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On electro-acoustic characteristics of a marine broadband sparker for seismic exploration
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作者 Jing LI Kai liu +3 位作者 Liancheng ZHANG chenguang liu Yanliang PEI Baohua liu 《Journal of Oceanology and Limnology》 SCIE CAS CSCD 2024年第3期760-771,共12页
The construction of major marine infrastructure projects and the exploration and development of deep-sea mineral resources require fine imaging of seabed strata and structures.The highresolution marine seismic explora... The construction of major marine infrastructure projects and the exploration and development of deep-sea mineral resources require fine imaging of seabed strata and structures.The highresolution marine seismic exploration based on a high broadband sparker source is an important approach to reveal seabed stratum and reservoir structure,and identify geohazard.To optimize the performance of sparker seismic source,we investigated the electro-acoustic characteristics of spark discharge under conditions of different charging voltages and electrode numbers.Results show that the sound source level increased with the increase of the charging voltage,whereas the main frequency decreased when the charging voltage increases.In addition,it was found that the charging capacitance had more obvious influence on the main frequency than the sound source level did.Although the load energy decreased with increasing electrode number,the sound source level still increased but the main frequency decreased.Meanwhile,the primary to bubble(P/B)ratio increased with the increase of the electrode number.To gain a deeper insight into the electro-acoustic characteristics,we investigate the relationship between sound source level and power peak,from which a good correlation was observed.A more practical statistical analysis on the rise rate of current was processed,and a perfect logarithmic function was derived.Furthermore,we found that the main frequency was most possibly subjected to the electrical energy,especially the charging energy per electrode.The results indicate that the charging energy per electrode less than 10 J could increase the main frequency to above 300 Hz.At last,the main frequency could be reduced to 20 Hz when the charging energy of a single-electrode discharge was enhanced to over 4 kJ.This study shall be helpful in developing a sparker seismic source and improving the performance for marine engineering exploration and geohazard assessment. 展开更多
关键词 high-resolution marine seismic exploration sparker seismic source sound source level main frequency electro-acoustic characteristics
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Characteristics of gravity anomalies and tectonic analysis of Enderby Land in East Antarctica and its adjacent areas
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作者 Long Ma chenguang liu +2 位作者 An Yang Baohua liu Chenglong Xia 《Acta Oceanologica Sinica》 SCIE CAS CSCD 2023年第2期94-103,共10页
Enderby Land in East Antarctica and its adjacent areas,which are closely related to the Indian Plate in their geological evolution,have become one of the key zones for studies on how the Antarctic continent evolves.Ba... Enderby Land in East Antarctica and its adjacent areas,which are closely related to the Indian Plate in their geological evolution,have become one of the key zones for studies on how the Antarctic continent evolves.Based on the isostasy and flexure theories of the lithosphere and using the CRUST1.0 model as the depth constraint,this paper uses the gravity field model EIGEN-6C4 and topographic data to calculate the isostatic gravity anomalies of Enderby Land and its adjacent areas.Then,the crustal thickness of the study area is calculated,and three comprehensive geophysical interpretation profiles that vertically span the study area are plotted.The results show that the flexural isostatic gravity anomalies in Enderby Land and its adjacent areas are closely related to the regional tectonic setting,and the anomalies in different regions differ substantially,ranging from−50×10^(−5)m/s^(2)to 85×10^(−5)m/s^(2).A zone of high isostatic gravity anomalies(30×10^(−5)−80×10^(−5)m/s^(2))is distributed outside the Cooperation Sea and Queen Maud Land,which may be plate remnants generated by early rifting.Except for the Kerguelen Plateau,which was formed by a hotspot and has a crustal thickness of 15 km,the thickness of the oceanic crust in other parts of the study area changes slightly by approximately 4–9 km,with the thinnest part being in Enderby Basin.The thickness of the inland crust along the coastline increases with the elevation,with the maximum thickness reaching 34 km.The isostatic gravity anomalies corresponding to the zone of high magnetic anomalies along the continental margin of Queen Maud Land are negative and small,with an isostatic adjustment trend indicating Moho surface uplift,and those on the edge of central Enderby Land are near zero,approaching the isostatic state,which may be caused by the magmatism at the early stage of rifting.The continental-oceanic boundary should be close to the contour line of the crustal thickness 10–12 km on the outer edge of the coastline. 展开更多
