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脱金属-还原策略诱导创制高分散PtZn合金催化剂用于丙烷脱氢反应
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作者 张龙康 马跃 +6 位作者 刘昌呈 万志鹏 翟承伟 王新 徐浩 关业军 吴鹏 《Chinese Journal of Catalysis》 SCIE EI CAS CSCD 2023年第12期241-252,共12页
丙烷脱氢(PDH)是一种高效的丙烯生产工艺.近年来随着页岩气产量的增加,PDH逐渐成为替代石油催化裂化增产丙烯的重要方法之一.Pt基双金属催化剂在催化PDH领域被广泛研究.其中,PtZn合金双金属催化剂因较好的催化活性和较强的经济可行性,... 丙烷脱氢(PDH)是一种高效的丙烯生产工艺.近年来随着页岩气产量的增加,PDH逐渐成为替代石油催化裂化增产丙烯的重要方法之一.Pt基双金属催化剂在催化PDH领域被广泛研究.其中,PtZn合金双金属催化剂因较好的催化活性和较强的经济可行性,被认为是PDH反应的理想催化剂之一.PtZn合金主要有Pt_(1)Zn_(1),PtZn1.7和Pt3Zn等,其中Pt_(1)Zn_(1)催化PDH反应的活性最好.采用传统共浸渍法制备的PtZn双金属催化剂的金属物种容易分布不均匀,并且成分组成复杂,可能会有多种PtZn合金以及金属单质生成,因此催化活性不理想.如何制备高分散的Pt_(1)Zn_(1)合金催化剂对于PDH工艺的发展有着重要的意义.本文报道了一种分子筛脱金属-还原诱导的策略,将高分散的PtZn合金纳米颗粒负载到Beta沸石上用于PDH反应.首先,在乙二胺的辅助下通过一步水热法合成了杂原子分子筛Zn@Beta.X射线衍射、高分辨透射电镜和紫外-可见光(UV-vis)光谱等结果证明Zn@Beta被成功合成,并且Zn主要以单分散的骨架Zn物种存在.随后,通过简单的浸渍法负载金属Pt.UV-vis光谱、X射线光电子能谱(XPS)、傅里叶变换红外光谱和氢气程序升温还原等结果表明,在浸渍的过程中骨架Zn物种从分子筛骨架移出,并与游离的Pt物种产生了强相互作用.再经H2还原最终得到催化剂0.3Pt1Zn@Beta (Pt和Zn的负载量分别为0.3 wt%和1 wt%).XPS、同步辐射吸收谱和球差矫正电镜结果表明,0.3Pt1Zn@Beta形成了以Pt_(1)Zn_(1)合金物种为主的金属纳米颗粒,而通过共浸渍法制备的PtZn双金属催化剂0.3Pt1Zn/Beta中除了Pt_(1)Zn_(1)合金以外,还有大量的金属Pt单质生成.PDH催化性能评价结果表明,与0.3Pt1Zn/Beta和单金属催化剂0.3Pt/Beta相比,0.3Pt1Zn@Beta表现出更好的PDH催化活性和稳定性.550°C反应时,0.3Pt1Zn@Beta催化生成丙烯的速率为128 mmol/gcat./h,而0.3Pt1Zn/Beta和0.3Pt/Beta催化生成丙烯的仅为75和21 mmol/gcat./h.在550°C,1 bar,C3H8:N2 (V:V)=1:4,丙烷空速4.7 h^(-1)的反应条件下,丙烷初始转化率和丙烯初始选择性分别为36.8%和99.3%,24 h连续反应失活率低至0.004 h^(-1).并且在共氢气条件下实现了180 h的平稳运行.0.3Pt1Zn@Beta也表现出了良好的再生性能,经7次循环后仍能保持较好的催化活性,并且再生过程仅需简单的氢气吹扫,避免了空气焙烧导致的金属颗粒的团聚和温室气体的排放.综上所述,本文发展了一种分子筛脱金属-还原诱导策略,可合成高分散的Pt_(1)Zn_(1)合金催化剂并高效催化PDH反应.该方法的关键是Pt浸渍过程中骨架Zn物种迁移出分子筛骨架并与Pt产生强相互作用,有效克服了共浸渍法制备的双金属催化剂分布不均匀、成分不单一的缺点,为沸石负载双金属催化剂的合成提供新思路. 展开更多
关键词 脱金属-还原诱导策略 PtZn合金 Beta分子筛 丙烷脱氢
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Preparation of AgCl Nano-Crystal Embedded Tellurite Nonlinear Optical Glasses under Electric Field Accompanied Heat Treatment
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作者 Jian LIN Wenhai HUANG +4 位作者 Bofang LI Chong JIN changcheng liu Shuhua LEI Zhenrong SUN 《Journal of Materials Science & Technology》 SCIE EI CAS CSCD 2008年第6期863-866,共4页
The quantum effect of nano-crystals is an important factor to improve nonlinear optical performance of nanocrystal embedded glasses, while controlling the size distribution and content of nano-crystals in the glass ac... The quantum effect of nano-crystals is an important factor to improve nonlinear optical performance of nanocrystal embedded glasses, while controlling the size distribution and content of nano-crystals in the glass accurately is a key to obtain good quality. The auxiliary direct current electric field, accompanied with heat treatment, was applied on AgCI containing niobic tellurite glass sheet. The nucleation and crystallization of the glass were well controlled under auxiliary electric field. It was found that the average size of AgCI nano-crystal particles in the glass is smaller than that under single heat treatment, and the content of nano- crystals is higher. Therefore the third-order nonlinear optical performance of the glass was increased a lot. The local-area distributed AgCl nano-crystal particles can also be embedded into a glass sheet by using locally applied electric field. 展开更多
