利用单边缺口拉伸试验方法对壁厚31.8 mm L485管线钢管环焊接头热影响区进行断裂韧性CTOD(crack tip opening displacement)测试,应用数理统计方法对测试结果进行分布拟合,采用A-D检验和K-S检验,确定了L485管线钢管环焊接头热影响区CTO...利用单边缺口拉伸试验方法对壁厚31.8 mm L485管线钢管环焊接头热影响区进行断裂韧性CTOD(crack tip opening displacement)测试,应用数理统计方法对测试结果进行分布拟合,采用A-D检验和K-S检验,确定了L485管线钢管环焊接头热影响区CTOD的最优分布规律.结果表明,δ_(m)和δ_(0.2)分别服从正态和对数正态分布,并获得了二者的特定分位数CTOD值.对比分析发现,MOTE方法确定的CTOD值在概率分布的5%~10%分位数之间.正态分布10%分位数值(δ_(m))和对数正态分布5%分位数值(δ_(0.2))与BS7910推荐做法保持一致,说明CTOD特征值概率分布函数的分位数法是处理离散断裂韧性合理可行的方法.展开更多
A copper-based non-aqueous-phase desulfurization agent is prepared by adding CuCl_(2) to the solvent N,Ndimethylformamide(DMF).Static desulfurization experiments show that the agent has high efficiency.However,the des...A copper-based non-aqueous-phase desulfurization agent is prepared by adding CuCl_(2) to the solvent N,Ndimethylformamide(DMF).Static desulfurization experiments show that the agent has high efficiency.However,the desulfurization reaction leads to the formation of a copper sulfide precipitate.It is found that the addition of chloride ions in the form of hydrochloric acid or potassium chloride prevents the formation of copper sulfide,and elemental sulfur is precipitated instead.The efficient absorption of H2S by the Cu/HCl–DMF agent relies on the rapid coordination of Cu^(2+)with DMF,Cl^(−),and H2S molecules to form a[Cu(DMF)_(n−p)(HS−)_(p)(Cl−)_(m)]_((2−p−m))+complex.The desulfurization agent has a sulfur capacity of up to 9.81 g/L when used in static bubble desulfurization at atmospheric pressure.The system has low viscosity and good chemical and thermal stability.It can be rapidly regenerated through continuous oxidation.After five repetitions of the regeneration procedure,the sulfur capacity reaches more than 91%of the initial capacity,indicating the potential of the system for commercial applications.展开更多
In this experiment,an EG/ChCl deep eutectic solvent(DES)was synthesized using choline chloride(ChCl)and ethylene glycol(EG)as the raw materials.The synthesized DES was characterized by Fourier transform infrared spect...In this experiment,an EG/ChCl deep eutectic solvent(DES)was synthesized using choline chloride(ChCl)and ethylene glycol(EG)as the raw materials.The synthesized DES was characterized by Fourier transform infrared spectroscopy and thermogravimetric analysis.The results demonstrate the successful synthesis of DES.A certain amount of FeCl_(3) and CuSO_(4) was added to the DES to promote the absorption of H_(2)S;thus,a Fe(Ⅲ)-Cu(Ⅱ)coupled DES desulfurization system was obtained.The effects of DES raw materials’ratio,FeCl_(3) concentration,water content,CuSO_(4) concentration,and reaction temperature on the desulfurization efficiency and the regeneration conditions were studied.The results show that ChCl/EG DES with a molar ratio of 1:2 has a better desulfurization effect,and the addition of an appropriate amount of water can effectively promote the dissolution of CuSO_(4) and the absorption of H_(2)S.An appropriate increase in reaction temperature and CuSO_(4) concentration would also promote the absorption of H_(2)S.When the concentration of CuSO_(4) in DES desulfurizer was 0.15 mol/L,the gas speed was 20 mL/min,and the sulfur capacity could reach 10.23 g/L.The desulfurizer could be regenerated by passing O_(2),and the desulfurization efficiency did not change much after repeated use of desulfurization-regeneration many times.The desulfurization product was characterized by XRD as rhombohedral sulfur.展开更多
文摘利用单边缺口拉伸试验方法对壁厚31.8 mm L485管线钢管环焊接头热影响区进行断裂韧性CTOD(crack tip opening displacement)测试,应用数理统计方法对测试结果进行分布拟合,采用A-D检验和K-S检验,确定了L485管线钢管环焊接头热影响区CTOD的最优分布规律.结果表明,δ_(m)和δ_(0.2)分别服从正态和对数正态分布,并获得了二者的特定分位数CTOD值.对比分析发现,MOTE方法确定的CTOD值在概率分布的5%~10%分位数之间.正态分布10%分位数值(δ_(m))和对数正态分布5%分位数值(δ_(0.2))与BS7910推荐做法保持一致,说明CTOD特征值概率分布函数的分位数法是处理离散断裂韧性合理可行的方法.
