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304不锈钢绿色化学机械抛光 被引量:3
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作者 张仁杰 张振宇 +3 位作者 李玉彪 徐光宏 崔祥祥 刘杰 《表面技术》 EI CAS CSCD 北大核心 2022年第5期325-335,共11页
目的采用对环境友好的抛光工艺来改善304不锈钢表面抛光质量。方法基于化学机械抛光(CMP)工艺,采用主要成分为氧化铝(Al_(2)O_(3))磨料、L-苹果酸、过氧化氢(H_(2)O_(2))、乳化剂OP-10、甘氨酸的绿色环保抛光液,设计并试验了pH值,H_(2)O... 目的采用对环境友好的抛光工艺来改善304不锈钢表面抛光质量。方法基于化学机械抛光(CMP)工艺,采用主要成分为氧化铝(Al_(2)O_(3))磨料、L-苹果酸、过氧化氢(H_(2)O_(2))、乳化剂OP-10、甘氨酸的绿色环保抛光液,设计并试验了pH值,H_(2)O_(2)、乳化剂OP-10、甘氨酸质量分数的4因素4水平CMP正交试验。采用极差法分析了4个因素对表面粗糙度和材料去除率的影响。采用电化学工作站,通过动电位极化曲线法,分析304不锈钢在不同抛光液环境下的静态腐蚀特性。通过X射线光电子能谱(XPS),分析304不锈钢在不同抛光液环境下的表面元素和化学组分变化。结果开发了一种不含任何强酸、强碱等危化物品的新型环保化学机械抛光液。通过绿色CMP加工,在70μm×50μm范围内将304不锈钢平均表面粗糙度从CMP前的7.972 nm降至0.543 nm。与之前报道的304不锈钢抛光相比,绿色CMP抛光后的表面粗糙度最低。通过正交试验,得到了绿色CMP加工的最优抛光液参数:pH=3,0.3%H_(2)O_(2),0.3%乳化剂OP-10,1.5%甘氨酸。结论L-苹果酸与甘氨酸之间相互促进,使抛光液的腐蚀性增强;而H_(2)O_(2)的作用则相反,可使抛光液的氧化性增强,减缓抛光液对304不锈钢表面的腐蚀。 展开更多
关键词 304不锈钢 化学机械抛光 绿色环保 正交试验 化学反应机理 表面粗糙度
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130例系统性硬化病患者肺动脉高压的检测及其高危因素分析 被引量:1
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作者 崔祥祥 杨骥 +1 位作者 屠文震 李明 《临床皮肤科杂志》 CAS CSCD 北大核心 2022年第4期204-207,共4页
目的:分析系统性硬化病(SSc)并发肺动脉高压(pulmonary arterial hypertension,PAH)(SSc-PAH)患者的高危因素。方法:收集2012—2016年复旦大学附属中山医院皮肤科及上海市中西医结合医院硬皮病专科确诊的130例SSc患者,按其有无PAH分为SS... 目的:分析系统性硬化病(SSc)并发肺动脉高压(pulmonary arterial hypertension,PAH)(SSc-PAH)患者的高危因素。方法:收集2012—2016年复旦大学附属中山医院皮肤科及上海市中西医结合医院硬皮病专科确诊的130例SSc患者,按其有无PAH分为SSc-PAH组和SSc无PAH(SSc-no PAH)组,并对这两组患者的临床特征进行分析。将弥漫型系统性硬化病并发肺动脉高压(dcSSc-PAH)组和弥漫型系统性硬化病无肺动脉高压(dcSSc-no PAH)组按病程各分为两组(A组<3年,B组≥3年)。局限型系统性硬化病并发肺动脉高压(lcSSc-PAH)组和局限型系统性硬化病无肺动脉高压(lcSSc-no PAH)组按病程各分为2组(C组<5年,D组≥5年),分别统计PAH在各组中的发生率。结果:130例SSc患者中,SSc-PAH 27例(20.8%)。27例SSc-PAH患者皮肤损害发生率依次为:雷诺现象26例(96.3%);手指硬化24例(88.9%);手指肿胀19例(70.4%);皮肤异色症19例(70.4%);毛细血管扩张16例(59.3%);面具貌13例(48.1%);指尖凹陷6例(22.2%);指腹萎缩5例(18.5%);指尖溃疡2例(7.4%)。确诊SSc-PAH时发生雷诺现象的时间为(5.41±7.68)年。DcSSc-PAH在A组和B组的发生率分别为46.2%和53.8%,lcSSc-PAH在C组和D组的发生率分别为58.3%和41.7%。DcSSc-PAH在A组和B组的发生率和lcSSc-PAH在C组和D组的发生率差异均无统计学意义。27例SSc-PAH患者中,抗DNA拓扑异构酶Ⅰ(SCL-70)抗体阳性6例(22.2%);抗着丝点抗体(ACA)阳性12例(44.4%);抗干燥综合征A(SSA)抗体阳性9例(33.3%);抗干燥综合征B(SSB)抗体阳性3例(11.1%)。27例SSc-PAH患者中器官累及发生率依次为心脏累及14例(51.9%);肺间质纤维化12例(44.4%);关节累及9例(33.3%);吞咽困难8例(29.6%);肾脏7例(25.9%)。SSc-PAH组ACA阳性率高于SSc-no PAH组(χ^(2)=5.317,P<0.05)。SSc-PAH组心脏累及与肾脏累及发生率高于SSc-no PAH组(χ^(2)值分别为13.623、6.911,P均<0.01)。结论:SSc患者雷诺现象发生(5.41±7.68)年后易出现PAH。PAH在SSc早期就会出现,因此早期筛查SSc是否并发PAH,以便及早治疗PAH有助于SSc的预后。ACA阳性的SSc患者PAH发生率高,SSc患者发生PAH的同时,常伴有心脏累及和肾脏累及。 展开更多
关键词 硬皮病 系统性 高血压 肺性 皮肤表现 自身抗体 器官累及
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Distribution and migration of lead in soil of Xiao River, Shijiazhuang, Hebei Province
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作者 cui xiang-xiang FEI Yu-hong +1 位作者 ZHANG Zhao-ji LI Ya-song 《Journal of Groundwater Science and Engineering》 2015年第1期98-104,共7页