关键词 Tellurite glass Electric field Nonlinear optical performance
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Experimental design of paraffin/methylated melamine-formaldehyde microencapsulated composite phase change material and the application in battery thermal management system
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作者 Que Huang Silong Wang +10 位作者 Jichun He Dengji Xu Safaa NAbdou Mohamed MIbrahim Shiqi Sun Yanjun Chen Handong Li Ben Bin Xu changcheng liu Zeinhom M.El-Bahy Zhanhu Guo 《Journal of Materials Science & Technology》 SCIE EI CAS CSCD 2024年第2期124-136,共13页
In order to maintain the optimal operating temperature of the battery surface and meet the demand for thermal storage technology,battery thermal management system based on phase change materials has attracted increasi... In order to maintain the optimal operating temperature of the battery surface and meet the demand for thermal storage technology,battery thermal management system based on phase change materials has attracted increasing interest.In this work,a kind of core-shell structured microcapsule was synthesized by an in-situ polymerization,where paraffin was used as the core,while methanol was applied to mod-ify the melamine-formaldehyde shell to reduce toxicity and improve thermal stability.Moreover,three different types of heat conductive fillers with the same content of 10 wt.%,i.e.,nano-Al_(2)O_(3),nano-ZnO and carbon nanotubes were added,generating composites.The microcapsules were uniform,and were not affected by the thermal fillers,which were evenly dispersed around.The composite sample with carbon nanotubes(10 wt.%)showed the highest thermal conductivity of 0.50 W/(m K)and latent heat of 139.64 J/g.Furthermore,according to the leakage testing and battery charge/discharge experiments,compared with Al_(2)O_(3)and ZnO,the addition of carbon nanotubes remarkably enhances the heat storage ability as latent heat from 126.98 J/g for the prepared sample with Al_(2)O_(3)and 125.86 J/g for the one with ZnO,then to 139.64 J/g,as well as dissipation performance as a cooling effect by decreasing the sur-face temperature of battery from 2%to 12%of microcapsule,composite sample with carbon nanotubes presents a broad application prospect in battery thermal management system and energy storage field. 展开更多
关键词 MICROCAPSULE Phase change material BATTERY Carbon nanotube Safety
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草原和荒漠植物多样性监测网规划与建设进展
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作者 宋创业 刘长成 郭柯 《生物多样性》 CAS CSCD 北大核心 2023年第12期162-168,共7页
