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Three-dimensional stochastic seepage field for embankment engineering
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作者 Ya-jun WANG Wo-hua ZHANG +1 位作者 chang-yu wu Da-chun REN 《Water Science and Engineering》 EI CAS 2009年第1期58-73,共16页
Owing to the complexity of geo-engineering seepage problems influenced by different random factors, three-dimensional simulation and analysis of the stochastic seepage field plays an important role in engineering appl... Owing to the complexity of geo-engineering seepage problems influenced by different random factors, three-dimensional simulation and analysis of the stochastic seepage field plays an important role in engineering applications. A three-dimensional anisotropic heterogeneous steady random seepage model was developed on the basis of the finite element method. A statistical analysis of the distribution characteristics of soil parameters sampled from the main embankment of the Yangtze River in the Southern Jingzhou zone of China was conducted. The Kolomogorov-Smirnov test verified the statistical hypothesis that the permeability coefficient tensor has a Gaussian distribution. With the help of numerical analysis of the stochastic seepage field using the developed model, various statistical and random characteristics of the stochastic seepage field of the main embankment of the Yangtze River in the Southern Jingzhou zone of China were investigated. The model was also examined with statistical testing. Through the introduction of random variation of the upstream and downstream water levels into the model, the effects of the boundary randomness due to variation of the downstream and upstream water levels on the variation of simulated results presented with a vector series of the random seepage field were analyzed. Furthermore, the combined influence of the variation of the soil permeability coefficient and such seepage resistance measures as the cut-off wall and relief ditch on the hydraulic head distribution was analyzed and compared with the results obtained by determinate analysis. Meanwhile, sensitivities of the hydraulic gradient and downstream exit height to the variation of boundary water level were studied. The validity of the simulated results was verified by stochastic testing and measured data. The developed model provides more detail and a full stochastic algorithm to characterize and analyze three-dimensional stochastic seepage field problems. 展开更多
关键词 anisotropic random seepage field three-dimensional seepage finite element method Monte Carlo simulation inhomogeneous permeability coefficient stochastic disturbance of hydraulic head boundary
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铈基催化剂催化氧化燃煤烟气中汞的实验及机理研究 被引量:5
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作者 李海龙 张军营 +3 位作者 赵永椿 李立清 郑楚光 chang-yu wu 《工程热物理学报》 EI CAS CSCD 北大核心 2012年第7期1251-1254,共4页
采用超声波增强的浸渍法合成了CeO_2-TiO_2催化剂,并采用BET,XRD,XPS等分析手段对催化剂进行了表征。利用固定床反应器,在模拟燃煤烟气条件下研究了CeO_2-TiO_2催化剂对单质汞的催化氧化行为及机理。结果表明:CeO_2-TiO_2催化剂在低温范... 采用超声波增强的浸渍法合成了CeO_2-TiO_2催化剂,并采用BET,XRD,XPS等分析手段对催化剂进行了表征。利用固定床反应器,在模拟燃煤烟气条件下研究了CeO_2-TiO_2催化剂对单质汞的催化氧化行为及机理。结果表明:CeO_2-TiO_2催化剂在低温范围(150~250°)具有很强的催化氧化汞的能力;最佳的CeO_2/TiO_2质量比在1.5左右,此时汞的氧化效率可高达90%以上;P25,Evonik TiO_2比锐钛矿TiO_2更适合做铈基催化剂载体;CeO_2-TiO_2催化剂上汞的催化氧化符合Langmuir-Hinshelwood机理,即吸附态的汞与其邻近的活性物质反应生成氧化态汞。 展开更多
