Objective The tectonic characteristics and evolution of the Paleoproterozoic Jiao-Liao-Ji belt have been extensively studied in recent decades （Fig. 1 a）. Two main models have been proposed for the formation of this...Objective The tectonic characteristics and evolution of the Paleoproterozoic Jiao-Liao-Ji belt have been extensively studied in recent decades （Fig. 1 a）. Two main models have been proposed for the formation of this belt： a continental-or arc-continent collisional belt, and the opening and closure of an intra-continental rift. The main reasons for these ongoing debates are own to the complex composition, including metamorphosed volcano-sedimentary rocks, multiple pulses of granitic magmatism, meta-mafic intrusions, and tectono- metamorphic history. In addition, earlier work focused on the geochronology and metamorphic evolution, whereas the source properties, petrogenesis, and tectonic setting of the metamorphosed volcano-sedimentary sequence and meta- mafic intrusions are poorly understood.展开更多
Chitin is a widely used important industrial polymer mainly from shrimp shells, but its commercial preparation is under the great challenge of serious pollution due to the requirement of HCl and Na OH.Herein, we demon...Chitin is a widely used important industrial polymer mainly from shrimp shells, but its commercial preparation is under the great challenge of serious pollution due to the requirement of HCl and Na OH.Herein, we demonstrated that high purity chitin can be obtained from waste shrimp shells(WSSs) by cascade separation with transition metal salt aqueous solution and ionic liquid(IL). Firstly, calcium carbonate of WSSs was effectively removed in the metal salt aqueous solution driven by the ion exchange interaction. Subsequently, 1-butyl-3-methylimidazolium chloride([Bmim]Cl) had bifunctional abilities to remove residual protein and introduced metal salts simultaneously by hydrogen bonding and coordination interactions. The key experimental factors affecting the separation process were systematically studied, including the type of metal salts, temperature, and [Bmim]Cl loading. After sequential treatment with a 20%(mass) Ni SO4aqueous solution at 130 ℃ and [Bmim]Cl at 150 ℃, the purity of a-chitin can be up to 96.5%(mass) that meets commercial requirements. The use of metal salts with higher coordination ability makes the preparation of chitin no longer depend on the commonly acid-base reaction, which is conducive to the preservation of chitin structure.展开更多
基金supported by the National Science Foundation of China(grants No.41572169 and 41202136)China Geological Survey(grant No. 12120114021601)the Outlay Research Fund of the Institute of Geology,CAGS(grants No.J1507 and J1301)
文摘Objective The tectonic characteristics and evolution of the Paleoproterozoic Jiao-Liao-Ji belt have been extensively studied in recent decades （Fig. 1 a）. Two main models have been proposed for the formation of this belt： a continental-or arc-continent collisional belt, and the opening and closure of an intra-continental rift. The main reasons for these ongoing debates are own to the complex composition, including metamorphosed volcano-sedimentary rocks, multiple pulses of granitic magmatism, meta-mafic intrusions, and tectono- metamorphic history. In addition, earlier work focused on the geochronology and metamorphic evolution, whereas the source properties, petrogenesis, and tectonic setting of the metamorphosed volcano-sedimentary sequence and meta- mafic intrusions are poorly understood.
基金support of the Startup Foundation of China(3160011181808)the National Natural Scientific Foundation of China(21878292,81673400)K.C.Wong Education Foundation(GJTD-2018-04).
文摘Chitin is a widely used important industrial polymer mainly from shrimp shells, but its commercial preparation is under the great challenge of serious pollution due to the requirement of HCl and Na OH.Herein, we demonstrated that high purity chitin can be obtained from waste shrimp shells(WSSs) by cascade separation with transition metal salt aqueous solution and ionic liquid(IL). Firstly, calcium carbonate of WSSs was effectively removed in the metal salt aqueous solution driven by the ion exchange interaction. Subsequently, 1-butyl-3-methylimidazolium chloride([Bmim]Cl) had bifunctional abilities to remove residual protein and introduced metal salts simultaneously by hydrogen bonding and coordination interactions. The key experimental factors affecting the separation process were systematically studied, including the type of metal salts, temperature, and [Bmim]Cl loading. After sequential treatment with a 20%(mass) Ni SO4aqueous solution at 130 ℃ and [Bmim]Cl at 150 ℃, the purity of a-chitin can be up to 96.5%(mass) that meets commercial requirements. The use of metal salts with higher coordination ability makes the preparation of chitin no longer depend on the commonly acid-base reaction, which is conducive to the preservation of chitin structure.
