We deal with a consensus control problem for a group of third order agents which are networked by digraphs.Assuming that the control input of each agent is constructed based on weighted difference between its states a...We deal with a consensus control problem for a group of third order agents which are networked by digraphs.Assuming that the control input of each agent is constructed based on weighted difference between its states and those of its neighbor agents, we aim to propose an algorithm on computing the weighting coefficients in the control input. The problem is reduced to designing Hurwitz polynomials with real or complex coefficients. We show that by using Hurwitz polynomials with complex coefficients, a necessary and sufficient condition can be obtained for designing the consensus algorithm. Since the condition is both necessary and sufficient, we provide a kind of parametrization for all the weighting coefficients achieving consensus. Moreover, the condition is a natural extension to second order consensus, and is reasonable and practical due to its comparatively decreased computation burden. The result is also extended to the case where communication delay exists in the control input.展开更多
A convenient and practical synthetic route for 2,4-dibromo-5-fluorobenzoic acid is described. Two intermediates, 2,4-dibromo-5-fluorobenzonitrile and 2,4-dibromo-5-fluorobenzamide, have not been reported before. This ...A convenient and practical synthetic route for 2,4-dibromo-5-fluorobenzoic acid is described. Two intermediates, 2,4-dibromo-5-fluorobenzonitrile and 2,4-dibromo-5-fluorobenzamide, have not been reported before. This route can be easily industrialized.展开更多
As the cleanest energy source,hydrogen energy is regarded as the most promising fuel.Water electrolysis,as the primary means of hydrogen production,has constantly been the focus of attention in the energy conversion f...As the cleanest energy source,hydrogen energy is regarded as the most promising fuel.Water electrolysis,as the primary means of hydrogen production,has constantly been the focus of attention in the energy conversion field.Developing eco-friendly,cheap,safe and efficient catalysts for electrochemical water splitting(EWS)is the key challenge.Herein,the intermetallic silicide alloy is first synthesized via a facile magnesiothermic reduction and employed as bifunctional electrocatalysts for EWS.Ferric-nickel silicide(denoted as FeNiSi)alloy is designed and shows a good electrocatalytic performance for EWS.The lattice distortions of FeNiSi enhance the electrocatalytic activity.Besides,the porous structure affords more active sites and improves the reaction kinetics.As a consequence,FeNiSi delivers an excellent performance with overpotential of 308 mV for oxygen evolution reaction(OER)and 386 mV for hydrogen evolution reaction(HER)at 10 mA·cm−2 in 1 M KOH.The stability structure of intermetallic silicide achieves an outstanding durability with an unchanged potential of 1.66 V for overall water splitting at 10 mA·cm−2 for 15 h.This work not only provides a facile method for the synthesis of intermetallic silicide with considerable porous structures,but also develops the potential of intermetallic silicide alloy as bifunctional electrocatalysts for EWS,which opens up a new avenue for the design and application of intermetallic silicide alloy.展开更多
The consensus protocol of cyber-physical power systems is proposed based on fractional-order multi-agent systems with communication constraints.It aims to enable each generator to reach a time-varying common rotor ang...The consensus protocol of cyber-physical power systems is proposed based on fractional-order multi-agent systems with communication constraints.It aims to enable each generator to reach a time-varying common rotor angle and rotor speed.Communication constraints including event-triggered sampling and partial information transmission are considered to render the consensus protocol more realistic.The Zeno behavior is excluded during the system sampling process.A sufficient condition is derived to solve the consensus problem.The effectiveness of the proposed consensus protocol is demonstrated by a numerical example.展开更多
Adsorbents are widely employed in both fundamental and applied research areas such as separation technology, biotechnology, and environmental science. Selectivity and reusability are two most important requirements fo...Adsorbents are widely employed in both fundamental and applied research areas such as separation technology, biotechnology, and environmental science. Selectivity and reusability are two most important requirements for adsorbents. Aptamers exhibit perfect selectivity and easy regeneration, which make them uniquely effective adsorption materials. Herein, we have rationally designed novel aptamer-based adsorbents and investigated their performance in extraction/ separation of targets from an aqueous solution. These adsorbents can selectively extract targets from complicated sample matrices containing background compounds. Moreover, they can also be easily recycled without a significant loss of adsorption capacity. Notably, the adsorbents did not affect the activity of isolated biological samples, revealing their potential for the purification/separation of biomolecules. Composite adsorbents were constructed using aptamer-based adsorbents and a porous polymer, displaying highly efficient target separation from aqueous solution. Finally, separation columns were constructed, and targets in the aqueous solution were efficiently separated by these columns. The aptamerbased adsorbents described here exhibit great promise for potential applications in separation technology, biotechnology, and environment-related areas.展开更多