基金the China National Science and Technology Major Project(2016ZX05017)the Sinopec Group Corporation 2020 Science and Technology Project“Organic Sulfur Catalytic Hydrolysis Technology Improves Quality Research”(No.120049-1).
文摘A copper-based non-aqueous-phase desulfurization agent is prepared by adding CuCl_(2) to the solvent N,Ndimethylformamide(DMF).Static desulfurization experiments show that the agent has high efficiency.However,the desulfurization reaction leads to the formation of a copper sulfide precipitate.It is found that the addition of chloride ions in the form of hydrochloric acid or potassium chloride prevents the formation of copper sulfide,and elemental sulfur is precipitated instead.The efficient absorption of H2S by the Cu/HCl–DMF agent relies on the rapid coordination of Cu^(2+)with DMF,Cl^(−),and H2S molecules to form a[Cu(DMF)_(n−p)(HS−)_(p)(Cl−)_(m)]_((2−p−m))+complex.The desulfurization agent has a sulfur capacity of up to 9.81 g/L when used in static bubble desulfurization at atmospheric pressure.The system has low viscosity and good chemical and thermal stability.It can be rapidly regenerated through continuous oxidation.After five repetitions of the regeneration procedure,the sulfur capacity reaches more than 91%of the initial capacity,indicating the potential of the system for commercial applications.
基金China National Science and Technology Major Project(2016ZX05017)Sinopec Group Corporation 2020 Science and Technology Project“Organic Sulfur Catalytic Hydrolysis Technology Improves Quality Research”(No.120049-1).
文摘In this experiment,an EG/ChCl deep eutectic solvent(DES)was synthesized using choline chloride(ChCl)and ethylene glycol(EG)as the raw materials.The synthesized DES was characterized by Fourier transform infrared spectroscopy and thermogravimetric analysis.The results demonstrate the successful synthesis of DES.A certain amount of FeCl_(3) and CuSO_(4) was added to the DES to promote the absorption of H_(2)S;thus,a Fe(Ⅲ)-Cu(Ⅱ)coupled DES desulfurization system was obtained.The effects of DES raw materials’ratio,FeCl_(3) concentration,water content,CuSO_(4) concentration,and reaction temperature on the desulfurization efficiency and the regeneration conditions were studied.The results show that ChCl/EG DES with a molar ratio of 1:2 has a better desulfurization effect,and the addition of an appropriate amount of water can effectively promote the dissolution of CuSO_(4) and the absorption of H_(2)S.An appropriate increase in reaction temperature and CuSO_(4) concentration would also promote the absorption of H_(2)S.When the concentration of CuSO_(4) in DES desulfurizer was 0.15 mol/L,the gas speed was 20 mL/min,and the sulfur capacity could reach 10.23 g/L.The desulfurizer could be regenerated by passing O_(2),and the desulfurization efficiency did not change much after repeated use of desulfurization-regeneration many times.The desulfurization product was characterized by XRD as rhombohedral sulfur.
