Reflection and transmission of elastic waves through a couple-stress elastic slab sandwiched between two half-spaces

The reflection and transmission of elastic waves through a couple-stress elastic slab that is sandwiched between two couple-stress elastic half-spaces are studied in this paper. Because of the couple-stress effects, there are three types of elastic waves in the couple-stress elastic solid, two of which are dispersive. The interface conditions between two couple-stress solids involve the surface couple and rotation apart from the surface traction and displacement. The nontraditional interface conditions between the slab and two solid half-spaces are used to obtain the linear algebraic equation sets from which the amplitude ratios of reflection and transmission waves to the incident wave can be determined. Then,the energy fluxes carried by the various reflection and transmission waves are calculated numerically and the normal energy flux conservation is used to validate the numerical results. The special case, couple-stress elastic slab sandwiched by the classical elastic half-spaces, is also studied and compared with the situation that the classical elastic slab sandwiched by the classical elastic half-spaces. Incident longitudinal wave(P wave) and incident transverse wave(SV wave) are both considered. The influences of the couplestress are mainly discussed based on the numerical results.It is found that the couple-stress mainly influences the transverse modes of elastic waves.

The Package Concept for Enforcing Usage Control

Access and usage control is a major challenge in information and computer security in a distributed network connected environment. Many models have been proposed such as traditional access control and UCONABC. Though these models have achieved their objectives in some areas, there are some issues both have not dealt with. The issue of what happens to a resource once it has been accessed rightfully. In view of this, this paper comes out with how to control resource usage by a concept known as the package concept. This concept can be implemented both with internet connection and without the internet connection to ensure continual control of resource. It packages the various types of resources with the required policies and obligations that pertain to the use of these different resources. The package concept of ensuring usage control focuses on resource by classifying them into three: Intellectual, sensitive and non-sensitive resources. Also this concept classifies access or right into three as: access to purchase, access to use temporally online and access to modify. The concept also uses biometric mechanism such as fingerprints for authentication to check redistribution of resource and a logic bomb to help ensure the fulfillment of obligations.

Nonstoichiometric In-S group yielding efficient carrier transfer pathway in In_(2)S_(3) photoanode for solar water oxidation

The construction of high-efficiency photoanodes is essential for developing outstanding photoelectrochemical(PEC)water splitting cells.Furthermore,insufficient carrier transport capabilities and sluggish surface water oxidation kinetics limit its application.Using a solvothermal annealing strategy,we prepared a nonstoichiometric In-S(NS)group on the surface of an In_(2)S_(3) photoanode in situ and unexpectedly formed a type II transfer path of carrier,thereby reducing the interfacial recombination and promoting the bulk separation.Firstprinciples calculations and comprehensive characterizations demonstrated NS group as an excellent oxygen evolution cocatalyst(OEC)that effectively facilitated carrier transport,lowered the surface overpotential,increased the surface active site,and accelerated the surface oxygen evolution reaction kinetics by precisely altering the rate-determining steps of*to*OH and*O to*OOH.These synergistic effects remarkably enhanced the PEC performance,with a high photocurrent density of 5.02 mA cm^(−2)at 1.23 V versus reversible hydrogen electrode and a negative shift in the onset potential by 310 mV.This work provides a new strategy for the in situ preparation of high-efficiency OECs and provides ideas for constructing excellent carrier transfer and transport channels.

Biomass-derived hard carbon microtubes with tunable apertures for high-performance sodium-ion batteries

Sodium-ion batteries(SIBs)are considered the most up-and-coming complements for large-scale energy storage devices due to the abundance and cheap sodium.However,due to the bigger radius,it is still a great challenge to develop anode materials with suitable space for the intercalation of sodium ions.Herein,we present hard carbon microtubes(HCTs)with tunable apertures derived from low-cost natural kapok fibers via a carbonization process for SIBs.The resulted HCTs feature with smaller surface area and shorter Na+diffusion path benefitting from their unique micro-nano structure.Most importantly,the wall thickness of HCTs could be regulated and controlled by the carbonization temperature.At a high temperature of 1,600℃,the carbonized HCTs possess the smallest wall thickness,which reduces the diffusion barrier of Na+and enhances the reversibility Na+storage.As a result,the 1600HCTs deliver a high initial Coulombic efficiency of 90%,good cycling stability(89.4%of capacity retention over 100 cycles at 100 mA·g^(−1)),and excellent rate capacity.This work not only charts a new path for preparing hard carbon materials with adequate ion channels and novel tubular micro-nano structures but also unravels the mechanism of hard carbon materials for sodium storage.