草原和荒漠是我国北方和青藏高原地区最主要的植被类型,生物多样性资源独特、丰富。草原和荒漠植物多样性监测网是中国生物多样性监测和研究网络的10个专项网之一,旨在以植被群系为基本单元,在草原和荒漠主要植被群系的典型地段建立植... 草原和荒漠是我国北方和青藏高原地区最主要的植被类型,生物多样性资源独特、丰富。草原和荒漠植物多样性监测网是中国生物多样性监测和研究网络的10个专项网之一,旨在以植被群系为基本单元,在草原和荒漠主要植被群系的典型地段建立植物模式群落监测样地,长期监测草原和荒漠植物多样性变化。本文从监测布局、监测样地布设、监测指标和数据产出等方面介绍了草原和荒漠植物多样性监测网的工作进展,并提出未来10年草原和荒漠植物多样性监测网的工作重点,即优化监测点的空间分布、推进自动化监测技术的应用、加强生物多样性变化研究。这些措施将有效提升草原和荒漠植物多样性监测网的研究水平和科学服务能力,为生物多样性保护和研究提供关键的数据支撑。 展开更多
关键词 生物多样性 生态系统 植被群系 植物模式群落样地
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青藏高原植被调查与制图评估 被引量:1
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作者 桑佳文 宋创业 +8 位作者 贾宁霞 贾元 刘长成 乔鲜果 张琳 袁伟影 吴冬秀 李凌浩 郭柯 《生物多样性》 CAS CSCD 北大核心 2023年第3期52-67,共16页
青藏高原植被调查与制图一直是青藏高原植被生态学研究的重要内容。历史上,我国多次开展青藏高原植被考察活动,在植被制图方面取得了一系列重要成果。本研究首先基于文献研读对青藏高原植被考察及其成果进行回顾,并对制图范围包括青藏... 青藏高原植被调查与制图一直是青藏高原植被生态学研究的重要内容。历史上,我国多次开展青藏高原植被考察活动,在植被制图方面取得了一系列重要成果。本研究首先基于文献研读对青藏高原植被考察及其成果进行回顾,并对制图范围包括青藏高原的、使用比较广泛的植被图进行对比和分析;然后,基于第二次青藏高原综合科学考察获取的植被调查样点数据,与多幅植被图在数据一致性方面进行了对比。结果表明:(1)青藏高原植被调查的历史久远,但系统、科学的青藏高原植被调查开始于1949年新中国成立之后,期间获取了大量植被调查数据,出版了大量的专著和图志,《中华人民共和国植被图(1:4,000,000)》《中国草地资源图集(1:1,000,000)》和《中华人民共和国植被图(1:1,000,000)》是包含整个青藏高原、应用最为广泛的3幅植被图,《青藏高原现状植被图》是基于现阶段植被调查数据制作的青藏高原植被图。但是这4幅图在植被分类体系上存在较大差异,严重影响了图件之间的可比性。(2)对比发现,4幅植被图之间均存在一定程度的不一致性。面积较大的植被型组,如森林和草本植被,在植被图之间的一致性较高;但面积相对较小的植被型组,如沼泽与水生植被和农业植被,在植被图之间的一致性较低。进一步以高山嵩草(Carexparvula)草甸、紫花针茅(Stipapurpurea)草原、青藏薹草(Carex moorcroftii)草原、沙生针茅(Stipa glareosa)草原、矮生嵩草(Carex alatauensis)草甸、藏沙蒿(Artemisia wellbyi)草原、昆仑针茅(Stipa roborowskyi)草原、固沙草(Orinus thoroldii)草原等8种青藏高原的典型植被类型为研究对象,发现它们的面积和空间分布格局在《中华人民共和国植被图(1:1,000,000)》和《中国草地资源图集(1:1,000,000)》之间也存在较大的差异。(3)植被调查样点数据与《中华人民共和国植被图(1:1,000,000)》《中国草地资源图集(1:1,000,000)》《青藏高原现状植被图》的对比发现,在植被型组水平上分别有45.05%、21.02%、50.83%的植被调查样点的植被类型与植被图不吻合。(4)近30年来,由于气候变化及人类活动的影响,青藏高原植被的分布格局已经发生了较大变化。同时,植被调查与制图技术进步巨大,高空间、时间及光谱分辨率遥感影像与深度学习技术在植被制图中的应用更加深入,绘制新一代青藏高原大、中比例尺的植被图的时机已经成熟。新一代大、中比例尺植被图的编制将给青藏高原的生态系统管理、生态屏障区和重大生态修复工程建设提供更为翔实的基础数据资料。 展开更多
关键词 植被图 植被类型 植被变化 气候变化 调查
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草原模式植物群落监测方法应用样例 被引量:1
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作者 高趁光 郭柯 +4 位作者 乔鲜果 陆帅志 刘长成 侯东杰 王孜 《生物多样性》 CAS CSCD 北大核心 2018年第3期266-273,共8页
模式植物群落是指能够反映某种植被分类单元基本特征,并可作为准确描述该植被类型"标准"的典型植物群落。草原模式植物群落监测是中国生物多样性监测与研究网络——草原/荒漠植物多样性监测网的核心内容,已初步确定了一套监... 模式植物群落是指能够反映某种植被分类单元基本特征,并可作为准确描述该植被类型"标准"的典型植物群落。草原模式植物群落监测是中国生物多样性监测与研究网络——草原/荒漠植物多样性监测网的核心内容,已初步确定了一套监测方法。本文应用这套方法分别建立了克氏针茅(Stipa krylovii)群系和百里香(Thymus mongolicus)群系模式植物群落监测固定样地,作为中国生物多样性监测与研究网络——草原/荒漠植物多样性监测网的样例。介绍了这两个模式植物群落监测样地选取与设置的过程、群落调查方法和数据分析结果。通过实际观测和案例分析,验证了"中国草原/荒漠植物多样性监测网模式植物群落监测方案"中监测方法的可行性,同时根据监测中出现的问题,提出了模式植物群落样地、监测频率和监测日期的选择原则,以及监测过程中的操作规范等,完善了模式植物群落监测内容、方法和指标体系的建议,为开展草原模式植物群落监测提供了可借鉴的实例与技术储备。 展开更多
关键词 模式植物群落 克氏针茅草原 百里香草原 监测方法
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Stipa steppes in scantily explored regions of the tibetan Plateau:classification,community characteristics and climatic distribution patterns 被引量:4
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作者 Haiwei Zhao Ke Guo +5 位作者 Yao Yang changcheng liu Liqing Zhao Xianguo Qiao Dongjie Hou Chenguang Gao 《Journal of Plant Ecology》 SCIE CSCD 2018年第4期585-594,共10页