关键词 Enderby Land and its adjacent areas flexural isostatic gravity anomalies crustal structure isostatic adjustment
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高温快速合成纳米MAZ分子筛(英文) 被引量:1
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作者 章芬 章凌 +6 位作者 杨志超 韩世超 朱秋艳 王亮 刘晨光 孟祥举 肖丰收 《Chinese Journal of Catalysis》 SCIE EI CAS CSCD 北大核心 2019年第7期1093-1099,共7页
作为重要的离子交换、吸附、分离与催化材料,沸石分子筛广泛地应用于不同的工业过程中.MAZ(Omega)分子筛的合成往往需要较长的晶化时间,从而限制了它的广泛应用.根据阿伦尼乌斯公式可以判断,提高MAZ沸石分子筛的晶化温度可以大幅度地缩... 作为重要的离子交换、吸附、分离与催化材料,沸石分子筛广泛地应用于不同的工业过程中.MAZ(Omega)分子筛的合成往往需要较长的晶化时间,从而限制了它的广泛应用.根据阿伦尼乌斯公式可以判断,提高MAZ沸石分子筛的晶化温度可以大幅度地缩短晶化时间,达到快速合成沸石分子筛的目的.本文将分子筛晶化温度从100提高到180°C,在3.6 h制得MAZ沸石分子筛.X射线粉末衍射测试(XRD)表明,所合成的样品是具有高纯度和高结晶度的MAZ沸石分子筛.从扫描电镜(SEM)图片可以看出, MAZ-180 (MAZ-T, T代表晶化温度)是由宽200 nm、长2–3μm的纳米棒状组成.为了探究这些纳米棒状构成的形貌是否稳定,将样品进行了超声处理.XRD和SEM结果表明,经过处理的样品仍然具有原来的结晶度与形貌,确认了它们的结构稳定性.高分辨透射图进一步确认了MAZ-180样品的规整微孔结构.热重分析显示该样品在500–700°C出现两个放热峰,这归因于有机模板的燃烧.氮气吸附测试表明, MAZ-180的比表面积为187m^2/g,甚至超过低温合成MAZ的表面积,与它的高结晶度相一致.将氢型MAZ-180(H-MAZ-180)和MAZ-100(H-MAZ-100)分子筛浸渍0.5%Pt后,用于正十二烷的加氢异构反应,发现Pt/H-MAZ-180催化剂总是具有更高的异构产物选择性和更低的裂化产物选择性.这可能是因为MAZ-180样品具有更小的尺寸,更有利于反应中的扩散.MAZ-180沸石分子筛可快速合成的特点及其所表现出的优异的催化性能使其在未来广泛应用于催化反应中成为可能. 展开更多
关键词 沸石分子筛MAZ 快速晶化 高温 铂纳米粒子 加氢异构反应
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Effect of preparation method on the bimetallic NiCu/SAPO-11 catalysts for the hydroisomerization of n-octane 被引量:7
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作者 Zhichao Yang Yunqi liu +4 位作者 Yanpeng Li Lingyou Zeng Zhi liu Xueying liu chenguang liu 《Journal of Energy Chemistry》 SCIE EI CAS CSCD 2019年第1期23-30,共8页
The bimetallic NiCu/SAPO-11 catalysts were prepared by co-impregnation, sequential impregnation, coprecipitation, and mechanical mixing methods. Powder X-ray diffraction, nitrogen adsorption-desorption,temperature-pro... The bimetallic NiCu/SAPO-11 catalysts were prepared by co-impregnation, sequential impregnation, coprecipitation, and mechanical mixing methods. Powder X-ray diffraction, nitrogen adsorption-desorption,temperature-programmed desorption of ammonia, transmission electron microscopy, temperatureprogrammed reduction of hydrogen, and X-ray photoelectron spectroscopy were used to characterize the physicochemical properties of the catalysts. The catalytic performance of the catalysts was assessed by the hydroisomerization of n-octane. Results indicated that the conversion of n-octane and selectivity to n-octane isomers were related to the preparation methods of the catalysts. The catalysts with Ni-Cu alloy effectively restrained the hydrogenolysis reaction that decreases the selectivity of isomerization. The catalyst prepared by the mechanical mixing of NiO and CuO hardly formed Ni-Cu alloy, showing obvious hydrogenolysis and low selectivity to n-octane isomers. The unbalance between the metal and acid sites resulted in the low conversion of n-octane and selectivity to n-octane isomers. Among all the catalysts,the catalyst prepared by the co-impregnation method exhibited high catalytic activity and selectivity to n-octane isomers. 展开更多
关键词 Ni-Cu/SAPO-11 BIMETALLIC Preparation method HYDROISOMERIZATION HYDROGENOLYSIS N-OCTANE
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Ultra-deep desulfurization by reactive adsorption desulfurization on copper-based catalysts 被引量:6
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作者 Yaqing liu Hongying Wang +2 位作者 Jinchong Zhao Yunqi liu chenguang liu 《Journal of Energy Chemistry》 SCIE EI CAS CSCD 2019年第2期8-16,共9页
In this paper,a novel copper-based catalyst for FCC gasoline improving the ability of removal the sulfur and avoiding the loss of the octane number from olefin saturation by reactive adsorption desulfurization(RADS) w... In this paper,a novel copper-based catalyst for FCC gasoline improving the ability of removal the sulfur and avoiding the loss of the octane number from olefin saturation by reactive adsorption desulfurization(RADS) was investigated.The series of Cu/Zn O-Al_2 O_3 catalysts were characterized by X-ray powder diffraction(XRD),N_2 adsorption analysis and temperature-programmed reduction(TPR) studies,X-ray photoelectron spectroscopy(XPS),scanning electron microscope(SEM) and transmission electron microscopy(TEM).The experiment results showed that the catalysts had an optimum desulfurization ability with copper loading 6 wt%,which the sulfur contents of product decreased less than 10 μg/g and olefin contents decreased from 16.19% to 14.14% for the long period operation.The appropriate Cu loading content could lead to the high active and low apparent activation energy(E_a).Therefore,the Cu-based catalyst may become a novel catalyst for second-generation for reactive adsorption desulfurization,which achieves the high desulfurization active and low olefins saturation to satisfy the upgrading the product. 展开更多
