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经典肉桂酸合成实验的改进与拓展
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作者 高庆英 罗涛 +6 位作者 苏建源 俞超凡 李家柱 焉炳飞 李文佐 张震 刘义 《大学化学》 CAS 2024年第5期243-250,共8页
肉桂酸合成实验是高等学校现行《有机化学实验》教材中的一个重要单列基础实验。该实验在教学实施过程中暴露出残余苯甲醛气味难闻、原料对水敏感、购存困难、高温副产物多等问题。针对以上问题,本论文对经典肉桂酸合成实验进行了改进:... 肉桂酸合成实验是高等学校现行《有机化学实验》教材中的一个重要单列基础实验。该实验在教学实施过程中暴露出残余苯甲醛气味难闻、原料对水敏感、购存困难、高温副产物多等问题。针对以上问题,本论文对经典肉桂酸合成实验进行了改进:采用苯甲醛/丙二酸/三乙烯二胺的均相反应体系制备肉桂酸,采用亚硫酸氢钠洗涤、萃取的后处理方法去除残余苯甲醛,使其更符合现代实验教学和绿色化学的要求。改进后的实验不仅可有效去除难闻的残余苯甲醛,还具有原料稳定性好、价格低廉、后处理操作简单等优点。通过增加波谱学表征、柱色谱分离等环节,该实验可以拓展为以精细化学品阿魏酸为合成目标的8学时综合性创新实验,提高对学生化学综合素质的培养。 展开更多
关键词 肉桂酸 合成实验 亚硫酸氢钠 实验创新
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Impact of air pressure variations on electrical vehicle motor insulation
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作者 Peng Wang chaofan yu +2 位作者 Shakeel Akram Ziyuan Fan Wenhuan Zhao 《High Voltage》 SCIE EI CSCD 2023年第5期1011-1019,共9页
Variation in air pressure severely affects the insulation of electric vehicle(EV)motors,hence weakening the reliability of EVs for safe operation.Nomex‐polyimide‐Nomex,a typical insulation material for EV motors,was... Variation in air pressure severely affects the insulation of electric vehicle(EV)motors,hence weakening the reliability of EVs for safe operation.Nomex‐polyimide‐Nomex,a typical insulation material for EV motors,was used to investigate the motor insulation performance under different air pressures.The results show that the partial discharge inception voltage is significantly reduced for EV motors operated at lower air pressures,and the probability of partial discharge(PD)occurrence is increased.The macroscopic results reveal that the active area of the PD expands at low pressure,while the non‐corroded ring appears in the centre.Additionally,although the number and amplitude of the PD increase significantly with decrease in air pressure,the active area of the PD expands and electrical stress on the insulation per unit area increases slowly.Therefore,when the pressure decreased from 60 to 40 kPa,the endurance life does not show a significant downward trend.Furthermore,the dielectric constant and loss of the low‐pressure samples significantly change during the ageing process,which further indicates critical degradation of the insulation.The aforementioned investigations reveal that the air pressure at different altitudes has a significant impact on the performance of insulation materials. 展开更多
关键词 INSULATION ELECTRICAL IMPACT
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