from dolomite cement shows a low Sr concentration (58.6 ppm) and high Fe and Mn contents (1233 and 1250 ppm, respectively). These data imply that the dolomite cement precipitated from higher temperature hydrothermal salinity fluids. These fluids could be related to widespread igneous activities in the Tarim Basin occurring during Permian time when the host dolostones were deeply buried. Faults likely acted as important conduits that channeled dolomitizing fluids from the underlying strata into the basal carbonates, leading to intense dolomitization. Therefore, dolomitization, in the Keping Uplift area is likely related to evaporated seawater via seepage reflux in addition to burial processes and hydrothermal fluids.
文摘Extensive organic-matter (OM) rich facies (black shales) occur in the Ordo-Silurian boundary successions in the Yangtze area, South China. To investigate the redox changes of the Yangtze Sea during the Ordo-Silurian transition, two OM sections (Wangjiawan in Yichang, Hubei Province, and Sanjiaguan in Zhangjiajie, Hunan Province) straddling the Ordo-Silurian boundary are studied. The measurements finished in this study include contents of the total organic carbon (TOC), pyrite sulphur, and different species of Fe, including dithionite-extractable Fe (FED), pyrite Fe (FeP), HCl-extractable Fe (FeH), and total Fe (FeT), in black shales, as well as other redox proxies, such as the SIC ratio, the ratio between highly reactive Fe (FeHR = FeD + FeP) and FeT, and the FeP/(FeP + FeH) ratio, known as the degree of pyritization (DOP). In the Wangjiawan section, the Middle Ashgill sediments have high FeHR/FeT ratios (0.20-0.77; avg. 0.45), high DOP values (0.21-0.72; avg. 0.54), and a relatively constant sulfur content independent of the organic carbon content. By the contrast, the mid-early Hirnantian deposits generally have low FeHR/FeT ratios (0.10-0.35; avg. 0.21), low DOP values (0.11- 0.40; avg. 0.28), and SIC values are clustering on the normal marine value (SIC = 0.36). The late Hirnantian and early Rhuddanian deposits, similar to those of the Middle Ashgill deposits, are characterized by high FeHR/FeT ratios (0.32-0.49; avg. 0.41), high DOP values (0.46-0.68; avg. 0.53) and fairly constant sulfur contents. These data suggest the occurrences of marine anoxia on the Yangtze Sea shelf during intervals of the Mid Ashgill, Late Hirnantian and Early Rhuddanian, and ventilated and oxygenated marine conditions during the mid-early Hirnantian time. The mid-early Hirnantian ventilated event was concomitant with the global glacial period, likely resulted from the glacio-eustatic sea-level fall and subsequent circulation of cold, dense oxygenated waters upon the shelf seabed. Accordingly, the abrupt change from oxygenated to anoxic marine waters from the late Hirnantian and the early Rhuddanian were resulted from the post-glacial rise of eustatic sea level. Combined with the data from Sanjiaguan section near the subemergent highland, salinity stratification of water columns are strongly evidenced by very low S/C ratios ( 0.00-0.08, avg. 0.02), low FeHR/FeT ratios (0.10-0.37, avg. 0.27), low DOP values (0.01-0.27, avg. 0.10), and TOC contents (0.72%-4.27%, avg. 2.55%). Under this circumstance, the anoxic water columns could have formed beneath the halocline, above which desalinized waters formed. In the Wangjiawan section, TOC contents are generally high (0.94- 9.32%, avg. 4.44%), but low (0.35%-2.12%, avg. 1.29%) in the mid-early Hirnantian that is coincident with the oceanic oxic stage, together with relation of the organic contents to the stratal thickness, suggesting that the accumulation of the organic matter was mainly controlled by the oxygen levels of the water columns; on the other hand, productivity and depositional rate may also have played a role in the organic accumulation and preservation.
基金financially supported by the National Key Research and Development(R&D)Program of China(2017YFC0603103)the National Natural Science Foundation of China(U19B6003)。
文摘The Upper Ediacaran microbial carbonates of the Tarim Basin are potential reservoir geobodies for future hydrocarbon exploration with rising interest in exploration for deeply-buried reserves.However,little knowledge has been acquired on the types of microbial carbonates that are present,the properties of the reservoir and the pore evolution,hampering predictions of high-quality reservoirs in these carbonates.Integrated with petrography and in-situ U-Pb dating geochronology analyses,this study aims to clarify the types of microbial carbonates present and to reconstruct the pore evolution processes of the potential reservoir rocks.The Upper Ediacaran microbial carbonates of the Tarim Basin can be divided into four types,based on their features in terms of different scales(macro-to micro-):microbial laminite,stromatolite,spongiomicrobialite and microbial-peloidal wackestone/mudstone.Petrophysical properties show that all these microbial carbonates have low porosity and very low permeability with poor connectivity.These carbonates were subject to long-term and complex diagenetic processes,mainly consisting of dissolution,compaction,pervasive dolomitization,cementation and fracturing.The most important reservoir spaces are contributed by vugs and dissolution-enlarged pores,which are likely to have been associated with the widespread uplift of the Aksu area in the terminal Ediacaran.In contrast,the cementation of the fine-to-medium crystalline dolomite greatly reduced the pre-existing pores.Pore types are closely related to different microbial fabrics,which played an important role in the pore evolution of the microbial carbonates.