关键词 Cu/ZnO-Al2O3 DESULFURIZATION activity OCTANE number OLEFINS SATURATION Stability
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Effect of silicon precursor on silicon incorporation in SAPO-11 and their catalytic performance for hydroisomerization of n-octane on Pt-based catalysts 被引量:3
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作者 Zhichao Yang Jilong Li +1 位作者 Yunqi liu chenguang liu 《Journal of Energy Chemistry》 SCIE EI CAS CSCD 2017年第4期688-694,共7页
SAPO-11 molecular sieves were synthesized using silica sol, hydrophilic fumed silica, and tetraethyl orthosilicate(TEOS) as silicon precursors. Their physicochemical properties were characterized using XRD,SEM, nitr... SAPO-11 molecular sieves were synthesized using silica sol, hydrophilic fumed silica, and tetraethyl orthosilicate(TEOS) as silicon precursors. Their physicochemical properties were characterized using XRD,SEM, nitrogen adsorption-desorption, Py-IR, NH;-TPD, EDS, and;Al,;P,;Si MAS NMR techniques. The catalytic performance was assessed in the hydroisomerization of n-octane. The results showed that the silicon precursors influenced the physicochemical properties and catalytic performance of SAPO-11. SAPO-11 synthesized using hydrophilic fumed silica as silicon precursor showed higher silicon distribution and had more medium acid sites. SAPO-11 synthesized using TEOS as silicon precursor had more silicon content, but more silicon islands formed in its framework. The depolymerization of silicon precursors might affect the silicon content and distribution in SAPO-11. In the hydroisomerization of n-octane, the catalytic activity strongly depended on the number of medium acid sites instead of the number of total acid sites.SAPO-11 synthesized using hydrophilic fumed silica as silicon precursor exhibited higher catalytic activity than the other samples because it has more medium acid sites. 展开更多
关键词 SAPO-11 Silicon precursor Silicon incorporation Acid sites HYDROISOMERIZATION N-OCTANE
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Efficient CO_2 capture on low-cost silica gel modified by polyethyleneimine 被引量:4
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作者 Ke Wang Hongyan Shang +4 位作者 Lin Li Xinlong Yan Zifeng Yan chenguang liu Qingfang Zha 《Journal of Natural Gas Chemistry》 EI CAS CSCD 2012年第3期319-323,共5页
In this work, a series of polyethyleneimine (PEI) functionalized commercial silica gel were prepared by wet impregnation method and used as CO2 sorbent. The as-prepared sorbents were characterized by N2 adsorption, ... In this work, a series of polyethyleneimine (PEI) functionalized commercial silica gel were prepared by wet impregnation method and used as CO2 sorbent. The as-prepared sorbents were characterized by N2 adsorption, FT-1R and SEM techniques. CO2 capture was tested in a fixed bed reactor using a simulated flue gas containing 15.1% CO2 in a temperature range of 25-100 ~C. The effects of sorption temperature and amine content on CO2 uptake of the adsorbents were investigated. The silica gel with a 30 wt% PEI loading manifested the largest CO2 uptake of 93.4 mgcoz/gadsorbent (equal to 311.3 mg^oz/gPEI) among the tested sorbents under the conditions of 15.1% (v/v) CO2 in N2 at 75 ~C and atmospheric pressure. Moreover, it was rather low-cost. In addition, the PEI-impregnated silica gel exhibited stable adsorption-desorption behavior during 5 consecutive test cycles. These results suggest that the PEI-impregnated silica gel is a promising and cost-effective sorbent for CO2 capture from flue gas and other stationary sources with low CO2 concentration. 展开更多
关键词 silica gel C02 capture POLYETHYLENEIMINE flue gas
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States of Carbon Nanotube Supported Mo-Based HDS Catalysts 被引量:1
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作者 Hongyan Shang chenguang liu +2 位作者 Yongqiang Xu Jieshan Qiu Fei Wei 《Journal of Natural Gas Chemistry》 EI CAS CSCD 2006年第3期203-210,共8页
