Solid polymer electrolytes(SPEs) have been considered as the spotlight in recent years due to their high safety, non-flammability and good flexibility. Nonetheless, high crystallinity of polymer matrix leads to low io...Solid polymer electrolytes(SPEs) have been considered as the spotlight in recent years due to their high safety, non-flammability and good flexibility. Nonetheless, high crystallinity of polymer matrix leads to low ionic conductivity at ambient conditions and retards the practical applications of SPEs. Herein, we report hybrid solid electrolytes(HSE) containing bulky LATP in poly(ethylene oxide)(PEO) matrix, which significantly enhances the electrochemical properties. LATP has been easily obtained by an accessible solid-state method. The solid electrolyte based on 20 wt% LATP in PEO polymer matrix(abbreviated as PEO-20) exhibits an ionic conductivity of 2.1 ×10-5 S·cm-1 at 30 ℃, an order of magnitude higher than 2.9 × 10-6 S·cm-1 of the pristine PEO solid electrolyte(abbreviated as PEO-0), mainly resulting from the decline of crystallinity in polymer matrix. The electrochemical window of PEO-20 can reach 4.84 V at room temperature, compared with 4.40 V for PEO-0, which could be compatible with high-voltage cathode materials.展开更多
文摘非饱和渗流问题涉及岩土、水利和环境等众多领域,合理有效地模拟非饱和渗流过程具有重要意义。基于数值流形方法(numerical manifold method,NMM)的覆盖思想,建立了非饱和渗流Richards方程的NMM离散格式,相比于有限元方法(finite element method,FEM),NMM的前处理更为灵活,对复杂边界具有更强的适应性。欠松弛技术和集中质量矩阵的引入,有效抑制了求解过程中的数值震荡现象。通过对一维和二维非饱和渗流算例的模拟,验证了算法的有效性与可靠性。
基金the Fujian Provincial Science and Technology Program (No. 2018H0042,2019T3017)Putian Municipal Science and Technology Program (2019HJSTS009)the DNL Cooperation Fund,CAS (DNL180308)。
文摘Solid polymer electrolytes(SPEs) have been considered as the spotlight in recent years due to their high safety, non-flammability and good flexibility. Nonetheless, high crystallinity of polymer matrix leads to low ionic conductivity at ambient conditions and retards the practical applications of SPEs. Herein, we report hybrid solid electrolytes(HSE) containing bulky LATP in poly(ethylene oxide)(PEO) matrix, which significantly enhances the electrochemical properties. LATP has been easily obtained by an accessible solid-state method. The solid electrolyte based on 20 wt% LATP in PEO polymer matrix(abbreviated as PEO-20) exhibits an ionic conductivity of 2.1 ×10-5 S·cm-1 at 30 ℃, an order of magnitude higher than 2.9 × 10-6 S·cm-1 of the pristine PEO solid electrolyte(abbreviated as PEO-0), mainly resulting from the decline of crystallinity in polymer matrix. The electrochemical window of PEO-20 can reach 4.84 V at room temperature, compared with 4.40 V for PEO-0, which could be compatible with high-voltage cathode materials.
