高放核废料存储环境下温度对纯铜腐蚀的影响（英文）

系统研究在高放核废料存储环境下温度对纯铜腐蚀的影响。采用交流阻抗谱、Mott-Schottky技术、动电位以及恒电位极化曲线分析纯铜在不同温度下的腐蚀行为;并采用体视显微镜以及扫描电镜观察样品表面形貌,同时结合X射线光电子能谱分析钝化膜成分。结果表明,钝化膜阻抗并不随着温度的升高而一直降低,在60°C由于致密的外层结构阻抗反常增大;点蚀在此环境下可能发生且钝化膜的点蚀电位随着温度的升高而降低;钝化膜主要成分为Cu_2S,而CuS的含量随着温度的升高而增加;钝化膜主要呈p型半导体特性,阳离子空位密度在1023 cm^(-3)数量级且随着温度的升高其密度增大。

Constituent phases of the passive film formed on 2205 stainless steel by dynamic electrochemical impedance spectroscopy

The passive film formed on 2205 duplex stainless steel（DSS） in 0.5 M NaHCO3＋0.5 M NaCl aqueous solution was characterized by electrochemical measurements,including potentiodynamic anodic polarization and dynamic electrochemical impedance spectroscopy（DEIS）.The results demonstrate that there is a great difference between the passive film evolutions of ferrite and austenite.The impedance values of ferrite are higher than those of austenite.The impedance peaks of ferritic and austenitic phases correspond to the potential of 0.15 and 0.25 V in the low potential range and correspond to 0.8 and 0.75 V in the high potential range.The evolutions of the capacitance of both phases are reverse compared to the evolutions of impedance.The thickness variations obtained from capacitance agree well with those of impedance analysis.The results can be used to explain why pitting corrosion occurs more easily in austenite phase than in ferrite phase.

Corrosion behavior of aluminum alloys in Na_2SO_4 solution using the scanning electrochemical microscopy technique

The corrosion behavior of aluminum alloys 1060 and 2A12 in a 10 mM Na2SO4＋5 mM KI solution was investigated by scanning electrochemical microscopy （SECM） and scanning electron microscopy （SEM）. The potential topography and corrosion morphology results show that the potential of the sample surface over the same area changes with the increase of immersion time. The corrosion area becomes large, and the potential becomes more negative. The corrosion potential of the 2A12 alloy surface is lower than that of 1060 aluminum, and 2A12 alloy becomes easily corrosive. This is the reason that preferential dissolution in the boundary region of some intermetallic particles （IMPs） occurs and different dissolution behaviors are associated with different types of IMPs because of different potentials.

Prediction model for atmospheric corrosion of 7005-T4 aluminum alloy in industrial and marine environments

Accelerated corrosion tests of the 7005-T4 aluminum alloy were conducted to determine a suitable service life prediction method by using alternating wet–dry cycles in three kinds of solutions. The morphology and composition analysis of the corrosion product revealed that slight corrosion occurred on the surfaces of the samples immersed in a 0.25 wt% Na_2S_2O_8 solution. However, pitting corrosion occurred on the surfaces of the samples immersed in a 3.5 wt% NaCl solution, whereas exfoliation corrosion occurred on the surfaces of the samples immersed in a mixture of 0.25 wt% Na_2S_2O_8 and 3.5 wt% NaCl solutions. A power exponent relationship was observed between the mass loss and exposure time of the 7005-T4 aluminum alloy immersed in the three kinds of solutions. In the mixture of 0.25 wt% Na_2S_2O_8 and 3.5 wt% NaCl solutions, the mass loss of the aluminum alloy yielded the maximum value. Based on the calculation of the correlation coefficients, the alternating wet–dry procedure in a 3.5 wt% NaCl solution could be used to predict the corrosion behavior of 7005-T4 aluminum alloy exposed in the atmosphere of Qingdao, China. The prediction model is as follows: T = 104.28×t^(0.91), where T is the equivalent time and t is the exposure time.

