Research of synthesis and neural network training on double quantum dot colorimetric fluorescent probe for freshness detection

There are many disadvantages such as small detection range and environmental restrictions on application conditions,when the single quantum dot powder or solution is used for fluorescent probe detection.In this paper,the blue fluorescent silicon quantum dots and green fluorescent carbon quantum dots were prepared,and their fluorescence color changes after mixing in different proportions were investigated under different pH conditions.When the two quantum dots were mixed with a concentration of 0.1 mg·mL^(-1) and a mass ratio of 1:1,the fluorescence color change could be better displayed at a pH from 1 to 14.Meanwhile,the double quantum dots were prepared into two forms(ink and film),successfully realizing the device application of the fluorescent probe.The films and inkjet-printed labels were used to test the spoilage of food(pork,milk,etc.),and the color change data of the labels were collected during the spoilage test.These data were used for neural network training to predict the spoilage changes of foods.

Effect of different acid anions on highly efficient Ce-based catalysts for selective catalytic reduction of NO with NH_(3)

Three kinds of Ce-based catalysts(CePO_(4),CeVO_(4),Ce_(2)(SO_(4))_(3))were synthesized and used for the selective catalytic reduction(SCR)of NO by NH_(3).NH_(3)-SCR performances were conducted in the temperature range of 80 to 400°C.The catalytic efficiencies of the three catalysts are as follow:CePO_(4)>CeVO_(4)>Ce_(2)(SO_(4))_(3),which is in agreement with their abilities of NH_(3)adsorption capacities.The highest NO conversion rate of CePO_(4)could reach about 95%,and the catalyst had more than 90%NO conversion rate between 260 and 320°C.The effect of PO_(4)^(3–),VO_(4)^(3–)and SO_(4)^(2–)on NH_(3)-SCR performances of Ce-based catalysts was systematically investigated by the X-ray photoelectron spectroscopy analysis,NH_(3)temperature programmed desorption,H2 temperature programmed reduction and field emission scanning electron microscopy tests.The key factors that can enhance the SCR are the existence of Ce4+,large NH_(3)adsorption capacity,high and early H2 consumptions,and suitable microstructures for gas adsorption.Finally,CePO_(4)and CeVO_(4)catalysts also exhibited relatively strong tolerance of SO2,and the upward trend about 8%was detected due to the sulfation enhancement by SO2 for Ce_(2)(SO_(4))3.