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纳米线状α-MnO_(2)电极材料的制备及电催化性能的研究
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作者 陈健 陈庆伦 +1 位作者 韩宁 何立子 《功能材料》 CAS CSCD 北大核心 2024年第8期8027-8033,8089,共8页
以KMnO_(4)和MnCl_(2)·4H_(2)O为原料通过水热法制备出二氧化锰电极材料,利用SEM、XRD观察材料的微观形貌并确定其晶型,通过放电测试和电化学测试研究二氧化锰作为电极材料的ORR电催化性能。研究结果表明,水热反应温度为180℃、KMn... 以KMnO_(4)和MnCl_(2)·4H_(2)O为原料通过水热法制备出二氧化锰电极材料,利用SEM、XRD观察材料的微观形貌并确定其晶型,通过放电测试和电化学测试研究二氧化锰作为电极材料的ORR电催化性能。研究结果表明,水热反应温度为180℃、KMnO_(4)∶MnCl_(2)·4H_(2)O摩尔比为2.5∶1时,能够制得均匀纳米线状的α-MnO_(2),其作为催化剂制备的空气阴极在极化电压为1.0 V时极化电流密度最大,达到76.15 mA/cm^(2),并且具有最小的阻抗,说明氧还原反应阻力最小,在10,20,30,40 mA/cm^(2)电流密度下放电电压分别为1.64,1.49,1.36和1.23 V,放电性能相较于5%铂碳催化剂提升10%左右。 展开更多
关键词 二氧化锰 电催化 放电性能 空气阴极
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热轧变形量对Al0.4Mg0.2Mn0.1Sn阳极合金电化学性能的影响
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作者 陈庆伦 何立子 +2 位作者 李力爽 王美洋 王宇钦 《轻合金加工技术》 CAS 2024年第2期39-44,49,共7页
添加适量的Mg、Mn和Sn等合金元素制备了性能良好的Al0.4Mg0.2Mn0.1Sn阳极合金。采用析氢速率测试、电化学测试、恒流放电测试、显微组织和腐蚀形貌观察,分析不同热轧变形量对该阳极合金活性的影响。结果表明:适当的热轧变形量使阳极合... 添加适量的Mg、Mn和Sn等合金元素制备了性能良好的Al0.4Mg0.2Mn0.1Sn阳极合金。采用析氢速率测试、电化学测试、恒流放电测试、显微组织和腐蚀形貌观察,分析不同热轧变形量对该阳极合金活性的影响。结果表明:适当的热轧变形量使阳极合金组织均匀,晶粒宽度变小,晶粒细化;适当的热轧变形量提升了该阳极合金的电化学性能,降低了腐蚀速率,改善了腐蚀形貌。Al0.4Mg0.2Mn0.1Sn阳极合金在60%热轧变形量下,自腐蚀速率最低,为0.167 mL(min·cm^(2));在60 mA/cm^(2)电流密度下的放电电压达到1.27 V,最大功率密度为53.65 mW/cm^(2)。 展开更多
关键词 Al0.4Mg0.2Mn0.1Sn阳极合金 热轧变形量 析氢 电化学性能:放电电压
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Uniform Elongation and Yield-Drop Phenomenon in Magnetically Annealed 1050 Aluminum Alloy Prepared by CryoECAP
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作者 He Lizi chen Jian +4 位作者 chen qinglun Han Ning Li Lishuang Wang Meiyang Wang Yuqin 《稀有金属材料与工程》 SCIE EI CAS CSCD 北大核心 2023年第9期2993-3002,共10页
The ultrafine grained(UFG)1050 aluminum alloy was prepared by equal channel angular pressing at cryogenic temperature,namely cryoECAP process.The tensile behavior and microstructures of UFG 1050 aluminum alloy after a... The ultrafine grained(UFG)1050 aluminum alloy was prepared by equal channel angular pressing at cryogenic temperature,namely cryoECAP process.The tensile behavior and microstructures of UFG 1050 aluminum alloy after annealing at 90-210°C for 4 h without and with high magnetic field of 12 T were investigated by tensile tests,transmission electron microscope,and electron backscattered diffraction analyses.After cryoECAP and annealing treatments,the 1050 aluminum alloy has ultrafine grains with 0.7-1.28μm in size,the ratio of ultimate tensile strength to yield strength is less than 1.24,and the uniform elongation is less than 2.3%.With increasing the annealing temperature from 90°C to 210°C,the yield-drop phenomenon becomes more obvious due to the decrease in mobile dislocations to maintain the applied strain rate during tensile deformation.The uniform elongation decreases from 1.55%to 0.55%,the dislocation density reduces from 5.6×10^(14)m^(−2)to 4.2×10^(13)m^(−2),and the fraction of high-angle grain boundaries(HABs)increases from 63.8%to 70.8%.These phenomena cause the higher annihilation rate of dislocations,thereby leading to the degradation of strain hardening effect.During annealing under high magnetic field at 90-210°C,the low fraction of HABs(61.7%-66.2%)can provide a slower annihilation rate of dislocations,therefore resulting in the higher uniform elongation(0.64%-1.60%)and slower decrease in the flow stress after the yield peak. 展开更多
关键词 magnetic annealing ultrafine grain uniform elongation yield-drop phenomenon high-angle grain boundaries dislocations
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