Aims As a unique geographical unit of the earth,the tibetan Plateau is extensively covered by various Stipa communities.However,their vegetation features have not been reported systematically till now,especially in so... Aims As a unique geographical unit of the earth,the tibetan Plateau is extensively covered by various Stipa communities.However,their vegetation features have not been reported systematically till now,especially in some scantily explored regions.In this study,we endeavor to reveal the community types,quantitative charac-teristics and climatic distribution patterns of Stipa steppes in these areas based on primary relevés obtained from fieldwork.Methods We collected a total of 223 plots in 79 study sites in the Changthang Plateau and the Yarlung Zangbo Valley,ranging from 79°E to 91°E.the categories of Stipa formations were identified according to the classification scheme in Vegetation of China and then verified by Nonmetric Multidimensional Scaling.We performed detrended correspondence analysis and detrended canonical correspondence analysis to hunt for the alteration of Stipa communities along the precipitation gradient.Quantitative characteristics including species richness,coverage,biomass as well as importance values(IV)of dominant species were calcu-lated and visualized,respectively.Important Findings Stipa steppes in scantily explored regions of the tibetan Plateau are classified into 11 formations but major formations are rather limited in number.Formation(form.)Stipa purpurea is the most widespread Stipa assemblages not only in scantily explored regions but also across the whole tibetan Plateau.the characteristics of Stipa com-munities,including coverage,species richness,productivity and IV of dominant species,demonstrate the features of typical alpine steppes on the tibetan Plateau.Precipitation proves to be the prime climatic factor controlling the distribution patterns of Stipa assemblages.Form.Stipa subsessiliflora var.basiplumosa and form.Stipa glareosa normally distribute in arid habitats,but rainfall for the former is of greater variance.Form.Stipa roborowskyi and form.Stipa capillacea favor moderately moist environment.Form.Stipa purpurea and form.Stipa roborowskyi can tolerate a fairly broad range of precipitation. 展开更多
关键词 stipa steppe community characteristic distribution pattern alpine steppe the tibetan Plateau
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Vegetation classification at the association level under the China Vegetation Classification System: an example of six Stipa steppe formations in China
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作者 changcheng liu Thomas RWentworth +2 位作者 Xianguo Qiao Ke Guo Dongjie Hou 《Journal of Plant Ecology》 SCIE CSCD 2019年第6期1009-1024,共16页
