Cation-πinteraction is considered one of the strongest noncovalent interactions in aqueous solutions,which endows natural biomolecules(e.g.,proteins)with robust wet adhesion and cohesion in humid/underwater environme...Cation-πinteraction is considered one of the strongest noncovalent interactions in aqueous solutions,which endows natural biomolecules(e.g.,proteins)with robust wet adhesion and cohesion in humid/underwater environments.However,it remains a challenge to construct synthetic functional materials(e.g.,self-healing hydrogels)by adopting the cation-πinteractions rationally.Herein,we present a facile and novel strategy to fabricate injectable self-healing synthetic hydrogel from self-assembly of a thermoresponsive ABA triblock copolymer via cation-πinteractions.展开更多
基金supports of the National Natural Science Foundation of China(no.21876119)Special Engineering Team of Sichuan University(no.2020SCUNG122)+1 种基金and Chengdu Science and Technology Program(no.2019-GH02-00029-HZ)H.Z.acknowledges the financial support from the Natural Sciences and Engineering Research Council of Canada(NSERC),Canada Foundation Innovation(CFI),and the Canada Research Chairs Program.
文摘Cation-πinteraction is considered one of the strongest noncovalent interactions in aqueous solutions,which endows natural biomolecules(e.g.,proteins)with robust wet adhesion and cohesion in humid/underwater environments.However,it remains a challenge to construct synthetic functional materials(e.g.,self-healing hydrogels)by adopting the cation-πinteractions rationally.Herein,we present a facile and novel strategy to fabricate injectable self-healing synthetic hydrogel from self-assembly of a thermoresponsive ABA triblock copolymer via cation-πinteractions.