Interface regulation of Cu_(2)Se via Cu–Se–C bonding for superior lithium-ion batteries

Transition metal selenides have aroused great attention in recent years due to their high theoretical capacity.However,the huge volume fluctuation generated by conversion reaction during the charge/discharge process results in the significant electrochemical performance reduction.Herein,the carbon-regulated copper(I)selenide(Cu_(2)Se@C)is designed to significantly promote the interface stability and ion diffusion for selenide electrodes.The systematic X-ray spectroscopies characterizations and density functional theory(DFT)simulations reveal that the Cu–Se–C bonding forming on the surface of Cu2Se not only improves the electronic conductivity of Cu_(2)Se@C but also retards the volume change during electrochemical cycling,playing a pivotal role in interface regulation.Consequently,the storage kinetics of Cu_(2)Se@C is mainly controlled by the capacitance process diverting from the ion diffusion-controlled process of Cu2Se.When employed this distinctive Cu_(2)Se@C as anode active material in Li coin cell configuration,the ultrahigh specific capacity of 810.3 mA·h·g^(−1)at 0.1 A·g^(−1)and the capacity retention of 83%after 1,500 cycles at 5 A·g^(−1)is achieved,implying the best Cu-based Li^(+)-storage capacity reported so far.This strategy of heterojunction combined with chemical bonding regulation opens up a potential way for the development of advanced electrodes for battery storage systems.

Unsaturated-sulfur-rich MoS2 nanosheets decorated on free-standing SWNT film： Synthesis, characterization and electrocatalytic application

Herein, we report a bottom-up solvothermal route to synthesize a flexible, highly efficient MoS2@SWNT electrocatalyst for hydrogen evolution reactions （HER）. Characterization revealed that branchqike MoS2 nanosheets containing sulfur- rich sites were in situ uniformly dispersed on free-standing single-walled carbon nanotube （SWNT） film, which could expose more unsaturated sulfur atoms, allowing excellent electrical contact with active sites. The flexible catalyst exhibited excellent HER performance with a low overpotential （-150 mV at 10 ma/cm2） and small Tafel slope （4l mV/dec）. To further explain the improved performance, the local electronic structure was investigated by X-ray absorption near-edge structure （XANES） analysis, proving the presence of unsaturated sulfur atoms and strong electronic coupling between MoS2 and SWNT. This study provides an in-situ synthetic route to create new multifunctional flexible hybridized catalysts and useful insights into the relationships electronic structure, and properties among the catalyst microstructure,

In situ trapped high-density single metal atoms within graphene： Iron-containing hybrids as representatives for efficient oxygen reduction

Atomically dispersed catalysts have attracted attention in energy conversion applications because their efficiency and chemoselectivity for special catalysis are superior to those of traditional catalysts. However, they have limitations owing to the extremely low metal-loading content on supports, difficulty in the precise control of the metal location and amount as well as low stability at high temperatures. We prepared a highly doped single metal atom hybrid via a single-step thermal pyrolysis of glucose, dicyandiamide, and inorganic metal salts. High-angle annular dark field-scanning transmission electron microscopy （HAADF-STEM） and X-ray absorption fine structure spectroscopy （XAFS） revealed that nitrogen atoms doped into the graphene matrix were pivotal for metal atom stabilization by generating a metal-Nx coordination structure. Due to the strong anchoring effect of the graphene matrix, the metal loading content was over 4 wt.% in the isolated atomic hybrid （the Pt content was as high as 9.26 wt.% in the Pt-doped hybrid）. Furthermore, the single iron-doped hybrid （Fe@N-doped graphene） showed a remarkable electrocatalytic performance for the oxygen reduction reaction. The peak power density was - 199 mW·cm-2 at a current density of 310 mA·cm-2 and superior to that of a commercial Pt/C catalyst when it was used as a cathode catalyst in assembled zinc-air batteries. This work offered a feasible approach to design and fabricate highly doped single metal atoms （SMAs） catalysts for potential energy applications.

