The effect of different Co phase structure(FCC/HCP)on the catalytic action towards the hydrogen storage performance of MgH_(2)

High hydrogen desorption temperature and sluggish reaction kinetics are the major limitations for the practical application of MgH_(2).In this study,Co particles with a face centered cubic(FCC)structure and a hexagonal close packed(HCP)structure were prepared facilely and proved to be good catalysts for magnesium hydride.Co particles with FCC structure presented better catalytic effect on MgH_(2)than that with HCP structure.Both 7%(mass)Co FCC and HCP particle modified MgH_(2)decreased the initial dehydrogenation temperature from 301.3℃ to approximately 195.0℃,but 7%(mass)Co with FCC structure modified MgH_(2)has a faster desorption rate,and around 6.5%(mass)H_(2)was desorbed in 10 min at325℃.Hydrogen uptake was detected at 70℃ under 3.25 MPa hydrogen pressure and 6.0%(mass)H_(2)was recharged in 40 min at 150℃.The hydrogen desorption and absorption activation energy for 7%(mass)FCC Co modified MgH_(2)was significantly decreased to(76.6±8.3)kJ·mol^(-1) and(68.3±6.0)kJ·mol^(-1),respectively.Thermodynamic property was also studied,the plateau pressures of MgH_(2)+7%(mass)FCC Co were determined to be 0.14,0.28,0.53 and 0.98 MPa for 300℃,325℃,350℃ and375℃.The decomposition enthalpy of hydrogen(ΔH)for MgH_(2)+7%(mass)FCC Co was(80.6±0.1)kJ·mol^(-1),5.8 kJ·mol^(-1)lower than that of as-prepared MgH_(2).Moreover,cycling performance for the first20 cycles revealed that the reaction kinetics and capacity of MgH_(2)-FCC Co composite remained almost unchanged.The result of density functional theory calculation demonstrated that cobalt could extract the Mg AH bond and reduced the decompose energy of magnesium hydride.Our paper can be presented as a reference for searching highly effective catalysts for hydrogen storage and other energy-related research fields.

Multi-Mode Bus Coupling Architecture of Superconducting Quantum Processor

Resonators in circuit quantum electrodynamics systems naturally carry multiple modes, which may have non-negligible influence on qubit parameters and device performance. While new theories and techniques are under investigation to deal with the multi-mode effects in circuit quantum electrodynamics systems, researchers have proposed novel engineering designs featuring multi-mode resonators to achieve enhanced functionalities of superconducting quantum processors. Here, we propose multi-mode bus coupling architecture, in which superconducting qubits are coupled to multiple bus resonators to gain larger coupling strength. Applications of multi-mode bus couplers can be helpful for improving i SWAP gate fidelity and gate speed beyond the limit of single-mode scenario. The proposed multi-mode bus coupling architecture is compatible with a scalable variation of the traditional bus coupling architecture. It opens up new possibilities for realization of scalable superconducting quantum computation with circuit quantum electrodynamics systems.

Review on field-induced phase transitions in lead-free NaNbO_(3)-based antiferroelectric perovskite oxides for energy storage

Emerging new applications of antiferroelectric perovskite oxides based on their fascinating phase transformation between polar and nonpolar states have provided considerable attention to this class of materials even decades after the discovery of antiferroelectricity.After presenting the challenge of formulating a precise definition of antiferroelectric materials,we briefly summarize proposed applications.In the following,we focus on the crystallographic structures of the antiferroelectric and ferroelectric phases of NaNbO_(3),which is emerging as a promising alternative to PbZrO_(3)-based systems.The field-induced phase transition behavior of NaNbO_(3)-based AFE materials in the form of single crystals,bulk ceramics,and multilayer ceramic capacitors is reviewed.Recent advances in a group of materials exhibiting high energy storage performance and relaxor-like behavior are also covered.The influence of electrode geometry on phase transition behavior and thus on the energy storage property is briefly addressed.The review concludes with an overview of the remaining challenges related to the fundamental understanding of the scientific richness of AFE materials in terms of structure,microstructure,defect transport under high fields,and phase transition dynamics required for their future development and applications.

Dynamic oxidation mechanism of carbon fiber reinforced SiC matrix composite in high-enthalpy and high-speed plasmas

This work employed an inductively coupled plasma wind tunnel to study the dynamic oxidation mechanisms of carbon fiber reinforced SiC matrix composite(C_(f)/SiC)in high-enthalpy and high-speed plasmas.The results highlighted a transition of passive/active oxidations of SiC at 800–1600℃and 1–5 kPa.Specially,the active oxidation led to the corrosion of the SiC coating and interruption of the SiO_(2) growth.The transition borders of active/passive oxidations were thus defined with respect to oxidation temperature and partial pressure of atomic O in the high-enthalpy and high-speed plasmas.In the transition and passive domains,the SiC dissipation was negligible.By multiple dynamic oxidations of C_(f)/SiC in the domains,the SiO_(2) thickness was not monotonously increased due to the competing mechanisms of passive oxidation of SiC and dissipation of SiO_(2).In addition,the mechanical properties of the SiC coating/matrix and the C_(f)/SiC were maintained after long-term dynamic oxidations,which suggested an excellent thermal stability of C_(f)/SiC serving in thermal protection systems(TPSs)of reusable hypersonic vehicles.