Effects of chitosan inhibitor on the electrochemical corrosion behavior of 2205 duplex stainless steel

The effects of chitosan inhibitor on the corrosion behavior of 2205 duplex stainless steel were studied by electrochemical measurements, immersion tests, and stereology microscopy. The influences of immersion time, temperature, and chitosan concentration on the corrosion inhibition performance of chitosan were investigated. The optimum parameters of water-soluble chitosan on the corrosion inhibition performance of 2205 duplex stainless steel were also determined. The water-soluble chitosan showed excellent corrosion inhibition performance on the 2205 duplex stainless steel. Polarization curves demonstrated that chitosan acted as a mixed-type inhibitor. When the stainless steel specimen was immersed in the 0.2 g/L chitosan solution for 4 h, a dense and uniform adsorption film covered the sample surface and the inhibition efficiency(IE) reached its maximum value. Moreover, temperature was found to strongly influence the corrosion inhibition of chitosan; the inhibition efficiency gradually decreased with increasing temperature. The 2205 duplex stainless steel specimen immersed in 0.4 g/L water-soluble chitosan at 30°C displayed the best corrosion inhibition among the investigated specimens. Moreover, chitosan decreased the corrosion rate of the 2205 duplex stainless steel in an FeCl_3 solution.

Effect of microstructure on corrosion behavior of high strength martensite steel-A literature review

The high strength martensite steels are widely used in aerospace,ocean engineering,etc.,due to their high strength,good ductility and acceptable corrosion resistance.This paper provides a review for the influence of microstructure on corrosion behavior of high strength martensite steels.Pitting is the most common corrosion type of high strength stainless steels,which always occurs at weak area of passive film such as inclusions,carbide/intermetallic interfaces.Meanwhile,the chromium carbide precipitations in the martensitic lath/prior austenite boundaries always result in intergranular corrosion.The precipitation,dislocation and grain/lath boundary are also used as crack nucleation and hydrogen traps,leading to hydrogen embrittlement and stress corrosion cracking for high strength martensite steels.Yet,the retained/reversed austenite has beneficial effects on the corrosion resistance and could reduce the sensitivity of stress corrosion cracking for high strength martensite steels.Finally,the corrosion mechanisms of additive manufacturing high strength steels and the ideas for designing new high strength martensite steel are explored.

Failure analysis of AZ31 magnesium alloy sheets based on the extended GTN damage model

Based on the Gurson-Tvergaard-Needleman （GTN） model and Hill＇s quadratic anisotropic yield criterion, a combined experimental-numerical study on fracture initiation in the process of thermal stamping of Mg alloy AZ31 sheets was carried out. The aim is to predict the formability of thermal stamping of the Mg alloy sheets at different temperatures. The presented theoretical framework was implemented into a VUMAT subroutine for ABAQUS/EXPLICIT. Internal damage evolution due to void growth and coalescence developed at different temperatures in the Mg alloy sheets was observed by scanning electron microscopy （SEM）. Moreover, the thermal effects on the void growth, coalescence, and fracture behavior of the Mg alloy sheets were analyzed by the extended GTN model and forming limit diagrams （FLD）. Parameters employed in the GTN model were determined from tensile tests and numerical iterative computation. The distribution of major and minor principal strains in the specimens was determined from the numerical results. Therefore, the corresponding forming limit diagrams at different stress levels and temperatures were drawn. The comparison between the predicted forming limits and the experimental data shows a good agreement.

Preparation and characterization of a chitosan-based low-pH-sensitive intelligent corrosion inhibitor

A chitosan （CS）-based low-pH-sensitive intelligent corrosion inhibitor was prepared by loading a pH-sensitive hydrogel with benzotriazole （BTA）; the pH-sensitive hydrogel was synthetized by crosslinking CS with glutaraldehyde （GTA）. Analysis by Fou- tier-transform inflared （FT-IR） spectroscopy showed that Schiff reactions occurred between amino and aldehyde groups. The swelling abil- ity of the hydrogel was investigated using a mass method, and it was observed to swell more in an acidic environment than in an alkaline en- vironment. The hydrogel＇s loading capacity of BTA was approximately 0.377 g·g ^-1, and its release speed was faster in an acidic environment than in an alkaline environment because of its swelling behavior. The corrosion inhibition ability of the intelligent inhibitor was tested by immersion and electrochemical methods. The results showed that after 4 h of immersion, the polarization resistance （Rp） value of copper with the intelligent inhibitor was approximately twice of that of copper with BTA, indicating that the intelligent inhibitor could effectively prevent copper from corroding.

