Despite the rapid advances of red and green perovskite light-emitting diodes(Pe LEDs),achieving high brightness with high external quantum efficiency(EQE)remains a challenge for the pure-blue Pe LEDs,which greatly hin...Despite the rapid advances of red and green perovskite light-emitting diodes(Pe LEDs),achieving high brightness with high external quantum efficiency(EQE)remains a challenge for the pure-blue Pe LEDs,which greatly hinders their practical applications,such as white-light illumination and in optical communication as a high-speed and low-loss light source.Herein,we report a high-performance pure-blue Pe LED based on mixed-halide quasi-2D perovskites incorporated with a zwitterionic molecule of 3-(benzyldimethylammonio)propanesulfonate(3-BAS).Experimental and density functional theory analysis reveals that 3-BAS can simultaneously eliminate non-radiative recombination loss,suppress halide migration,and regulate phase distribution for smoothing energy transfer in the mixed-halide quasi-2D perovskites,leading to the final perovskites with high photoluminescence quantum yield and robust spectrum stability.Thus,the highperformance pure-blue Pe LED with a recorded brightness with 1806 cd m-2and a relative higher EQE of 9.25%is achieved,which is successfully demonstrated in a visible light communication system for voice signal transmission.We pave the way for achieving highly efficient pure-blue Pe LEDs with great application potential in future optical communication networks.展开更多
基金the support of the National Natural Science Foundation of China(NSFC)(61774077,12304473,62175094)the Key Projects of Joint Fund of Basic and Applied Basic Research Fund of Guangdong Province(2019B1515120073,2019B090921002)+3 种基金the Guangdong Science and Technology Research Foundation(2020A1414010036)the High-End Foreign Experts Project(G20200019046)the Young Talent Support Project of Henan Province(2024HYTP001)the Opening Project of Key Laboratory of Optoelectronic Chemical Materials and Devices,Ministry of Education,Jianghan University(JDGD-202302)
文摘Despite the rapid advances of red and green perovskite light-emitting diodes(Pe LEDs),achieving high brightness with high external quantum efficiency(EQE)remains a challenge for the pure-blue Pe LEDs,which greatly hinders their practical applications,such as white-light illumination and in optical communication as a high-speed and low-loss light source.Herein,we report a high-performance pure-blue Pe LED based on mixed-halide quasi-2D perovskites incorporated with a zwitterionic molecule of 3-(benzyldimethylammonio)propanesulfonate(3-BAS).Experimental and density functional theory analysis reveals that 3-BAS can simultaneously eliminate non-radiative recombination loss,suppress halide migration,and regulate phase distribution for smoothing energy transfer in the mixed-halide quasi-2D perovskites,leading to the final perovskites with high photoluminescence quantum yield and robust spectrum stability.Thus,the highperformance pure-blue Pe LED with a recorded brightness with 1806 cd m-2and a relative higher EQE of 9.25%is achieved,which is successfully demonstrated in a visible light communication system for voice signal transmission.We pave the way for achieving highly efficient pure-blue Pe LEDs with great application potential in future optical communication networks.
