Three displacement functions are introduced to represent each mechanical displacement according to the 3-D theory in this paper. By expanding the displacement functions and the electric potential in orthogonal series,...Three displacement functions are introduced to represent each mechanical displacement according to the 3-D theory in this paper. By expanding the displacement functions and the electric potential in orthogonal series, the free vibration equation of piezoelectric cylindrical shells satisfying SS3 boundary conditions can be obtained. The equation was solved by utilizing Bessel functions with complex arguments. Results are presented graphically as well as in table, and compared with those of other references. Some frequencies that were missing in Ref. [9] are discovered.展开更多
Electroactive self-assembled monolayers (SAMs) containing viologen group are formed through the adsorption of thiol-functionalized viologen compound CH3(CH2)(9)V2+(CH2)(8)SH, where V2+ is N,N'-dialkylbipyridinium ...Electroactive self-assembled monolayers (SAMs) containing viologen group are formed through the adsorption of thiol-functionalized viologen compound CH3(CH2)(9)V2+(CH2)(8)SH, where V2+ is N,N'-dialkylbipyridinium (i.e. a viologen group), onto gold electrodes from methanol/water solution and its electrochemical behavior is investigated ty Ac voltammetry and square wave voltammetry, which have the high sensitivity against background charging. The viologen SAM formed is a sub-monolayer and the normal potentials corresponding to the two successive one-electron transfer processes of the active centers (viologen) are -360 mV and -750 mV (vs. Ag/AgCl) in 0.1 mol/L phosphate buffer solutions (pH 6.96) respectively, and the standard electron transfer rate constant is 9.0 s(-1). The electrochemical behavior of this SAM in various solutions has been preliminarily discussed.展开更多
基金The project is supported by National Natural Science Foundation of ChinaZhejiang Provincial Natural Science Foundation of China.
文摘Three displacement functions are introduced to represent each mechanical displacement according to the 3-D theory in this paper. By expanding the displacement functions and the electric potential in orthogonal series, the free vibration equation of piezoelectric cylindrical shells satisfying SS3 boundary conditions can be obtained. The equation was solved by utilizing Bessel functions with complex arguments. Results are presented graphically as well as in table, and compared with those of other references. Some frequencies that were missing in Ref. [9] are discovered.
基金Project supported by the National Natural Science Foundation of China.
文摘Electroactive self-assembled monolayers (SAMs) containing viologen group are formed through the adsorption of thiol-functionalized viologen compound CH3(CH2)(9)V2+(CH2)(8)SH, where V2+ is N,N'-dialkylbipyridinium (i.e. a viologen group), onto gold electrodes from methanol/water solution and its electrochemical behavior is investigated ty Ac voltammetry and square wave voltammetry, which have the high sensitivity against background charging. The viologen SAM formed is a sub-monolayer and the normal potentials corresponding to the two successive one-electron transfer processes of the active centers (viologen) are -360 mV and -750 mV (vs. Ag/AgCl) in 0.1 mol/L phosphate buffer solutions (pH 6.96) respectively, and the standard electron transfer rate constant is 9.0 s(-1). The electrochemical behavior of this SAM in various solutions has been preliminarily discussed.