The dispersion of the active phase and loading capacity of the Mo species on carbon nanotube (CNT) was studied by the XRD technique. The reducibility properties of Co-Mo catalysts in the oxide state over CNTs were i... The dispersion of the active phase and loading capacity of the Mo species on carbon nanotube (CNT) was studied by the XRD technique. The reducibility properties of Co-Mo catalysts in the oxide state over CNTs were investigated by TPR, while the sulfided Co-Mo/CNT catalysts were characterized by means of the XRD and LRS techniques. The activity and selectivity with respect to the hydrodesulfurization (HDS) performances on carbon nanotube supported Co-Mo catalysts were evaluated. It was found that the main active molybdenum species in the oxide state MoO3/CNT catalysts were MoO2, but not MoO3, as generally expected. The maximum loading before the formation of the bulk phase was lower than 6% (percent by mass, based on MoO3). TPR studies revealed that the active species in the oxide state Co-Mo/CNT catalysts were reduced more easily at relatively lower temperatures in comparison to those of the Co-Mo/γ-Al2O3 catalysts, indicating that the CNT support promoted or favored the reduction of the active species. The active species of a Co-Mo-0.7/CNT catalyst were more easily reduced than those of the Co-Mo/CNT catalysts with Co/Mo atomic ratios of 0.2, 0.35, and 0.5, respectively, suggesting that the Co/Mo atomic ratio has a great effect on the reducibility of the active species. It was found that the incorporation of cobalt improved the dispersion of the molybdenum species on the support, and a phenomenon of mobilization and re-dispersion had occurred during the sulfurization process, resulting in low valence state Mo3S4 and Co-MoS2.17 active phases. HDS measurements showed that the Co-Mo/CNT catalysts were more active than the Co-Mo/γ-Al2O3 ones for the desulfurization of DBT, and the hydrogenolysis/hydrogenation selectivity of the Co-Mo/CNT catalysts was also much higher than those of the Co-Mo/γ-Al2O3. The Co-Mo/CNT catalyst with a Co/Mo atomic ratio of 0.7 showed the highest activity, whereas the catalyst with a Co/Mo atomic ratio of 0.35 had the highest selectivity. 展开更多
关键词 carbon nanotubes XRD TPR HDS LRS
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Density Functional Investigation of Methanethiol and Dimethyl Sulfide Adsorption on Zeolite 被引量:1
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作者 Renqing Lü Guangmin Qiu chenguang liu 《Journal of Natural Gas Chemistry》 EI CAS CSCD 2006年第2期134-143,共10页
The density functional theory and cluster model methods have been employed to investigate the interactions between methanethiol, dimethyl sulfide and zeolites. The molecular complexes formed by adsorption of methaneth... The density functional theory and cluster model methods have been employed to investigate the interactions between methanethiol, dimethyl sulfide and zeolites. The molecular complexes formed by adsorption of methanethiol or dimethyl sulfide on silanol H3SiOSi(OH)2OSiH3 with five coordination forms or four coordination forms, and complexes formed by interactions of BrSnsted acid sites of bridging hydroxyl H3Si(OH)AI(OH)2OSiH3 with methanethiol or dimethyl sulfide have been investigated. Full optimization and frequency analysis of all cluster models have been carried out using the B3LYP hybrid method at 6-31+G (d,p) basis set level for hydrogen, silicon, aluminum, oxygen, carbon, and sulfur atoms. The structures and energy changes of different coordination forms between methanethiol and H3Si(OH)Al(OH)2OSiH3, dimethyl sulfide and H3Si(OH)Al(OH)2OSiH3, methanethiol and H3SiOSi(OH)2OSiH3, dimethyl sulfide and H3SiOSi(OH)2OSiH3 complexes have been comparatively studied. The calculated results showed the nature of interactions that led to the formation of all complexes was van der Waals force confirmed by an insignificant change of geometric structures and properties. The conclusions that methanethiol and dimethyl sulfide molecules were adsorbed on bridging hydroxyl group prior to silanol group were obtained on the basis of adsorption heat, the most stable adsorption models of a 6 ring structure for interaction between bridging hydroxyl and methanethiol, and a 7 ring structure for interaction between bridging hydroxyl and dimethyl sulfide. 展开更多
关键词 density functional theory METHANETHIOL dimethyl sulfide ZEOLITE model cluster
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Weakening internal diffusion effect in selective hydrodesulfurization of FCC gasoline by novel designed eggshell CoMoS/Al_2O_3 catalysts 被引量:1
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作者 Bin liu Yongming Chai +2 位作者 Yajing Wang Yunqi liu chenguang liu 《Journal of Natural Gas Chemistry》 EI CAS CSCD 2012年第2期194-199,共6页
