Sulfide solid electrolytes(e.g.,lithium thiophosphates)have the highest room-temperature ionic conductivity(-10^(-2) S cm^(-1))among solid Li-ion conductors so far,and thus have attracted ever-increasing attention for...Sulfide solid electrolytes(e.g.,lithium thiophosphates)have the highest room-temperature ionic conductivity(-10^(-2) S cm^(-1))among solid Li-ion conductors so far,and thus have attracted ever-increasing attention for high energy-density and safety all-solid-state batteries(ASSBs).However,interfacial issues between sulfide electrolytes and electrodes have been the main challenges for their applications in ASSBs.The interfacial instabilities would occur due to side reactions of sulfides with electrodes,poor solid-solid contact,and lithium dendrites during charge/discharge cycling.In this review,we analyze the interfacial issues in ASSBs based on sulfide electrolytes,and in particular,discuss strategies for solving these interfacial issues and stabilize the electrode-electrolyte interfaces.Moreover,a perspective of the interfacial engineering for sulfide-based ASSBs is provided.展开更多
Bulk-type all-solid-state batteries(ASSBs)using sulfide solid electrolyte are considered as a promising alternative to commercial lithium-ion batteries owing to their high energy density and safety.However,cell energy...Bulk-type all-solid-state batteries(ASSBs)using sulfide solid electrolyte are considered as a promising alternative to commercial lithium-ion batteries owing to their high energy density and safety.However,cell energy density is often comparatively low due to use of a thick solid electrolyte separator and a lithium alloy as anode.For achieving high-performance ASSBs,creating a thin free-standing electrolyte with high-conductivity and good cycling stability against lithium anode is essential.In this work,we present Li_(6)PS_(5)Cl/poly(vinylidene difluoride)(LPSCl/PVDF)composite electrolytes prepared by a slurry method.The influence of the PVDF content on the microstructure,morphology,ionic conductivity and activation energy of the LPSCl/PVDF electrolytes is systematically investigated.Free-standing LPSCl/PVDF membranes with a thickness of 100-120 mm and a high ionic conductivity of about 1·10^(-3) S cm^(-1) at 25℃ are obtained.After adding PVDF to the LPSCl electrolyte,the cycling stability of the LPSCl electrolyte against lithium metal improves significantly.Therefore,LPSCl/PVDF composite electrolytes are promising candidates to be used in ASSBs.展开更多
Magnetoelectric(ME)composites have recently attracted an ever-increasing interest and provoked a great number of research activities,driven by the potential applications in novel multifunctional devices,such as sensor...Magnetoelectric(ME)composites have recently attracted an ever-increasing interest and provoked a great number of research activities,driven by the potential applications in novel multifunctional devices,such as sensors and transducers[1].Direct ME effect,which describe the appearance of an electric polarization P upon applying a magnetic field H,is usually evaluated by the展开更多
基金supported by the Basic Science Center Program of NSFC under Grant No.51788104,NSFC projects under Grant Nos.51532002.F.H.R.acknowledges the support from the BMBF for the project FLiPS(03XP0261).S.W.acknowledges the financial support by the China Scholarship Council.
文摘Sulfide solid electrolytes(e.g.,lithium thiophosphates)have the highest room-temperature ionic conductivity(-10^(-2) S cm^(-1))among solid Li-ion conductors so far,and thus have attracted ever-increasing attention for high energy-density and safety all-solid-state batteries(ASSBs).However,interfacial issues between sulfide electrolytes and electrodes have been the main challenges for their applications in ASSBs.The interfacial instabilities would occur due to side reactions of sulfides with electrodes,poor solid-solid contact,and lithium dendrites during charge/discharge cycling.In this review,we analyze the interfacial issues in ASSBs based on sulfide electrolytes,and in particular,discuss strategies for solving these interfacial issues and stabilize the electrode-electrolyte interfaces.Moreover,a perspective of the interfacial engineering for sulfide-based ASSBs is provided.
基金supported by the Basic Science Center Program of NSFC under Grant No.51788104NSFC projects under Grant Nos.51532002,51572141,and 51625202financial support within the project 03XP0177A funded by BMBF with the cluster of competence FESTBATT.
文摘Bulk-type all-solid-state batteries(ASSBs)using sulfide solid electrolyte are considered as a promising alternative to commercial lithium-ion batteries owing to their high energy density and safety.However,cell energy density is often comparatively low due to use of a thick solid electrolyte separator and a lithium alloy as anode.For achieving high-performance ASSBs,creating a thin free-standing electrolyte with high-conductivity and good cycling stability against lithium anode is essential.In this work,we present Li_(6)PS_(5)Cl/poly(vinylidene difluoride)(LPSCl/PVDF)composite electrolytes prepared by a slurry method.The influence of the PVDF content on the microstructure,morphology,ionic conductivity and activation energy of the LPSCl/PVDF electrolytes is systematically investigated.Free-standing LPSCl/PVDF membranes with a thickness of 100-120 mm and a high ionic conductivity of about 1·10^(-3) S cm^(-1) at 25℃ are obtained.After adding PVDF to the LPSCl electrolyte,the cycling stability of the LPSCl electrolyte against lithium metal improves significantly.Therefore,LPSCl/PVDF composite electrolytes are promising candidates to be used in ASSBs.
基金supported by the National Natural Science Foundation of China (51402164)
文摘Magnetoelectric(ME)composites have recently attracted an ever-increasing interest and provoked a great number of research activities,driven by the potential applications in novel multifunctional devices,such as sensors and transducers[1].Direct ME effect,which describe the appearance of an electric polarization P upon applying a magnetic field H,is usually evaluated by the