基金Supported by National Basic Research Program of China (Grant No.2005CB422101)
文摘The trace element and rare earth element(REE) variations across the Ordovician-Silurian succession are presented from two outcrop sections on the Yangtze Platform:the Nanbazi section,Guizhou Province,deposited in a shallow platform interior setting,and the Wangjiawan section,Hubei Province,deposited in a deeper basinal environment.Geochemical analysis of closely spaced samples through three intervals,the Wufeng,Guanyinqiao and Longmaxi,revealed vast palaeoceanographic changes.Some geochemical proxies,including Th/U,Ni/Co,V/Cr,and V/(V+Ni) ratios,together with sedimentary facies and biotic data,indicate that an anoxic condition on the most of the Yangtze Platform during the Wufeng and Longmaxi intervals,but an oxic condition during the Guanyinqiao time.The shift of the anoxic to the oxic environment during the Guanyinqiao time coincided with a global sea-level lowstand,in parallel with the global glaciation.The Longmaxian anoxic environment was a result of a global sea-level rise,which may be synchronized with a mainly catastrophic event in the latest Ordovician.Although the two sections generally show similar variation patterns of trace and REE concentrations and some element ratios,a minor difference occurs between the Wangjiawan and Nanbazi sections,likely reflecting a difference in depositional setting during the accumulation.Such an oceanic oxygen-level variation may add a useful constraint to the current arguments on the cause and consequence of the latest Ordovician mass extinction.
基金supported by SINOPEC(G5800-07-ZS-WX032)the National Key Scientific Special Program of China(2008ZX05008-003-002 and 2011ZX05008-003-10)+1 种基金the National Basic Research Program of China(2012CB214802)the State Key Laboratory of Oil/Gas Reservoir Geology and Exploitation at CDUT(PL200801)
文摘Detailed characterization of diagenetic fluid behaviour and evolution is commonly hindered by shortage of appropriate and economic methods to carry out in situ analysis in the tiny diagenetic mineral crystals. Using micromill sampling method, this study presents in situ stable isotopic data for the growth zones of saddle dolomite crystals in the hydrothermally-altered dolostones of Upper Cambrian (Furongian) at Keping, Tarim Basin, NW China. These data show minor and large variations in δ13C ( 0.7‰ to 1.5‰ VPDB) and δ18O ( 8.3‰ to 13.8‰ VPDB), respectively, from the cores to outer rims of the dolomite crystals and suggest that saddle dolomites precipitated from dolomitizing fluids with similar carbon sources but oscillatory temperatures during different formation stages. This scenario is confirmed by microthermometry of fluid inclusions within the growth zones of dolomite crystals. This study indicates that in situ isotope analysis could provide more detailed information related to the source and pathway of dolomitizing fluids, facilitating better characterization of dolomitizing fluids and processes.
基金supported by National Natural Science Foundation of China(Grant No. 40839907)
文摘The end-Paleozoic biotic crisis is characterized by two-phase mass extinctions;the first strike,resulting in a large decline of sessile benthos in shallow marine environments,occurred at the end-Guadalupian time.In order to explore the mechanism of organisms' demise,detailed analyses of depositional facies,fossil record,and carbonate carbon isotopic variations were carried out on a Maokou-Wujiaping boundary succession in northwestern Sichuan,SW China.Our data reveal a negative carbon isotopic excursion across the boundary;the gradual excursion with relatively low amplitude(2.15‰) favors a long-term influx of isotopically light 12 C sourced by the Emeishan basalt trap,rather than by rapid releasing of gas hydrate.The temporal coincidence of the beginning of accelerated negative carbon isotopic excursion with onsets of sea-level fall and massive biotic demise suggests a cause-effect link between them.Intensive volcanic activity of the Emeishan trap and sea-level fall could have resulted in detrimental environmental stresses and habitat loss for organisms,particularly for those benthic dwellers,leading to their subsequent massive extinction.
基金supported by Petrochemical Joint Foundation of China (Grant No. U1663209)National Natural Science Foundation of China (Grant No. 41502118)
文摘High-frequency metre-scale cycles are present within the Lower-Middle Ordovician carbonate successions in northern Tarim Basin, NW China. These metre-scale cycles were variably dolomitised from top to bottom. Three types of replacive dolomites were recognised, including dololaminite(very finely to finely crystalline, planar-s to nonplanar-a dolomite;type-1), patterned dolomite(finely crystalline, planar-s dolomite; type-2), and mottled dolomite(finely to medium crystalline,nonplanar-a(s) dolomite; type-3). Petrographic evidence indicate these dolomites were primarily deposited in supratidal to restricted subtidal environments, and formed in near-surface to shallow burial realms. Geochemically, all types of dolomites have similar δ13C and 87Sr/86 Sr ratios comparable to calcite precipitated in equilibrium with the Early-Middle Ordovician seawater. These geochemical attributes indicate that these dolomites were genetically associated and likely formed from connate seawater-derived brines. Of these, type-1 dolomite has δ18O values(.4.97‰ to.4.04‰ VPDB) slightly higher than those of normal seawater dolomite of the Early-Middle Ordovician age. Considering the absence of associated evaporites within type-1 dolomite, its parental fluids were likely represented by slightly evaporated(i.e., mesosaline to penesaline) seawater with salinity below that of gypsum precipitation. More depleted δ18O values(.7.74‰ to.5.20‰ VPDB) of type-2 dolomite and its stratigraphic position below type-1 dolomite indicate the generation of this dolomite from mesosaline to penesaline brines at higher temperatures in near-surface to shallow burial domains. Type-3 dolomite yields the most depleted δ18O values(–9.30‰to –7.28‰ VPDB), pointing to that it was most likely formed from coeval seawater-derived brines at highest temperatures in a shallow burial setting. There is a downward decreasing trend in δ18O values from type-1 through type-2 to type-3 dolomites, and in abundance of dolomites, indicating that the dolomitising fluids probably migrated downward from above and persisted into shallow burial conditions.