Anodic dissolution of a crack tip at AA2024-T351 in 3.5wt% NaCl solution

The anodic dissolution process of a crack tip at 2024-T351 aluminium alloy （AA2024-T351） was determined by means of scanning Kelvin probe （SKP）. Wedge-open loading （WOL） specimens were immersed in a 3.5wt% NaCl solution. After various durations of immersion, the Volta potential distributions around the crack were measured by SKP and the surface morphologies were observed by scanning electron microscopy （SEM）. It is found that there is a nonuniform distribution of Volta potential around the crack. Before immersion, the Volta potential at crack tip is more negative than that in other regions. However, after immersion, a converse result occurs with the most positive Volta potential measured at the crack tip. SEM observations demonstrate that the noticeable positive shift of Volta potential results fi：om the formation of corrosion products which deposit around the crack tip. Energy-dispersive spectrometry （EDS） analysis shows that the corrosion products are mainly A1 oxide and Cu-rich particles. These observations implicate that the applied stress contributes to the preferential anodic dissolution of the crack tip and the redistribution of Cu.

Corrosion behavior of the expandable tubular in formation water

The corrosion behavior of expandable tubular materials was investigated in simulated downhole formation water environments using a series of electrochemical techniques. The corrosion morphologies in the real downhole environment after three months of application were also observed by stereology microscopy and scanning electron microscopy （SEM）. The results show that, compared with the unex- panded sample, the area of ferfite increases dramatically after a 7.09% expansion. The expanded material shows a higher corrosion current in the polarization curve and a lower corrosion resistance in the electrochemical impedance spectroscopy （EIS） plot at every studied tempera- ture. The determined critical pitting temperatures （CPT） before and after expansion are 87.5℃and 79.2℃, respectively. SEM observations demonstrate stress corrosion cracks, and CO2 corrosion and H2S corrosion also occur in the downhole environment. Due to additional defects generated during the plastic deformation, the corrosion performance of the expanded tubing deteriorates.

Effects of BN content on the mechanical properties of nanocrystalline 3Y-TZP/Al_(2)O_(3)/BN dental ceramics

3Y-TZP/3wt%Al_(2)O_(3) powder was coated with varying amounts of BN using the urea and borate reaction sintering method,and then multiphase ceramics were prepared by hot pressing sintering.The micro-topography and the compositional analysis of synthesized ceramics were conducted through scanning electron microscopy,transmission electron microscopy and X-ray diffraction.A mechanical tester was used to analyze the Vickers hardness,fracture toughness,and bending strength of the synthesized ceramics.The results showed that the ceramic with a BN content of 12wt%showed the best processability,but had diminished mechanical properties(such as fracture toughness and bending strength).The ceramic with a BN content of 9wt%showed better processability than those with 3wt%and 6wt%BN.However,the fracture toughness was affected by the addition of 9wt%BN,making this ceramic only usable as a base material for a three-unit fixed bridge.In contrast,the ceramics with a BN content of 3wt%or 6wt%fulfilled the criteria for use in multi-unit restoration,but their low processability made them unsuitable for milling after sintering.

Influence of oxide scales on the corrosion behaviors of B510L hot-rolled steel strips

The influence of oxide scales on the corrosion behaviors of B510 L hot-rolled steel strips was investigated in this study. Focused ion beams and scanning electron microscopy were used to observe the morphologies of oxide scales on the surface and cross sections of the hot-rolled steel. Raman spectroscopy and X-ray diffraction were used for the phase analysis of the oxide scales and corrosion products. The corrosion potential and impedance were measured by anodic polarization and electrochemical impedance spectroscopy. According to the results, oxide scales on the hot-rolled strips mainly comprise iron and iron oxides. The correlation between mass gain and test time follows a power exponential rule in the damp-heat test. The corrosion products are found to be mainly composed of γ-Fe OOH, Fe3O4, ？-Fe OOH, and γ-Fe2O3. The contents of the corrosion products are different on the surfaces of the steels with and without oxide scales. The steel with oxide scales is found to show a higher corrosion resistance and lower corrosion rate.