关键词 催化剂 燃煤烟气 CeO_2 煤燃烧
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SO2对CeO2-TiO2催化剂上汞氧化的双面影响研究 被引量:1
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作者 李海龙 王晓刚 +3 位作者 chang-yu wu 李立清 赵永椿 张军营 《工程热物理学报》 EI CAS CSCD 北大核心 2013年第9期1775-1778,共4页
采用超声波增强的浸渍法合成了组成优化的CeO_2-TiO_2(CeTi)催化剂。在200℃,模拟烟气条件下研究了SO_2对CeTi催化剂上单质汞(Hg^0)催化氧化的影响。结果表明:纯N_2条件下,SO_2抑制了CeTi催化剂上Hg^0的氧化;有O_2条件下SO_2既可以促进H... 采用超声波增强的浸渍法合成了组成优化的CeO_2-TiO_2(CeTi)催化剂。在200℃,模拟烟气条件下研究了SO_2对CeTi催化剂上单质汞(Hg^0)催化氧化的影响。结果表明:纯N_2条件下,SO_2抑制了CeTi催化剂上Hg^0的氧化;有O_2条件下SO_2既可以促进Hg^0的氧化,也可以抑制Hg^0的氧化,取决于烟气中SO_2的浓度。低浓度的SO_2在O_2的协助下可以促进Hg^0的氧化,而高浓度的SO_2抑制了Hg^0的氧化。实验条件下,SO_2本身不具有氧化Hg^0的能力,其对Hg^0氧化的促进作用源于其在CeTi催化剂表面反应生成的SO_3等活性物质。SO_2对Hg^0氧化的抑制作用归因于SO_2与Hg^0间的竞争吸附,SO_2抑制了Hg^0的吸附从而抑制了Hg^0的进一步氧化。 展开更多
关键词 SO2 CEO2 催化剂 煤燃烧
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Microbial aerosol characteristics in highly polluted and nearpristine environments featuring different climatic conditions 被引量:12
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作者 Kai Wei Yunhao Zheng +6 位作者 Jing Li Fangxia Shen Zhuanglei Zou Hanqing Fan Xinyue Li chang-yu wu Maosheng Yao 《Science Bulletin》 SCIE EI CAS CSCD 2015年第16期1439-1447,共9页
There is an increasing interest in understanding ambient bioaerosols due to their roles both in health and in climate. Here, we deployed an Ultraviolet Aerodynamic Particle Sizer to monitor viable (fluorescent) bioa... There is an increasing interest in understanding ambient bioaerosols due to their roles both in health and in climate. Here, we deployed an Ultraviolet Aerodynamic Particle Sizer to monitor viable (fluorescent) bioaerosol concentration levels at city centers (highly polluted) and their corresponding suburbs (near pristine) (total 40 locations) in 11 provinces featuring different climate zones in China between July 16 and 28, 2013. The concentration levels of viable bioaerosol particles (BioPM) of 〉0.5 μm were measured, and corresponding percentages of BioPM% (biological fraction of total PM) and BioPM2.5% (biological fraction of PM2.5) in particulate matter (PM) and BioPM, respectively, were determined. For some key cities, indoor viable bioaerosol levels were also obtained. In addition, bacterial structures of the air samples collected across these monitoring locations were studied using pyrosequencing. BioPM concentration levels ranged from 2.1 ×10^4 to 2.4 × 10^5/m3 for city centers [BioPM% = 6.4 % (4-6.3 %)] and 0.5 × 10^4 to 4.7 × 10^5/m3 for suburbs [BioPM% = 10 % (4-8.7 %)]. Distinctive bioaerosol size distribution patterns were observed for different climate zones, e.g., some had fluorescence peaks at 3 μm, while the majority had peaks at 1 μm. Ambient bacterial aerosol community structures were also found different for different geophysical locations. Results suggest that there was a poor overall relationship between PM and BioPM across 40 monitoring locations (R2= 0.081, two-tailed P value = 0.07435). Generally, city centers had higher PM concentrations than suburbs, but not BioPM and BioPM%. Indoor bioaerosol levels were found at least tenfold higher than those corresponding outdoors. Bacillus was observed to dominate the bacterial aerosol community in the air sample. 展开更多
关键词 Viable bioaerosol BACTERIA Airpollution - Climate China
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