Zirconium-based metal-organic framework UiO-66 was successfully prepared by solvothermal method,and UiO-66 was modified by adding regulators such as formic acid,acetic acid,and hydrochloric acid.The NH_(3)-SCR reactiv...Zirconium-based metal-organic framework UiO-66 was successfully prepared by solvothermal method,and UiO-66 was modified by adding regulators such as formic acid,acetic acid,and hydrochloric acid.The NH_(3)-SCR reactivity of the samples was evaluated by the denitration activity evaluation system,and the UiO-66 and the regulator-modified UiO-66 were characterized by XRD,SEM,BET,FTIR,TG,NH_(3)-TPD,etc.,the effects of regulator types on the structure and properties of UiO-66 were investigated.The experimental results show that,after adding the modifier,the morphology of UiO-66 changes from irregular quadrilateral with serious agglomeration to particles with regular crystal shape and good dispersibility,and the crystal morphology of the catalyst is improved.In addition,after adding the modifier,UiO-66 has a larger specific surface area and stronger surface acidity,which optimizes the catalytic performance of UiO-66.The catalytic performance test results of NH_(3)-SCR show that the low-temperature activity of UiO-66 is poor,and it only shows a certain catalytic activity at higher temperatures.The catalytic activity of UiO-66 was significantly improved after adding the regulator.Among them,the UiO-66-HCl modified with hydrochloric acid had the best catalytic activity,and the denitration rate reached 70%when the denitration temperature was 380℃.展开更多
针对卡方自动交互诊断(CHAID)决策树易过拟合的问题,提出CHAID随机森林方法(CHAID Random Forest,CHAID-RF)。该方法采用随机采样、随机选择特征以及集成的策略,将CHAID决策树作为基分类器,形成CHAID-RF。为了验证CHAID-RF的有效性,选取...针对卡方自动交互诊断(CHAID)决策树易过拟合的问题,提出CHAID随机森林方法(CHAID Random Forest,CHAID-RF)。该方法采用随机采样、随机选择特征以及集成的策略,将CHAID决策树作为基分类器,形成CHAID-RF。为了验证CHAID-RF的有效性,选取CART、CHAID、SVM、RF作为对比算法,以准确率、加权查准率、加权查全率、加权F值作为分类模型评价指标,以均方根误差作为回归模型评价指标,采用10个分类数据集和7个回归数据集进行验证。实验结果表明CHAID-RF可行有效。展开更多
基金Funded by the National Key Research and Development Program of China(No.2016YFC0209302)。
文摘Zirconium-based metal-organic framework UiO-66 was successfully prepared by solvothermal method,and UiO-66 was modified by adding regulators such as formic acid,acetic acid,and hydrochloric acid.The NH_(3)-SCR reactivity of the samples was evaluated by the denitration activity evaluation system,and the UiO-66 and the regulator-modified UiO-66 were characterized by XRD,SEM,BET,FTIR,TG,NH_(3)-TPD,etc.,the effects of regulator types on the structure and properties of UiO-66 were investigated.The experimental results show that,after adding the modifier,the morphology of UiO-66 changes from irregular quadrilateral with serious agglomeration to particles with regular crystal shape and good dispersibility,and the crystal morphology of the catalyst is improved.In addition,after adding the modifier,UiO-66 has a larger specific surface area and stronger surface acidity,which optimizes the catalytic performance of UiO-66.The catalytic performance test results of NH_(3)-SCR show that the low-temperature activity of UiO-66 is poor,and it only shows a certain catalytic activity at higher temperatures.The catalytic activity of UiO-66 was significantly improved after adding the regulator.Among them,the UiO-66-HCl modified with hydrochloric acid had the best catalytic activity,and the denitration rate reached 70%when the denitration temperature was 380℃.
文摘针对卡方自动交互诊断(CHAID)决策树易过拟合的问题,提出CHAID随机森林方法(CHAID Random Forest,CHAID-RF)。该方法采用随机采样、随机选择特征以及集成的策略,将CHAID决策树作为基分类器,形成CHAID-RF。为了验证CHAID-RF的有效性,选取CART、CHAID、SVM、RF作为对比算法,以准确率、加权查准率、加权查全率、加权F值作为分类模型评价指标,以均方根误差作为回归模型评价指标,采用10个分类数据集和7个回归数据集进行验证。实验结果表明CHAID-RF可行有效。