A simple method for preparation of presulfided eggshell CoMoS/γ-Al2O3 catalysts with sharp boundary is developed, through which the eggshell thicknesses of Co and Mo could be easily regulated by controlling the impre... A simple method for preparation of presulfided eggshell CoMoS/γ-Al2O3 catalysts with sharp boundary is developed, through which the eggshell thicknesses of Co and Mo could be easily regulated by controlling the impregnation time. According to the results characterized by EDS, XRD, HRTEM and FT-IR of adsorbed CO, the active component structures, the nature and/or the amount of active sites on the eggshell catalyst are similar to these on the uniform catalyst. The evaluation results of the catalytic performance in selective hydrodesulfurization (HDS) of FCC gasoline show the presence of significant internal diffusion inhibition effect on HDS of S-compounds especially in the uniform catalyst. Compared with uniform catalyst, the eggshell catalyst could remarkably reduce such an internal diffusion inhibition effect due to a shortened diffusion path of the reactants, thus showing higher HDS activity and selectivity. 展开更多
关键词 CoMoS/γ-Al2O3 eggshell catalyst uniform catalyst internal diffusion HYDRODESULFURIZATION
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Synthesis and characterization of γ-alumina nanospheres templated by lauric acid 被引量:1
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作者 Qingtao Fu Tingting He +2 位作者 lianqing Yu Yongming Chai chenguang liu 《Journal of Natural Gas Chemistry》 EI CAS CSCD 2010年第6期557-559,共3页
A novel route for the synthesis of alumina nanospheres was reported by a surfactant-governed approach in the presence of lauric acid.The products were characterized using X-ray diffraction (XRD),scanning electron mi... A novel route for the synthesis of alumina nanospheres was reported by a surfactant-governed approach in the presence of lauric acid.The products were characterized using X-ray diffraction (XRD),scanning electron microscope (SEM) and N2 adsorption-desorption techniques.The results show that the produced alumina nanospheres possess uniform nanosphere sizes ranging from 80 120 nm,and high surface area of 550 m2/g.It suggests that the synthesized alumina nanospheres are formed through self-assembly of surfactant/alumina species complex in 1-propanol system. 展开更多
关键词 alumina nanospheres TEMPLATE lauric acid
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Study of Carbon Nanotube Supported Co-Mo Selective Hydrodesulphurization Catalysts for Fluid Catalytic Cracking Gasoline
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作者 Wenkui Yin Mei Li +2 位作者 Hongyan Shang chenguang liu Fei Wei 《Journal of Natural Gas Chemistry》 EI CAS CSCD 2005年第3期163-167,共5页
In this paper, carbon nanotube supported Co-Mo catalysts for selective hydrodesulphurization (HDS) of fluid catalytic cracking (FCC) gasoline were studied, using di-isobutylene, cyclohexene, 1-octene and thiophene... In this paper, carbon nanotube supported Co-Mo catalysts for selective hydrodesulphurization (HDS) of fluid catalytic cracking (FCC) gasoline were studied, using di-isobutylene, cyclohexene, 1-octene and thiophene as model compounds to simulate FCC gasoline. The results show that the Co-Mo/CNT has very high HDS activity and HDS/hydrogenation selectivity comparing with the Co-Mo/γ-Al2O3 and Co-Mo/AC catalyst systems. The saturation ratio of cyclohexene was lower than 50%, and the saturation ratio of 1,3-di-isobutylene lower than 60% for the Co-Mo/CNT catalysts. Co/Mo atomic ratio was found to be one of the most important key factors in influencing the hydrogenation selectivity and HDS activity, and the most suitable Co/Mo atomic ratio was 0.4. Co/CNT and Mo/CNT mono-metallic catalysts showed lower HDS activity and selectivity than the Co-Mo/CNT bi-metallic catalysts. 展开更多
关键词 XRD HYDRODESULPHURIZATION carbon nanotube cobalt MOLYBDENUM SELECTIVITY fluid catalytic cracking GASOLINE
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Construction of N-doped carbon frames anchored with Co single atoms and Co nanoparticles as robust electrocatalyst for hydrogen evolution in the entire pH range
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作者 Minmin Wang Min Li +14 位作者 Yilin Zhao Naiyou Shi Hui Zhang Yuxue Zhao Yaru Zhang Haoran Zhang Wenhong Wang Kaian Sun Yuan Pan Shoujie liu Houyu Zhu Wenyue Guo Yanpeng Li Yunqi liu chenguang liu 《Journal of Energy Chemistry》 SCIE EI CAS CSCD 2022年第4期147-156,共10页
