Solar-driven interfacial evaporation is an emerging technology for water desalination.Generally,double-layered structure with separate surface wettability properties is usually employed for evaporator construction.How...Solar-driven interfacial evaporation is an emerging technology for water desalination.Generally,double-layered structure with separate surface wettability properties is usually employed for evaporator construction.However,creating materials with tunable properties is a great challenge because the wettability of existing materials is usually monotonous.Herein,we report vinyltrimethoxysilane as a single molecular unit to hybrid with bacterial cellulose(BC)fibrous network,which can be built into robust aerogel with entirely distinct wettability through controlling assembly pathways.Siloxane groups or carbon atoms are exposed on the surface of BC nanofibers,resulting in either superhydrophilic or superhydrophobic aerogels.With this special property,single component-modified aerogels could be integrated into a double-layered evaporator for water desalination.Under 1 sun,our evaporator achieves high water evaporation rates of 1.91 and 4.20 kg m^(-2)h^(-1)under laboratory and outdoor solar conditions,respectively.Moreover,this aerogel evaporator shows unprecedented lightweight,structural robustness,long-term stability under extreme conditions,and excellent salt-resistance,highlighting the advantages in synthesis of aerogel materials from the single molecular unit.展开更多
Despite the impressive progress of stimuli-responsive fluorescent materials,little is known about the influence of confinement created by crystalline polymer over the fluorescence properties of fluorescent molecules.T...Despite the impressive progress of stimuli-responsive fluorescent materials,little is known about the influence of confinement created by crystalline polymer over the fluorescence properties of fluorescent molecules.The effects of confinement on the fluorescence of an aggregation-induced emission luminogen(AIEgen)are investigated using computational simulations,which reveal that the confined space induces the AIEgens to take a more planar conformation,resulting in a red-shifted emission spectrum.With this property,the study is extended to explore the confinement generated by various polymer crystalline forms,and it is shown that different fluorescence colors are activated.This confinement fluorescence effect is attributed to the different spatial dimensions of the polymer amorphous layer between lamellar crystals where the AIEgens are located.These results indicate the immediate association between crystalline structure and fluorescence signals,activating unprecedented photophysical properties of luminescent materials,and also providing the possibility for crystalline structure visualization,it is important for the many polymer crystallization processes occurring in the materials processing.展开更多
基金supported by the National Key Research and Development Program of China(2021YFB3701603)National Science Foundation of China(51973030,52103075)+6 种基金Shanghai Rising-Star Program(20QA1400100)Science and Technology Commission of Shanghai Municipality(20JC1414900)China Postdoctoral Science Foundation(2022M710664,2022T150111)China Postdoctoral Science Foundation(2022M710663)the Fundamental Research Funds for the Central Universities“DHU”Distinguished Young Professor Program(LZB2021001)State Key Laboratory for Modification of Chemical Fibers and Polymer Materials,Donghua University。
文摘Solar-driven interfacial evaporation is an emerging technology for water desalination.Generally,double-layered structure with separate surface wettability properties is usually employed for evaporator construction.However,creating materials with tunable properties is a great challenge because the wettability of existing materials is usually monotonous.Herein,we report vinyltrimethoxysilane as a single molecular unit to hybrid with bacterial cellulose(BC)fibrous network,which can be built into robust aerogel with entirely distinct wettability through controlling assembly pathways.Siloxane groups or carbon atoms are exposed on the surface of BC nanofibers,resulting in either superhydrophilic or superhydrophobic aerogels.With this special property,single component-modified aerogels could be integrated into a double-layered evaporator for water desalination.Under 1 sun,our evaporator achieves high water evaporation rates of 1.91 and 4.20 kg m^(-2)h^(-1)under laboratory and outdoor solar conditions,respectively.Moreover,this aerogel evaporator shows unprecedented lightweight,structural robustness,long-term stability under extreme conditions,and excellent salt-resistance,highlighting the advantages in synthesis of aerogel materials from the single molecular unit.
基金the National Science Foundation of China,Grant/Award Numbers:51973030,52127805,52273031,22173017the Science and Technology Commission of Shanghai Municipality,Grant/Award Numbers:20JC1414900,22511103900+3 种基金the Shanghai Rising-Star Program,Grant/Award Number:20QA1400100the China Postdoctoral Science Foundation,Grant/Award Numbers:2022M710664,2022M710663,2022T150111the Fundamental Research Funds for the Central Universities,Grant/Award Numbers:2232021A-06,22D210613“DHU”Distinguished Young Professor Program,Grant/Award Number:LZB2021001。
文摘Despite the impressive progress of stimuli-responsive fluorescent materials,little is known about the influence of confinement created by crystalline polymer over the fluorescence properties of fluorescent molecules.The effects of confinement on the fluorescence of an aggregation-induced emission luminogen(AIEgen)are investigated using computational simulations,which reveal that the confined space induces the AIEgens to take a more planar conformation,resulting in a red-shifted emission spectrum.With this property,the study is extended to explore the confinement generated by various polymer crystalline forms,and it is shown that different fluorescence colors are activated.This confinement fluorescence effect is attributed to the different spatial dimensions of the polymer amorphous layer between lamellar crystals where the AIEgens are located.These results indicate the immediate association between crystalline structure and fluorescence signals,activating unprecedented photophysical properties of luminescent materials,and also providing the possibility for crystalline structure visualization,it is important for the many polymer crystallization processes occurring in the materials processing.