The synchronous construction of metal phosphate and phosphorus-doped carbon structures is of great significance to innovate the design,synthesis,and application of catalysts,as these phosphoruscontaining composite mat...The synchronous construction of metal phosphate and phosphorus-doped carbon structures is of great significance to innovate the design,synthesis,and application of catalysts,as these phosphoruscontaining composite materials have shown a remarkable contribution to electrocatalysts.However,their preparation procedure generally involves using large amounts of excess phosphorus sources for phosphorization,which inevitably release poisonous PH_(3) or dangerous phosphorus vapor.Here,a strategy for in-situ formation of FePO_(4) embedded in P-doped carbon 2D nano film(FePO_(4)/PdC)is developed using a highly integrated precursor,which is a small molecular organophosphine ligand,1,1’bis(diphenylphosphine)ferrocene(DPPF).The multi-source precursor DPPF that contains Fe,P,and C is molecular-vapor-deposited on the nickel foam(NF)supported ZIF-67 nanosheets to obtain the composite catalyst,namely DPPF-500/ZIF-67/NF.FePO_(4)/PdC encapsulated the ZIF-67 derived Co/N-doped carbon matrix(Co NC)to form a sandwich structure FePO_(4)/PdC@CoNC.The constructed catalyst shows good performance for OER,requiring an overpotential of only 297 m V to deliver 600 m A/cm^(2) with a Tafel slope of 42.7 m V dec^(-1).DFT calculations demonstrate that the synergistic effects between the metal active center and P-doped carbon film reduce the energy barriers and improve electron transport.This method of constructing P-containing catalysts overcomes the demand for additional P sources to realize eco-friendly fabrication and yields a unique structure with good catalytic activity.展开更多
Synchronous reluctance machines(SynRMs)have drawn increasing attention in recent years owing to their advantages such as low cost,simple structure,ease of manufacture,and high robustness.The main obstacle to the promo...Synchronous reluctance machines(SynRMs)have drawn increasing attention in recent years owing to their advantages such as low cost,simple structure,ease of manufacture,and high robustness.The main obstacle to the promotion of SynRMs is severe parameter nonlinearity,which deteriorates drive performance.Sensorless control methods for SynRMs are critical technologies that can broaden the industrial applications of SynRMs.Various methods of parameter identification and sensorless control strategies are reviewed and discussed,including self-commissioning,which is analyzed in detail.Furthermore,sensorless control strategies that can improve the industrial application of SynRMs are described.Finally,future research trends concerning SynRMs are analyzed and discussed.展开更多
基金financially supported by the National Natural Science Foundation of China(21872020)the 1226 Engineering Health Major Project(BWS17J028,AWS16J018)the Fundamental Research Funds for the Central Universities(N180705004)。
文摘The synchronous construction of metal phosphate and phosphorus-doped carbon structures is of great significance to innovate the design,synthesis,and application of catalysts,as these phosphoruscontaining composite materials have shown a remarkable contribution to electrocatalysts.However,their preparation procedure generally involves using large amounts of excess phosphorus sources for phosphorization,which inevitably release poisonous PH_(3) or dangerous phosphorus vapor.Here,a strategy for in-situ formation of FePO_(4) embedded in P-doped carbon 2D nano film(FePO_(4)/PdC)is developed using a highly integrated precursor,which is a small molecular organophosphine ligand,1,1’bis(diphenylphosphine)ferrocene(DPPF).The multi-source precursor DPPF that contains Fe,P,and C is molecular-vapor-deposited on the nickel foam(NF)supported ZIF-67 nanosheets to obtain the composite catalyst,namely DPPF-500/ZIF-67/NF.FePO_(4)/PdC encapsulated the ZIF-67 derived Co/N-doped carbon matrix(Co NC)to form a sandwich structure FePO_(4)/PdC@CoNC.The constructed catalyst shows good performance for OER,requiring an overpotential of only 297 m V to deliver 600 m A/cm^(2) with a Tafel slope of 42.7 m V dec^(-1).DFT calculations demonstrate that the synergistic effects between the metal active center and P-doped carbon film reduce the energy barriers and improve electron transport.This method of constructing P-containing catalysts overcomes the demand for additional P sources to realize eco-friendly fabrication and yields a unique structure with good catalytic activity.
基金Supported by the National Natural Science Foundation of China(51807037)the Power Electronics Science and Education Development Program of Delta Group(DREG2019003).
文摘Synchronous reluctance machines(SynRMs)have drawn increasing attention in recent years owing to their advantages such as low cost,simple structure,ease of manufacture,and high robustness.The main obstacle to the promotion of SynRMs is severe parameter nonlinearity,which deteriorates drive performance.Sensorless control methods for SynRMs are critical technologies that can broaden the industrial applications of SynRMs.Various methods of parameter identification and sensorless control strategies are reviewed and discussed,including self-commissioning,which is analyzed in detail.Furthermore,sensorless control strategies that can improve the industrial application of SynRMs are described.Finally,future research trends concerning SynRMs are analyzed and discussed.