The development of low-cost, efficient, and high atomic economy electrocatalysts for hydrogen evolution reaction(HER) in the entire p H range for sustainable hydrogen production is of great importance but still challe... The development of low-cost, efficient, and high atomic economy electrocatalysts for hydrogen evolution reaction(HER) in the entire p H range for sustainable hydrogen production is of great importance but still challenging. Herein, we synthesize a highly dispersed N-doped carbon frames(NCFs) anchored with Co single atoms(SAs) and Co nanoparticles(NPs) catalyst by a doping-adsorption-pyrolysis strategy for electrocatalytic hydrogen evolution. The Co SAs-Co NPs/NCFs catalyst exhibits an excellent HER activity with small overpotential, low Tafel slope, high turnover frequency as well as remarkable stability. It also exhibits a superior HER performance in the entire p H range. Combining with experimental and theoretical calculation, we find that Co SAs with Co-N_(3) coordination structure and Co NPs have a strong interaction for promoting synergistic HER electrocatalytic process. The H_(2)O molecule is easily activated and dissociated on Co NPs, while the generated H^(*) is easily adsorbed on Co SAs for HER, which makes the Co SAs-Co NPs/NCFs catalyst exhibit more suitable H adsorption strength and more conducive to the activation and dissociation of H_(2)O molecules. This work not only proposes a novel idea for constructing coupling catalyst with atomic-level precision, but also provides strong reference for the development of high-efficiency HER electrocatalysts for practical application. 展开更多
关键词 Single-atom catalyst Doping-adsorption-pyrolysis strategy Structure regulation Synergistic electrocatalysis EXAFS
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Detailed seafloor geomorphology of the western region of the North Yellow Sea,China:The result of Holocene erosional and depositional processes sculpting the offshore continental shelf
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作者 Xiaoyu liu Yilan Chen +3 位作者 chenguang liu Qiuhua Tang Yanhong Wang Shan Gao 《Acta Oceanologica Sinica》 SCIE CAS CSCD 2022年第12期38-47,共10页
High-resolution multi-beam/single-beam bathymetric data and seismic profiling data from the latest surveys are used to map and interpret the detailed seafloor geomorphology of the western region of the North Yellow Se... High-resolution multi-beam/single-beam bathymetric data and seismic profiling data from the latest surveys are used to map and interpret the detailed seafloor geomorphology of the western region of the North Yellow Sea(NYS),China.The mapping area covers 156410 km^(2),and incorporates a flat shelf plain,subaqueous accumulation shoals,tidal scouring troughs,and tidal sand ridge groups.Offshore areas with water depths less than 50 m in the western region of the NYS are mainly covered by thick,loose sediments,forming wide spread accumulation geomorphological features;these include the Liaodong Peninsula subaqueous accumulation system containing shoals and rugged scouring troughs,and the large mud wedge of the Shandong Peninsula.In the central part of the NYS,there is a relatively flat residual shelf plain with coarser sediment deposits.This flat shelf plain has a water depth larger than 50 m and a thin layer of sediment,on which there is a large pockmark field caused by seafloor seepage.These geomorphological structures indicate that modern sedimentary processes are the main driving force controlling the sculpture of the current seafloor surface landform.Extensive strong tidal current systems and abundant sediment sources provide the critical external forces and essential conditions for the formation of seafloor geomorphology.The tectonic basement controls the macroscopic morphological shape of the NYS,but is reflected very little in the seafloor geomorphic elements.Our results provide a detailed seafloor geomorphological map of the western region of the NYS,an area that has not previously mapped and also provide a scientific framework for further research into offshore seafloor geomorphology,shelf sedimentary processes,and submarine engineering construction in this region. 展开更多
关键词 seafloor geomorphology North Yellow Sea geomorphic map mud wedge accumulative shoal
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Preparation and properties of magnetic alumina microspheres with a γ-Fe_2O_3/SiO_2 core and Al_2O_3 shell
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作者 Qingtao Fu Tingting He +2 位作者 Lianqing Yu Yongming Chai chenguang liu 《Journal of Natural Gas Chemistry》 EI CAS CSCD 2011年第1期72-76,共5页
Magnetic alumina composite microspheres with γ-Fe 2 O 3 core/Al 2 O 3 shell structure were prepared by the oil column method. A dense silica layer was deposited on the surface of γ-Fe 2 O 3 particles (denoted as γ... Magnetic alumina composite microspheres with γ-Fe 2 O 3 core/Al 2 O 3 shell structure were prepared by the oil column method. A dense silica layer was deposited on the surface of γ-Fe 2 O 3 particles (denoted as γ-Fe 2 O 3 /SiO 2 ) with a desired thickness to protect the iron oxide core against acidic or high temperature conditions. γ-Fe 2 O 3 /SiO 2 /Al 2 O 3 particles with about 85 wt% Al 2 O 3 were obtained and showed to be suitable for practical applications as a magnetic catalyst or catalyst support due to their magnetic properties and pore structure. The products were characterized with scanning electron microscope (SEM) and transmission electron microscope (TEM), nitrogen adsorption-desorption, and vibrating sample magnetometer (VSM). The specific surface area and pore volume of the γ-Fe 2 O 3 /SiO 2 /Al 2 O 3 composite microspheres calcined at 500 ? C were 200 m 2 /g and 0.77 cm 3 /g, respectively. 展开更多