Aims The latest China Vegetation Classification System(China-VCS)for natural/semi-natural vegetation has eight hierarchical levels:Association<Association-group<Subformation<Formation<Formation-group<Ve... Aims The latest China Vegetation Classification System(China-VCS)for natural/semi-natural vegetation has eight hierarchical levels:Association<Association-group<Subformation<Formation<Formation-group<Vegetation-subtype<Vegetation-type<Vegetation-type-group.The classification is based on dominant species and their growth forms and has been completed at the formation level.The principal challenge today in Chinese vegetation classification is to develop the China-VCS at levels below the formation in a way that is consistent with current international standards.We explored the following question:how can existing vegetation plot data help develop the China-VCS and improve its compatibility with other international classification systems?Methods We compiled 401 plots having plant cover and/or aboveground biomass measurements collected in six Stipa steppe formations and divided them into those with cover data(299 plots)and/or biomass data(283 plots).We applied a combination of hierarchical clustering and ordination to partition the cover and biomass data sets into formations and constituent associations.We then used supervised noise clustering to improve the classification and to identify the core plots representing each association.Diagnostic species were also identified at both association and formation levels.Finally,we compared the classification results based on cover and biomass data sets and combined these results into a comprehensive classification framework for the six formations.Important Findings Our results using cover data were comparable with those using biomass data at both formation and association levels.Three Stipa formations were classified into associations based on cover data,two based on biomass data and one based on both biomass and cover data.Twenty-seven associations were defined and proposed within the six formations,using cover or biomass data as consistent classification sections(CCSs).Both dominant species in the dominant stratum and diagnostic species from multiple strata of the core plots were used to characterize vegetation types at both formation and association levels,improving the compatibility of our classification with the International Vegetation Classification.Temperature and precipitation were found to be important climatic factors determining the distribution pattern and species composition of Stipa-dominated vegetation.We propose a framework for plotbased vegetation classification in the China-VCS,using our work with Stipa-dominated steppe vegetation as an example.We applied the concept of CCS to make optimal use of available data representing both plant cover and biomass.This study offers a model for developing the China-VCS to the association level in a way that is consistent with current international standards. 展开更多
关键词 association China Vegetation Classification System consistent classification section cluster analysis ORDINATION Stipa steppe
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