Microstructure and mechanical properties of nickel-based superalloy fabricated by laser powder-bed fusion using recycled powders

Evaluating the recyclability of powders in additive manufacturing has been a long-term challenge.In this study,the microstructure and mechanical properties of a nickel-based superalloy fabricated by laser powder-bed fusion(LPBF)using recycled powders were investigated.Re-melted powder surfaces,satellite particles,and deformed powders were found in the recycled powders,combined with a high-oxygencontent surface layer.The increasing oxygen content led to the formation of high-density oxide inclusions;moreover,printing-induced cracks widely occurred and mainly formed along the grain boundaries in the as-built LPBF nickel-based superalloys fabricated using recycled powders.A little change in the Si or Mn content did not increase the hot cracking susceptibility(HCS)of the printed parts.The changing aspect ratio and the surface damage of the recycled powders might contribute to increasing the crack density.Moreover,the configuration of cracks in the as-built parts led to anisotropic mechanical properties,mainly resulting in extremely low ductility vertical to the building direction,and the cracks mainly propagated along the cellular boundary owing to the existence of a brittle precipitation phase.

Electrochemical corrosion failure mechanism of M152 steel under a salt-spray environment

The corrosion failure mechanism of M152 was studied using the neutral salt-spray test to better understand the corrosion behavior of 1Cr12Ni3Mo2VN（M152）, provide a basis for the optimization of material selection, and prevent the occurrence of failure. Moreover, the mechanism was investigated using the mass loss method, polarization curves, electrochemical impedance spectroscopy（EIS）, stereology microscopy, scanning electron microscopy, and energy-dispersive X-ray spectroscopy（EDS）. The results show that M152 steel suffers severe corrosion, especially pitting corrosion, in a high-salt-spray environment. In the early stage of the experiment, the color of the corrosion products was mainly orange. The products then gradually evolved into a dense, brown substance, which coincided with a decrease of corrosion rate. Correspondingly, the EIS spectrum of M152 in the late test also exhibited three time constants and presented Warburg impedance at low frequencies.

Effects of chloride ion concentration and pH values on the corrosion behavio of Cr12Ni3Co12Mo4W ultra-high-strength martensitic stainless steel

The effects of Cl ion concentration and pH values on the corrosion behavior of Cr12Ni3Co12Mo4W ultra-high-strength martensitic stainless steel（UHSMSS） were investigated by a series of electrochemical tests combined with observations by stereology microscopy and scanning electron microscopy. A critical Cl- ion concentration was found to exist（approximately 0.1wt%）, above which pitting occurred. The pitting potential decreased with increasing Cl- ion concentration. A UHSMSS specimen tempered at 600°C exhibited a better pitting corrosion resistance than the one tempered at 400°C. The corrosion current density and passive current density of the UHSMSS tempered at 600°C decreased with increasing pH values of the corrosion solution. The pits developed a shallower dish geometry with increasing polarization potential. A lacy cover on the pits of the UHSMSS tempered at 400°C accelerated pitting, whereas corrosion products deposited in the pits of the UHSMSS tempered at 600°C hindered pitting.

Atmospheric Corrosion of Q235 Carbon Steel and Q450 Weathering Steel in Turpan,China

Q235carbon steel and Q450 weathering steel were exposed to the hot and dry environment of Turpan,China for three years.The corrosion rates of both steels were calculated and compared.The morphologies of the rust layer products were observed by optical microscopy and scanning electron microscopy.Analyses of the rust layers were performed by X-ray photoelectron spectroscopy,X-ray powder diffraction,and Raman spectroscopy,and analysis results indicate that the compositions of rust are main iron rich oxide such as FeOOH,Fe_3O_4,and Fe_2O_3.The iron oxide layer content proportion was calculated through a semi-quantitative algorithm.The resistance elements（Cr,Ni,and Cu）enhanced the resistance properties of the Q450 weathering steel matrix.Moreover,the resistance elements increased the proportion of goethite crystals in the corroded rust layer.