关键词 γ-Fe 2 O 3 microsphere alumina CORE-SHELL sol-gel method
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Iron adsorption engineering facilitated by Cu doping on cobalt hydroxide host with enhanced oxygen evolution reaction
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作者 Xinyu Zhang Yiwen Dong +6 位作者 Huiying Wang Ziyi Zhao Wenchun Jiang Bin Dong Han Hu chenguang liu Yongming Chai 《Nano Research》 SCIE EI CSCD 2023年第2期2111-2118,共8页
Iron plays a crucial role in improving the oxygen evolution reaction(OER)activity of hydroxide materials.Increasing the number of iron active sites at the solid–liquid interface is beneficial to enhancing the OER per... Iron plays a crucial role in improving the oxygen evolution reaction(OER)activity of hydroxide materials.Increasing the number of iron active sites at the solid–liquid interface is beneficial to enhancing the OER performance of catalysts but still challenging.Here,by systematic exploring the activity trends of M(OH)_(x)and Cu-M(OH)_(x)(M=Mn,Cu,Ni,Fe,and Co),we discover that the Cu doping can promote the deposition of Fe active sites on metal hydroxide and Cu-Co(OH)2 shows the most favorable iron adsorption capacity.When loaded on a conductive substrate(cobalt foam(CF),the M-Cu-Co(OH)2/CF(Co(OH)_(2))prepared by molten salt method)exhibits an attractive low overpotential of 337 mV at 1,000 mA·cm^(−2).Using in anion exchange membrane(AEM)water electrolyzer,the single cell with M-Cu-Co(OH)_(2)/CF as anode catalyst performs a stable cell voltage of 2.02 V to reach 1,000 mA·cm^(−2)over 24 h,indicating a great application potential for actual electrolytic water.Therefore,the promoted adsorption of copper on iron provides a new perspective for further enhancing the OER activity of other metal hydroxides. 展开更多
关键词 copper doping promoted Fe adsorption industrial-level current density anion exchange membrane water electrolyzer oxygen evolution reaction
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Effects of sediment characteristics on the sediment transport capacity of overland flow
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作者 chenguang liu Suhua Fu +2 位作者 Zhanbin Li Zeyu Zhang Jianhui Zeng 《International Soil and Water Conservation Research》 SCIE CSCD 2023年第1期75-85,共11页
The transport of sediments is a crucial part of soil erosion.Accurately calculating the sediment transport capacity is key to the construction of soil erosion process models.Research on Tc has focused mainly on the dy... The transport of sediments is a crucial part of soil erosion.Accurately calculating the sediment transport capacity is key to the construction of soil erosion process models.Research on Tc has focused mainly on the dynamics of a single particle of sediment and hydraulic variables.There have been few studies of the impact of soil aggregates on the Tc.To clarify how sediment characteristics,including those for single particles and aggregates,affect the Tc of overland flow with no raindrop import,flume experiments were implemented at slope gradients varying from 5.24%to 26.80%and flow discharges ranging from 0.68 to 5.41×10^(-3)m^(2)s^(-1).The experimental materials were five typical soils in China.The results indicated that the correlation between the measured Tc and sediment mechanical composition indexes of the five soils was indistinctive in this study.The sediment settling velocity with aggregates has a significant corre-lation with the measured Tc.New equations,including for the sediment settling velocity with aggregatesωud75,were established to calculate the Tc.The empirical equation that includedωud75,slope gradient and unit discharge performed greatly in predicting Tc(R^(2)=0.93,NSE=0.90).ωud75 can effectively improve the calculation accuracy of Tc.The new equation including flow and sediment properties obtained through dimensional analysis performed well in predicting Tc(R^(2)=0.99,NSE=0.91),and the calculation accuracy was better than that of the empirical model derived in this study.These findings indicate that the sediment settling velocity is an important variable in the equation for predicting sediment transport capacity of overland flow. 展开更多
关键词 Sediment transport capacity Soil mechanical composition Soil aggregates Sediment settling velocity Dimensional analysis
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Engineering Komagataella phaffii to biosynthesize cordycepin from methanol which drives global metabolic alterations at the transcription level
