The previous methods of figuring the numbers of chemical elements is summed up in this paper. Based on that, another two creative calculative methods are introduced as well.
A novel polyoxovanadate-based MOFs microsphere,[Ni(phen)V2O7]·H2O(phen=1,10-phenanthroline),constructed from 3-D discrete nano-sheets has been prepared and characterized by XRD,FT-IR,SEM and TEM.Electrochemical p...A novel polyoxovanadate-based MOFs microsphere,[Ni(phen)V2O7]·H2O(phen=1,10-phenanthroline),constructed from 3-D discrete nano-sheets has been prepared and characterized by XRD,FT-IR,SEM and TEM.Electrochemical properties as supercapacitor of the as-prepared sample,such as CV,EIS,GCD and the cycle life test have also been studied.The as-prepared MOF(V,Ni)showed a high specific capacitance of 178.09 F×g^(-1) at 1 A×g^(-1) as well as good cycling stability and coulombic efficiency.This work proved that the novel MOFs based on polyoxovanadate hybrid material may serve as a promising electrode material for high-performance supercapacitor.展开更多
In this study,S-doped g-C_(3)N_(4)nanoparticles were successfully prepared by one-step solid-state microwave synthesis.The detailed characterizations through XRD,FT-IR,SEM and XPS were studied.In addition,the electroc...In this study,S-doped g-C_(3)N_(4)nanoparticles were successfully prepared by one-step solid-state microwave synthesis.The detailed characterizations through XRD,FT-IR,SEM and XPS were studied.In addition,the electrochemical properties as supercapacitor of the sample were tested by cyclic voltammetry(CV),galvanostatic charge-discharge(GCD)and electrochemical impedance spectroscopy(EIS)techniques.The results showed a high specific capacitance of 691 F/g at current density of 4 A/g in 2 M KOH+0.15 M K3[Fe(CN)_(6)]electrolyte.This study shows that the microwave synthesis is a promising way to design carbon-based electrodes for supercapacitor.展开更多
Nanometer blocks of amide-functionalized Fe(Ⅲ)-based metal-organic frameworks,NH2-MIL-53(Fe),were prepared via ultrasonic method without any surfactants at room temperature and atmospheric pressure.The characterizati...Nanometer blocks of amide-functionalized Fe(Ⅲ)-based metal-organic frameworks,NH2-MIL-53(Fe),were prepared via ultrasonic method without any surfactants at room temperature and atmospheric pressure.The characterization for the as-prepared nano-structured MOFs was established by XRD,SEM,TEM,XPS and N2 adsorption-desorption.The as-prepared sample with high specific surface area(179.9 m^(2)·g^(-1))showed excellent adsorption for methylene blue in the liquid phase.The as-prepared NH_(2)-MIL-53(Fe)adsorbent seems to be a promising material in practice for organic dye removal from aqueous solution.展开更多
基金This work is supported by the National Science Foundation of China （No. 20471001 and 20671001）, the Important Project of Anhui Provincial Education Department （No. ZD2007004-1）, the Specific Project for Talents of Science and Technology of Universities of Anhui Province （No. 2005hbz03） and the Key Laboratory of Environment-friendly Polymer Materials of Anhui Province.
文摘The previous methods of figuring the numbers of chemical elements is summed up in this paper. Based on that, another two creative calculative methods are introduced as well.
基金supported by the Natural Science Foundation of Fujian Province(No.2020J01803)Fujian Provincial Key Laboratory of Featured Materials in Biochemical Industry(FJKL_FBCM202004)the Fujian Provincial Key Laboratory of Ecotoxicological Effects and Control of New Pollutants(PY19001)。
文摘A novel polyoxovanadate-based MOFs microsphere,[Ni(phen)V2O7]·H2O(phen=1,10-phenanthroline),constructed from 3-D discrete nano-sheets has been prepared and characterized by XRD,FT-IR,SEM and TEM.Electrochemical properties as supercapacitor of the as-prepared sample,such as CV,EIS,GCD and the cycle life test have also been studied.The as-prepared MOF(V,Ni)showed a high specific capacitance of 178.09 F×g^(-1) at 1 A×g^(-1) as well as good cycling stability and coulombic efficiency.This work proved that the novel MOFs based on polyoxovanadate hybrid material may serve as a promising electrode material for high-performance supercapacitor.
基金the Natural Science Foundation of Fujian Province(No.2020J01803)Fujian Provincial Key Laboratory of Featured Materials in Biochemical Industry(FJKL_FBCM202004)the Fujian Provincial Key Laboratory of Ecotoxicological Effects and Control of New pollutants(PY19001)。
文摘In this study,S-doped g-C_(3)N_(4)nanoparticles were successfully prepared by one-step solid-state microwave synthesis.The detailed characterizations through XRD,FT-IR,SEM and XPS were studied.In addition,the electrochemical properties as supercapacitor of the sample were tested by cyclic voltammetry(CV),galvanostatic charge-discharge(GCD)and electrochemical impedance spectroscopy(EIS)techniques.The results showed a high specific capacitance of 691 F/g at current density of 4 A/g in 2 M KOH+0.15 M K3[Fe(CN)_(6)]electrolyte.This study shows that the microwave synthesis is a promising way to design carbon-based electrodes for supercapacitor.
基金Supported by the Fujian Provincial Key Laboratory of ecotoxicological effects and Control of New pollutants(PY19001)the Innovation and Entrepreneurship training Program for College students in 2019(201910402063)。
文摘Nanometer blocks of amide-functionalized Fe(Ⅲ)-based metal-organic frameworks,NH2-MIL-53(Fe),were prepared via ultrasonic method without any surfactants at room temperature and atmospheric pressure.The characterization for the as-prepared nano-structured MOFs was established by XRD,SEM,TEM,XPS and N2 adsorption-desorption.The as-prepared sample with high specific surface area(179.9 m^(2)·g^(-1))showed excellent adsorption for methylene blue in the liquid phase.The as-prepared NH_(2)-MIL-53(Fe)adsorbent seems to be a promising material in practice for organic dye removal from aqueous solution.