Minqing Xiao received the Ph.D.degree from Chongqing University,Chongqing,China,in 2008.He is currently a Professor with the College of Mathematics and Informatics,Fujian Normal University,Fuzhou,China.His current res...Minqing Xiao received the Ph.D.degree from Chongqing University,Chongqing,China,in 2008.He is currently a Professor with the College of Mathematics and Informatics,Fujian Normal University,Fuzhou,China.His current research interests include robust control/filter theory,delta operator systems,networked control systems,and switched systems;Guisheng Zhai received his B.S.degree from Fudan University,China,in 1988,and he received his M.E.and Ph.D.degrees,both in system science,from Kobe University,Japan,in 1993 and 1996,respectively.After two years of industrial experience,Dr.Zhai moved to Wakayama University,Japan,in 1998,and then to Osaka Prefecture University,Japan,in 2004.He held visiting professor positions at University of Notre Dame from August 2001 to July 2002,and at Purdue University from March 2016 through February 2017.In April 2010,he joined the faculty board of Shibaura Institute of Technology,Japan,where he currently is a full Professor of Mathematical Sciences.His research interests include large scale and decentralised control systems,robust control,switched systems and switching control,networked control and multi-agent systems,neural networks and signal processing,etc.Dr.Zhai is on the editorial board of several academic journals including IET Control Theory&Applications,International Journal of Applied Mathematics and Computer Science,Journal of Control and Decision,and Frontiers of Mechanical Engineering.He is a Senior Member of IEEE,a member of ISCIE,SICE,JSST and JSME.展开更多
This study is concerned with probabilistic Boolean control networks(PBCNs)with state feedback control.A novel definition of bisimilar PBCNs is proposed to lower computational complexity.To understand more on bisimulat...This study is concerned with probabilistic Boolean control networks(PBCNs)with state feedback control.A novel definition of bisimilar PBCNs is proposed to lower computational complexity.To understand more on bisimulation relations between PBCNs,we resort to a powerful matrix manipulation called semi-tensor product(STP).Because stabilization of networks is of critical importance,the propagation of stabilization with probability one between bisimilar PBCNs is then considered and proved to be attainable.Additionally,the transient periods(the maximum number of steps to implement stabilization)of two PBCNs are certified to be identical if these two networks are paired with a bisimulation relation.The results are then extended to the probabilistic Boolean networks.展开更多
Low-cost,high safety and environment-friendly aqueous energy storage systems(ESSs)are huge potential for grid-level energy storage,but the(de)intercalation of metal ions in the electrode materials(e.g.vanadium oxides)...Low-cost,high safety and environment-friendly aqueous energy storage systems(ESSs)are huge potential for grid-level energy storage,but the(de)intercalation of metal ions in the electrode materials(e.g.vanadium oxides)to obtain superior long-term cycling stability is a significant challenge.Herein,we demonstrate that polyvinyl alcohol(PVA)-assisted hydrated vanadium pentoxide/reduced graphene oxide(V_(2)O_(5)·n H_(2)O/r GO/PVA,denoted as the VGP)films enable long cycle stability and high capacity for the Li^(+)and Zn^(2+)storages in both the VGP//Li Cl(aq)//VGP and the VGP//Zn SO4(aq)//Zn cells.The binderfree VGP films are synthesized by a one-step hydrothermal method combination with the filtration.The extensive hydrogen bonds are formed among PVA,GO and H_(2)O,and they act as structural pillars and connect the adjacent layers as glue,which contributes to the ultrahigh specific capacitance and ultralong cyclic performance of Li^(+)and Zn^(2+)storage properties.As for Li^(+)storage,the binder-free VGP4 film(4mg PVA)electrode achieves the highest specific capacitance up to 1381 F g^(-1)at 1.0 A g^(-1)in the three-electrode system and 962 F g^(-1)at 1.0 A g^(-1)in the symmetric two-electrode system.It also behaves the outstanding cyclic performance with the capacitance retention of 96.5%after 15000 cycles in the three-electrode system and 99.7%after 25000 cycles in the symmetric two-electrode system.As for Zn^(2+)storage,the binder-free VGP4 film electrode exhibits the high specific capacity of 184 m A h g^(-1)at 0.5A g^(-1)in the VGP4//Zn SO4(aq)//Zn cell and the superb cycle performance of 98.5%after 25000 cycles.This work not only provides a new strategy for the construction of vanadium oxides composites and demonstrates the potential application of PVA-assisted binder-free film with excellent electrochemical properties,but also extends to construct other potential electrode materials for metal ion storage cells.展开更多
基金supported by Japan Ministry of Education,Sciences and Culture(C21560471)the National Natural Science Foundation of China(61603268)+1 种基金the Research Project Supported by Shanxi Scholarship Council of China(2015-044)the Fundamental Research Project of Shanxi Province(2015021085)
文摘We deal with a consensus control problem for a group of third order agents which are networked by digraphs.Assuming that the control input of each agent is constructed based on weighted difference between its states and those of its neighbor agents, we aim to propose an algorithm on computing the weighting coefficients in the control input. The problem is reduced to designing Hurwitz polynomials with real or complex coefficients. We show that by using Hurwitz polynomials with complex coefficients, a necessary and sufficient condition can be obtained for designing the consensus algorithm. Since the condition is both necessary and sufficient, we provide a kind of parametrization for all the weighting coefficients achieving consensus. Moreover, the condition is a natural extension to second order consensus, and is reasonable and practical due to its comparatively decreased computation burden. The result is also extended to the case where communication delay exists in the control input.