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作者 Huiping Tan Liang Wang +6 位作者 Huiguo Wang Yanghao Cheng Xiang Li Huihui Wan chenguang liu Tian liu Qian Li 《Synthetic and Systems Biotechnology》 SCIE CSCD 2023年第2期242-252,共11页
Cordycepin has the potential to be an alternative to the disputed herbicide glyphosate.However,current laborious and time-consuming production strategies at low yields based on Cordyceps militaris lead to extremely hi... Cordycepin has the potential to be an alternative to the disputed herbicide glyphosate.However,current laborious and time-consuming production strategies at low yields based on Cordyceps militaris lead to extremely high cost and restrict its application in the field of agriculture.In this study,Komagataella phaffii(syn.Pichia pastoris)was engineered to biosynthesize cordycepin from methanol,which could be converted from CO_(2).Combined with fermentation optimization,cordycepin content in broth reached as high as 2.68±0.04 g/L within 168 h,around 15.95 mg/(L⋅h)in productivity.Additionally,a deaminated product of cordycepin was identified at neutral or weakly alkaline starting pH during fermentation.Transcriptome analysis found the yeast producing cordycepin was experiencing severe inhibition in methanol assimilation and peroxisome biogenesis,responsible for delayed growth and decreased carbon flux to pentose phosphate pathway(PPP)which led to lack of precursor supply.Amino acid interconversion and disruption in RNA metabolism were also due to accumu-lation of cordycepin.The study provided a unique platform for the manufacture of cordycepin based on the emerging non-conventional yeast and gave practical strategies for further optimization of the microbial cell factory. 展开更多
关键词 CORDYCEPIN Komagataella phaffii Fermentation optimization TRANSCRIPTOME
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铜掺杂生物活性玻璃的生物医学应用 被引量:1
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作者 韩雅卉 刘晨光 +1 位作者 王士斌 陈爱政 《科学通报》 EI CAS CSCD 北大核心 2020年第36期4262-4271,共10页
生物活性玻璃作为一种既能与骨组织键合又能与软组织连接的活性材料,可通过降解过程实现对活性离子的控制释放,在临床生物医学方面得到长足发展.本文综述了近年来合成的铜掺杂生物活性玻璃的基本特征,并对相关生物医学应用研究进展进行... 生物活性玻璃作为一种既能与骨组织键合又能与软组织连接的活性材料,可通过降解过程实现对活性离子的控制释放,在临床生物医学方面得到长足发展.本文综述了近年来合成的铜掺杂生物活性玻璃的基本特征,并对相关生物医学应用研究进展进行介绍,对研究中存在的问题和面临的挑战进行深入剖析.其中,基本特征内容包括结构及分类,具体细分为45S5型、1393型、70S型和1393 B3型等;生物医学应用进展内容涵盖抗菌、抗癌、骨/软骨修复再生及血管生成. 展开更多
关键词 铜掺杂生物活性玻璃 抗菌 癌症治疗 成骨 成血管
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Passive-source ocean bottom seismograph(OBS) array experiment in South China Sea and data quality analyses 被引量:11
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作者 chenguang liu Qingfeng Hua +7 位作者 Yanliang Pei Ting Yang Shaohong Xia Mei Xue Ba Manh Le Da Huo Fang liu Haibo Huang 《Chinese Science Bulletin》 SCIE EI CAS 2014年第33期4524-4535,共12页
Long-term passive source ocean bottom seismograph(OBS) observatory is challenging due to various technical difficulties. In order to gain experience in this field, and to reveal the lithospheric structure beneath the ... Long-term passive source ocean bottom seismograph(OBS) observatory is challenging due to various technical difficulties. In order to gain experience in this field, and to reveal the lithospheric structure beneath the extinct ridge in the central South China Sea(SCS), we carried out a passive source OBS array experiment, which includes 18 OBSs, in the deep portion of SCS. Here we present the instrumentation, the OBS deployment and recovery of this experiment, and more importantly, the data quality evaluated by a number of approaches. Through processing and inspecting waveforms from global, regional and local earthquakes, we find that most of recovered OBSs have good data quality with discernible main phases. The ambient noise analyses of OBS recordings show that their noise is higher than the global average, and the horizontal component is noisier than the vertical, indicating current impacts on horizontal components are more severe. In the period range of 5–10 s, there is a noise notch for the SCS OBSs, and noise levels of horizontal components are comparable to the vertical. This feature, which is not seen at OBS stations in open ocean, suggests the distant sources for double frequency microseism in this marginal sea are not significant. In addition, we successfully determined the orientations for 7 OBSs by investigating their Rayleigh wave polarizations; and we demonstrated the dispersion feature of Rayleigh waves through the frequency-time analysis. Finally, we summarized lessons learned from this experiment regarding the passive source OBS investigations in SCS. 展开更多
关键词 海底地震仪 中国南海 OBS 被动源 实验 质量分析 阵列 水平分量
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