基于输运床的内在碳捕集气化制氢反应器操作条件研究

针对固定床或鼓泡流化床反应器的内在碳捕集气化过程中气固混合程度差的问题,本文将输运床作为内在碳捕集气化制氢反应器,建立了考虑流体动力学及反应动力学的反应器动力学模型,研究了水碳比、操作温度及操作压力对反应器运行可行性及性能的影响。结果表明,以输运床小试装置为基准,当反应器操作压力为900 kPa、反应器温度为800℃、进口水碳比为2时,反应器内碳转化率可达60%,出口气体产物(干气)中氢气的摩尔分数可达到82%。研究结果证实了基于输运床的内在碳捕集气化反应器的可行性及其在提高反应性能上的优势,指出了操作条件范围,可为内在碳捕集气化制氢技术的研究提供参考。

Thermodynamic Performance Analysis of E/F/H-Class Gas Turbine Combined Cycle with Exhaust Gas Recirculation and Inlet/Variable Guide Vane Adjustment under Part-Load Conditions

Exhaust gas recirculation control(EGRC),an inlet air heating technology,can be utilized in combination with inlet/variable guide vane control(IGV/VGVC) and fuel flow control(FFC) to regulate the load,thereby effectively improving the part-load(i.e.,off-design) performance of the gas turbine combined cycle(GTCC).In this study,the E-,F-,and H-Class EGR-GTCC design and off-design system models were established and validated to perform a comparative analysis of the part-load performance under the EGR-IGV-FFC and conventional IGV-FFC strategies in the E/F/H-Class GTCC.Results show that EGR-IGV-FFC has considerable potential for the part-load performance enhancement and can show a higher combined cycle efficiency than IGV-FFC in the E-,F-,and H-Class GTCCs.However,the part-load performance improvement in the corresponding GTCC was weakened for the higher class of the gas turbine because of the narrower load range of EGR action and the deterioration of the gas turbine performance.Furthermore,EGR-IGV-FFC was inferior to IGV-FFC in improving the performance at loads below 50% for the H-Class GTCC.The results obtained in this paper could help guide the application of EGR-IGV-FFC to enhance the part-load performance of various classes of GTCC systems.

Off-Design Performance of 9F Gas Turbine Based on gPROMs and BP Neural Network Model

Gas turbines are increasingly and widely used,whose research and production reflect a country’s industrial capacity and level.Due to the changeable working environment,gas turbines usually work under the condition of simultaneous changes of ambient temperature,load and fuel.However,the current researches mainly focus on the change in single condition,and do not fully consider the simultaneous change in different conditions.On the basis of single condition,this paper further studies the dual off-design performance of gas turbines under three conditions:temperature-load,fuel-load and fuel-temperature.Firstly,the whole machine model of a gas turbine is established,in which the compressor model has the greatest impact on the performance of gas turbines.Therefore,this paper obtains a more accurate compressor model by combining the engineering modeling advantages of gPROMs and the powerful mathematical calculation ability of MATLAB neural network.Then,according to the established gas turbine model,the dual off-design performance is studied,which is mainly based on the parameter of output and efficiency.The result shows that the efficiency and power output of gas turbines will decrease with the increase of ambient temperature.With the decrease of fuel calorific value,power output and efficiency will increase.As the load decreases,the efficiency of the gas turbines will decrease,and these changes are consistent with the single off-design performance.However,when the fuel and temperature change simultaneously,only adjusting the IGV angle cannot avoid the surge when the temperature is above 30°C.At this time,it is necessary to adjust the extraction rate in order to ensure the safe and stable operation of gas turbines.Therefore,the research on dual off-design performance of gas turbines has an important significance for the peak shaving operation of gas turbines.