The Electro-chemistry process to produce Fenton reagents has been described. The in situ oxidation of dyes, acid chrome and alizarin red(Fenton reagents) with electrogenerated hydroxyl radicals was investigated. The \...The Electro-chemistry process to produce Fenton reagents has been described. The in situ oxidation of dyes, acid chrome and alizarin red(Fenton reagents) with electrogenerated hydroxyl radicals was investigated. The \{ I-V \} cyclic voltammograms were measured. The redox peaks of the dyes were not observed in the treated dye solutions instead of a couple of O_2/H_2O_2 redox peaks. The IR results indicate that acid chrome dye was decomposed into naphthylamine and phenol aminophenol sulfonic acid. The degradation and the decolorization of the dyes were comfirmed by the visible spectrum and the chemical analysis. The COD_ cr removing rate was close to 80%.展开更多
文摘海水电池镁阳极腐蚀产生Mg^(2+),与虾池养殖废水中的NH_4^+和P形成鸟粪石,实现资源化利用.研究了磷氮物质的量比、pH值、温度对海水电池发电和鸟粪石结晶的影响.结果表明,海水电池阴极产生OH-使废水pH值稳定在10. 0左右,适合于鸟粪石结晶. 1∶1的磷氮物质的量比可促进鸟粪石结晶,NH_4^+-N和P的回收率分别为38. 12%和98. 78%.在15~35℃范围内,提高温度可以缩短回收时间.实验过程中海水电池可以产生相对稳定的电能,产电量约为21 m W.
基金Supported by the Foundation of Fujian Education Comm ittee(AJ0 0 15 3)
文摘The Electro-chemistry process to produce Fenton reagents has been described. The in situ oxidation of dyes, acid chrome and alizarin red(Fenton reagents) with electrogenerated hydroxyl radicals was investigated. The \{ I-V \} cyclic voltammograms were measured. The redox peaks of the dyes were not observed in the treated dye solutions instead of a couple of O_2/H_2O_2 redox peaks. The IR results indicate that acid chrome dye was decomposed into naphthylamine and phenol aminophenol sulfonic acid. The degradation and the decolorization of the dyes were comfirmed by the visible spectrum and the chemical analysis. The COD_ cr removing rate was close to 80%.