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Analysis of solute redistribution and centerline segregation in continuously cast thin slab 被引量:2
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作者 changwen ma Houfa SHEN +1 位作者 Tianyou HUANG Baicheng LIU 《China Foundry》 SCIE CAS 2004年第2期94-98,共5页
A model has been built to calculate the solute redistribution in continuously cast thin slab and the effect of the fluid flow in mush on the centerline segregation was analyzed. The corresponding simulation program wa... A model has been built to calculate the solute redistribution in continuously cast thin slab and the effect of the fluid flow in mush on the centerline segregation was analyzed. The corresponding simulation program was developed by applying the SIMPLER algorithm. The momentum, energy and species conservation equations were solved simultaneously. The macro-segregation of a 3-D thin slab with 900 mm × 50 mm cross section was simulated. The obtained results show that negative segregation forms near the slab surface and severe centerline segregation forms in the mid-thickness plane. The species concentration in the centerline of the slab increases obviously at the final solidification stage. 展开更多
关键词 centerline segregation continuous casting SOLIDIFICATION numerical simulation
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缺陷工程调控ZnIn_(2)S_(4)纳米片用于增强近红外驱动制氢 被引量:1
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作者 黄元勇 杨洪 +5 位作者 冯硕 马畅文 曹佩一 李菲菲 陆欣宇 施伟东 《Science China Materials》 SCIE EI CAS CSCD 2024年第6期1812-1819,共8页
近红外(NIR)光驱动水分解产生氢气(H_(2))一直以来都是光催化领域备受关注的问题,但由于其动力学和热力学方面的缺陷,迄今为止仍是一项艰巨的挑战.为了突破这一限制,我们通过简便的水热法设计出了富含硫空位的无贵金属二维(2D)ZnIn_(2)S... 近红外(NIR)光驱动水分解产生氢气(H_(2))一直以来都是光催化领域备受关注的问题,但由于其动力学和热力学方面的缺陷,迄今为止仍是一项艰巨的挑战.为了突破这一限制,我们通过简便的水热法设计出了富含硫空位的无贵金属二维(2D)ZnIn_(2)S_(4)-基光催化剂,并首次使用单组分ZnIn_(2)S_(4)-基材料实现了波长大于800 nm的近红外驱动制氢性能.根据价带光谱、紫外-可见-近红外DRS光谱、稳态PL光谱、瞬态光电流响应和EPR表征,我们揭示了存在一个高效的Urbach带尾吸收用于捕获近红外光.硫空位在ZnIn_(2)S_(4)纳米片中的成功构建不仅扩展了光谱吸收范围,而且具有出色的载流子扩散特性和丰富的活性位点.因此,我们的研究结果可能会为未来开发近红外响应的ZnIn_(2)S_(4)-基光催化剂用于实现高效近红外驱动制氢提供一定的指导. 展开更多
关键词 NEAR-INFRARED H2 production ZnIn2S4 sulfur va-cancies Urbach tail
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Capture of phosphates in surface water by TiO_2 nanoparticles under UV irradiation
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作者 Hongyong Xie Qi Zheng +4 位作者 Shanzhu Wang changwen ma Guilan Gao Naici Bing Zhiguo Sun 《Particuology》 SCIE EI CAS CSCD 2014年第3期98-102,共5页
The capture of orthophosphates and total phosphorus from the Pudong Canal river in the Pudong District of Shanghai by TiO2 nanoparticles is studied using a rotating photoreactor and the nano-TiO2 photocatalyst Degussa... The capture of orthophosphates and total phosphorus from the Pudong Canal river in the Pudong District of Shanghai by TiO2 nanoparticles is studied using a rotating photoreactor and the nano-TiO2 photocatalyst Degussa P25. The effects of UV irradiation intensity in a range of 20-74 mW/cm^2, the loading of the TiO2 nanoparticles in a range of 0.05-0.1 g/L, irradiation time up to 4 h, and pH values in a range of 2-10.5 on the capture efficiency are investigated. The results show that the capture of orthophosphates and total P are significantly enhanced by UV irradiation; at a loading of 0.1 g/L and an irradiation intensity above 36 mW/cm^2, orthophosphates and total phosphorus are rapidly captured by TiO2 nanoparticles, causing an observed reduction from 0.4 mg/L down to 0.02 mg/L. pH values in a range of 2-10.5 have little effect on the capture efficiency of orthophosphates and total phosphorus. 展开更多
关键词 Orthophosphates Total phosphorus Surface water TiO2 nanoparticles UV irradiation
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