The compression and polymorphic phase transitions of iodine have been studied by using x-ray diffraction with a diamond anvil cell at high pressure up to 77GPa.Considering that iodine is reactive with iron in air,a co...The compression and polymorphic phase transitions of iodine have been studied by using x-ray diffraction with a diamond anvil cell at high pressure up to 77GPa.Considering that iodine is reactive with iron in air,a corrosion-resisting and high-strength gasket was put between the diamonds,thus the sample can be mounted at atmospheric pressure and room temperature.Pressure was measured in terms of the ruby fluorescence and the molybdenum diffraction as an internal pressure standard.According to the x-ray diffraction results,the iodine undergoes the following three structural phase transitions with pressure increasing:(1)At 21 GPa,from base centred orthorhombic phase(phase Ⅰ)to body centred orthorhombic phase(phase Ⅱ).A 2%change in volume occurs.(2)At 44 GPa,from phase II to body centred tetragonal phase(phase Ⅲ).This is a second order phase transition.(3)At 71 GPa,from phase III to fcc phase(phase Ⅳ).The volume decreases by 3%.At this time,the volume is 45%of the original one at atmospheric pressure.展开更多
Based on in situ high pressure x-ray diffraction with diamond anvil cell by using synchrotron radiation and pressure-quench x-ray measurement,phase transition of C_(60)under high pressured is studied.The maximum press...Based on in situ high pressure x-ray diffraction with diamond anvil cell by using synchrotron radiation and pressure-quench x-ray measurement,phase transition of C_(60)under high pressured is studied.The maximum pressure used is 30GPa in quasi-hydrostatic case but 44GPa in nonhydrostatic case.At ambient pressure,C_(60)crystal is a fcc phase with lattice parameter a=14.2086Å.It transforms from fcc to a lower symmetry phase at pressure of 13.7GPa,and then transforms to an amorphous state under pressure up to 25-30 GPa.This amorphous state is metastable at normal condition.Finally,the experimental results are discussed.展开更多
The crystal structure stability as well as electric conductance of (Sr/Ca)_2CuO_2Cl_2 compound with K_2NiF_4 structure was investigated up to 31 GPa using diamond anvil technique. It seems that (Sr/Ca)_2CuO_2Cl_2 is q...The crystal structure stability as well as electric conductance of (Sr/Ca)_2CuO_2Cl_2 compound with K_2NiF_4 structure was investigated up to 31 GPa using diamond anvil technique. It seems that (Sr/Ca)_2CuO_2Cl_2 is quite stable under pressure but with obvious anisotropic compressibility. The equation of state (EOS) obtained shows relative large bulk modulus.展开更多
Boron-doped diamond has been synthesized from graphite mixed with different ratio of B 4 C at high pressure high temperature (HPHT) using laser heated diamond anvil cell.The starting composition was transformed to dia...Boron-doped diamond has been synthesized from graphite mixed with different ratio of B 4 C at high pressure high temperature (HPHT) using laser heated diamond anvil cell.The starting composition was transformed to diamond compound at pressure ~9 GPa,2300-2400 K as indicated by the in-situ X-ray diffraction pattern with synchrotron radiation source.Raman spectrum of the recovered specimen from HPHT state confirmed that boron has been doped into diamond lattice.展开更多
基金the National Natural Science Foundation of China。
文摘The compression and polymorphic phase transitions of iodine have been studied by using x-ray diffraction with a diamond anvil cell at high pressure up to 77GPa.Considering that iodine is reactive with iron in air,a corrosion-resisting and high-strength gasket was put between the diamonds,thus the sample can be mounted at atmospheric pressure and room temperature.Pressure was measured in terms of the ruby fluorescence and the molybdenum diffraction as an internal pressure standard.According to the x-ray diffraction results,the iodine undergoes the following three structural phase transitions with pressure increasing:(1)At 21 GPa,from base centred orthorhombic phase(phase Ⅰ)to body centred orthorhombic phase(phase Ⅱ).A 2%change in volume occurs.(2)At 44 GPa,from phase II to body centred tetragonal phase(phase Ⅲ).This is a second order phase transition.(3)At 71 GPa,from phase III to fcc phase(phase Ⅳ).The volume decreases by 3%.At this time,the volume is 45%of the original one at atmospheric pressure.
基金C_(60)sample is provided by LI Yuliang and YAO Youxin,Institute of Chemistry,Academia Sinica.This research is supported by the Beijing Synchrotron Radiation Laboratory,Institute of High Energy Physics,Academia Sinica,and the National Natural Science Foundation of China.
文摘Based on in situ high pressure x-ray diffraction with diamond anvil cell by using synchrotron radiation and pressure-quench x-ray measurement,phase transition of C_(60)under high pressured is studied.The maximum pressure used is 30GPa in quasi-hydrostatic case but 44GPa in nonhydrostatic case.At ambient pressure,C_(60)crystal is a fcc phase with lattice parameter a=14.2086Å.It transforms from fcc to a lower symmetry phase at pressure of 13.7GPa,and then transforms to an amorphous state under pressure up to 25-30 GPa.This amorphous state is metastable at normal condition.Finally,the experimental results are discussed.
基金National Basic Research Program of China (Grant Nos. 2005CB724402, 2006CB601002) National Natural Science Foundation of China (Grant No. 50701048)
文摘The crystal structure stability as well as electric conductance of (Sr/Ca)_2CuO_2Cl_2 compound with K_2NiF_4 structure was investigated up to 31 GPa using diamond anvil technique. It seems that (Sr/Ca)_2CuO_2Cl_2 is quite stable under pressure but with obvious anisotropic compressibility. The equation of state (EOS) obtained shows relative large bulk modulus.
基金supported by the Scientific Research Foundation of China Agricultural University (2009008)Fundamental Research Funds for the Central Universities 2009-2-05the National Natural Science Foundation of China (60776039)
文摘Boron-doped diamond has been synthesized from graphite mixed with different ratio of B 4 C at high pressure high temperature (HPHT) using laser heated diamond anvil cell.The starting composition was transformed to diamond compound at pressure ~9 GPa,2300-2400 K as indicated by the in-situ X-ray diffraction pattern with synchrotron radiation source.Raman spectrum of the recovered specimen from HPHT state confirmed that boron has been doped into diamond lattice.