The Xiao River sewage irrigation area in Luancheng where wastewater from Shijiazhuang flows through was taken as the research area. Five groundwater monitoring wells were set perpendicular to Xiao River, the research ... The Xiao River sewage irrigation area in Luancheng where wastewater from Shijiazhuang flows through was taken as the research area. Five groundwater monitoring wells were set perpendicular to Xiao River, the research reveals the migration law and distribution characteristics of poisonous metal lead, through collecting and analyzing soil samples at different depths, investigating lithologic structure and pollution. The result shows that soil type has great impact on vertical lead distribution in aeration zone, which means that lead concentrates more in clay than in sand. Lead migrates fast in silty soil and silty clay, but slow in sand. The content of lead soil adsorbed decreases with grain size increasing. The most important factor influencing the distribution of lead is the soil type. 展开更多
关键词 Sewage irrigation SOIL LEAD Vertical migration
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Research on numerical simulation of the groundwater funnels restoration in Shijiazhuang
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作者 GUO Chun-yan cui Ya-li +2 位作者 LIU Wen-na cui xiang-xiang FEI Yu-hong 《Journal of Groundwater Science and Engineering》 2018年第2期126-135,共10页
In order to simulate the recovery of groundwater funnels under the condition of reducing groundwater abstraction, hydrogeological conditions of recoverability construction of Shijiazhuang groundwater funnel were analy... In order to simulate the recovery of groundwater funnels under the condition of reducing groundwater abstraction, hydrogeological conditions of recoverability construction of Shijiazhuang groundwater funnel were analyzed, and a numerical simulation method was used based on the change of various parameters. The results show that the groundwater flow model can accurately reflect groundwater hydrogeological characteristics, and can guarantee the reliability of groundwater restoration prediction. The research has set up four schemes for rural water-saving, planting structure adjustment, urban reducing abstraction and integrated method. The effect of four restoration schemes on the restoration of groundwater funnels was compared with water table variations of two observation well. Comparison results show that the level changes of plan Three and Four are different from the other two kinds of exploitation and the drop trend of water table in the funnel area is flat. So we can conclude that Plan Three and Four have significant effect on the groundwater funnel restoration of Shijiazhuang. 展开更多
关键词 Shijiazhuang Reducing groundwater abstraction Groundwater funnel Numeric simulation Restoration scheme
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