Stress corrosion cracking behavior of PH13-8Mo stainless steel in Cl^- solutions

The stress corrosion cracking（ SCC） behavior of PH13-8Mo precipitation hardening stainless steel（ PHSS） in neutral NaCl solutions was investigated through slow-strain-rate tensile（ SSRT） test at various applied potentials. Fracture morphology,elongation ratio,and percentage reduction of area were measured to evaluate the SCC susceptibility. A critical concentration of 1. 0 mol / L neutral NaCl existed for SCC of PH13-8Mo steel. Significant SCC emerged when the applied potential was more negative than -0. 15 VSCE,and the SCC behavior was controlled by an anodic dissolution（ AD） process.When the applied potential was lower than -0. 55 VSCE,an obvious hydrogen-fracture morphology was observed,which indicated that the SCC behavior was controlled by hydrogen-induced cracking（ HIC）.Between -0. 15 and -0. 35 VSCE,the applied potential exceeded the equilibrium hydrogen evolution potential in neutral NaCl solutions and the crack tips were of electrochemical origin in the anodic region; thus,the SCC process was dominated by the AD mechanism.

Electrochemical behaviors of magnesium alloy with phosphate conversion coating in NaCl solutions

A composite conversion coating was prepared on magnesium alloy by the only one-step immersion treatment. The characteristics of the conversion coating were investigated by scanning electron microscopy （SEM） and X-ray photoelectron spectroscopy （XPS）. The results indicate that the composite conversion coating consists of magnesium hydroxide, magnesium phosphate and man- ganese phosphate. The electrochemical behavior of the conversion coating was investigated systematically by electrochemical impedance spectroscopy （EIS） and poten- tiodynamic polarization measurement in different NaC1 solutions. Polarization measurements and EIS results reveal that the magnesium alloy with the conversion coating have better corrosion resistance compared to the bare magnesium alloy in these conditions. And the corro- sion rate of the magnesium alloy with conversion coating increases consistently with the chloride ion concentration. In alkaline conditions, the magnesium alloy with conver- sion coating has superior corrosion resistance by the syn- ergistic effects between Mg（OH）2 film and conversion coating. Moreover, the electrochemical corrosion mechanism of the magnesium alloy was analyzed with respect to the conversion coating in a Cl^- containing environment.

Relationship Between Microstructure and Corrosion Behavior of Cr12Ni3Co12Mo4W Ultra-High-Strength Martensitic Stainless Steel

The effect of tempering temperature on the microstructure and corrosion behavior of Cr12Ni3Co12Mo4W ultra-high-strength martensitic stainless steel was investigated using transmission electron microscopy, atomic force microscopy, X-ray diffraction, and electrochemical tests. The microstructures of the ultra-high-strength martensitic stainless steel consisted of some retained austenite and lath/plant martensite with the carbides distributed within the matrix and at the grain boundaries. Tempering of the steel for 4 h at various temperatures resulted in various carbide grain sizes and different amounts of the retained austenite. The results showed that larger carbide grains led to diminished corrosion resistance, whereas larger amounts of the retained austenite resulted in improved corrosion resistance. The steels exhibited good corrosion resistance in 0.017 mol/L NaCl solution and exhibited pitting corrosion in 0.17 mol/L Na Cl solution. The martensite and prior austenite crystal boundaries dissolved in solution with pH 1.

Atmospheric corrosion behavior of low-alloy steels in a tropical marine environment

The corrosion behavior of carbon steels and weathering steels was investigated in a tropical marine environment.And both exhibited similar corrosion weight-loss behavior in tropical marine environments.Corrosion weight loss(W)as a function of exposure time(t)can be calculated using the power function,W=A^tn.The values of the initial corrosion rate,A,and corrosion tendency,n,can be easily obtained by taking the logarithm of the power equation.However,the corrosion rust-layer structure of the two materials was quite different.The rust layer of carbon steel presents a single-layer structure.Meanwhile,the rust layer of weathering steel exhibits a single-layer structure after exposure for about 24 months and then gradually evolves into a double-layer structure.The main corrosion products of the steels areβ-FeOOH,γ-FeOOH,and Fe3O4 in the initial stage of exposure.In the rust layers,α-FeOOH appeared after 12 months of exposure.