Base communication model of IP covert timing channels

IP covert timing channel （IPCTC） is an unconventional communication channel which attaches time information to the packets of an overt channel as messages carders, e.g., using different inter-packet delays to transmit messages in a packet-switched network. Although the IPCTCs have many different communication methods, based on the concept of time, we categorized the base communication model of the IPCTCs into three types and then utilized the signal processing theory to build their mathematical models. As a result, the basic characteristics of the IPCTCs＇ base model were formally derived. Hence, the characteristics of any IPCTC can be derived from the base models that consist of the IPCTC. Furthermore, a set of approaches was devised to implement the base model of the IPCTCs in a TCP/IP network. Experimental results show the correctness of the pro- posed base model of the IPCTCs in this paper.

Vacancy manipulating of molybdenum carbide MXenes to enhance Faraday reaction for high performance lithium-ion batteries

“Intrinsic”strategies for manipulating the local electronic structure and coordination environment of defect-regulated materials can optimize electrochemical storage performance.Nevertheless,the structure–activity relationship between defects and charge storage is ambiguous,which may be revealed by constructing highly ordered vacancy structures.Herein,we demonstrate molybdenum carbide MXene nanosheets with customized in-plane chemical ordered vacancies(Mo_(1.33)CT_(x)),by utilizing selective etching strategies.Synchrotron-based X-ray characterizations reveal that Mo atoms in Mo1.33CTx show increased average valence of+4.44 compared with the control Mo_(2)CT_(x).Benefited from the introduced atomic active sites and high valence of Mo,Mo_(1.33)CT_(x)achieves an outstanding capacity of 603 mAh·g^(−1)at 0.2 A·g^(−1),superior to most original MXenes.Li+storage kinetics analysis and density functional theory(DFT)simulations show that this optimized performance ensues from the more charge compensation during charge–discharge process,which enhances Faraday reaction compared with pure Mo_(2)CT_(x).This vacancy manipulation provides an efficient way to realize MXene’s potential as promising electrodes.

Relection of elastic waves at the elastically supported boundary of a couple stress elastic half-space

The relection elastic waves at the elastically supported boundary of a couple stress elastic half-space are studied in this paper. Different from the classical elastic solid, there are three kinds of elastic waves in the couple stress elastic solid, and two of them are dispersive. The boundary conditions of a couple stress elastic half-space include the couple stress vector and the rotation vector which disappear in the classical elastic solids. These boundary conditions are used to obtain a linear algebraic equation set, from which the amplitude ratios of relection waves to the incident wave can be determined. Then, the relection coeficients in terms of energy lux ratios are calculated numerically, and the normal energy lux conservation is used to validate the numerical results. Based on these numerical results,the inluences of the boundary parameters, which relect the mechanical behavior of elastic support, on the relection energy partition are discussed. Both the incident longitudinal wave（the P wave） and incident transverse wave（the SV wave） are considered.

Cation-intercalated engineering and X-ray absorption spectroscopic characterizations of two dimensional MXenes

The geometrically multiplied development of 2D MXenes has already promoted the prosperity of various fields of scientific researches especially but not limited in energy storage and conversion.Notably,cation intercalation can improve the interlayer spacing of MXenes resulting in tunable physical and chemical properties.Moreover,the synchrotron radiation X-ray characterizations have also shown high potential on exploring the property and structu re of cation intercalated MXe nes.This review is mainly focused on the recent achievements of cation intercalated MXenes through different methods on energy storage systems.Synchrotron-based X-ray absorption spectroscopic characterizations are emphasized to probe the local coordination and electronic structure in intercalated MXenes.The outlook of cation intercalation on MXenes and their applications are also discus sed.