文摘A convenient and practical synthetic route for 2,4-dibromo-5-fluorobenzoic acid is described. Two intermediates, 2,4-dibromo-5-fluorobenzonitrile and 2,4-dibromo-5-fluorobenzamide, have not been reported before. This route can be easily industrialized.
基金the Natural Science Foundation of Liaoning Province(No.2023-MS-115)and Large Instrument and Equipment Open Foundation of Dalian University of Technology.
文摘As the cleanest energy source,hydrogen energy is regarded as the most promising fuel.Water electrolysis,as the primary means of hydrogen production,has constantly been the focus of attention in the energy conversion field.Developing eco-friendly,cheap,safe and efficient catalysts for electrochemical water splitting(EWS)is the key challenge.Herein,the intermetallic silicide alloy is first synthesized via a facile magnesiothermic reduction and employed as bifunctional electrocatalysts for EWS.Ferric-nickel silicide(denoted as FeNiSi)alloy is designed and shows a good electrocatalytic performance for EWS.The lattice distortions of FeNiSi enhance the electrocatalytic activity.Besides,the porous structure affords more active sites and improves the reaction kinetics.As a consequence,FeNiSi delivers an excellent performance with overpotential of 308 mV for oxygen evolution reaction(OER)and 386 mV for hydrogen evolution reaction(HER)at 10 mA·cm−2 in 1 M KOH.The stability structure of intermetallic silicide achieves an outstanding durability with an unchanged potential of 1.66 V for overall water splitting at 10 mA·cm−2 for 15 h.This work not only provides a facile method for the synthesis of intermetallic silicide with considerable porous structures,but also develops the potential of intermetallic silicide alloy as bifunctional electrocatalysts for EWS,which opens up a new avenue for the design and application of intermetallic silicide alloy.
基金jointly supported by the Research Project Supported by the Shanxi Scholarship Council of China(No.2015044)the Fundamental Research Project of Shanxi Province(No.2015021085)the National Science Foundation of China(No.61603268,No.61272530 and No.61573096).
文摘The consensus protocol of cyber-physical power systems is proposed based on fractional-order multi-agent systems with communication constraints.It aims to enable each generator to reach a time-varying common rotor angle and rotor speed.Communication constraints including event-triggered sampling and partial information transmission are considered to render the consensus protocol more realistic.The Zeno behavior is excluded during the system sampling process.A sufficient condition is derived to solve the consensus problem.The effectiveness of the proposed consensus protocol is demonstrated by a numerical example.
基金Acknowledgements This work was supported by the National Natural Science Foundation of China （Nos. 51272186 and 21422105）, ＂A Foundation for the Author of National Excellent Doctoral Dissertation of P. R. China＂ （No. 201220）, and Ten Thousand Talents Program for Young Talents. Q. Y. thanks for large-scale instrument and equipment sharing foundation of Wuhan University.
文摘Adsorbents are widely employed in both fundamental and applied research areas such as separation technology, biotechnology, and environmental science. Selectivity and reusability are two most important requirements for adsorbents. Aptamers exhibit perfect selectivity and easy regeneration, which make them uniquely effective adsorption materials. Herein, we have rationally designed novel aptamer-based adsorbents and investigated their performance in extraction/ separation of targets from an aqueous solution. These adsorbents can selectively extract targets from complicated sample matrices containing background compounds. Moreover, they can also be easily recycled without a significant loss of adsorption capacity. Notably, the adsorbents did not affect the activity of isolated biological samples, revealing their potential for the purification/separation of biomolecules. Composite adsorbents were constructed using aptamer-based adsorbents and a porous polymer, displaying highly efficient target separation from aqueous solution. Finally, separation columns were constructed, and targets in the aqueous solution were efficiently separated by these columns. The aptamerbased adsorbents described here exhibit great promise for potential applications in separation technology, biotechnology, and environment-related areas.
基金Project supported by the Natural Science Foundation of Zhejiang Province, China （No. LZ12F02004）, the Program of Xinmiao Talent of Zhejiang Province, China （No. ZX13005002064）, and the National Natural Science Foundation of China （No. 81471734）
基金This research has been supported in part by National Science Foundation of Fujian Province of China under Grant 2017J01567the Fundamental Research Funds for the Central Universities under grant no.JBK190502Japan Ministry of Education,Sciences and Culture under Grants-in-Aid for Scientific Research(C)21560471.
文摘Minqing Xiao received the Ph.D.degree from Chongqing University,Chongqing,China,in 2008.He is currently a Professor with the College of Mathematics and Informatics,Fujian Normal University,Fuzhou,China.His current research interests include robust control/filter theory,delta operator systems,networked control systems,and switched systems;Guisheng Zhai received his B.S.degree from Fudan University,China,in 1988,and he received his M.E.and Ph.D.degrees,both in system science,from Kobe University,Japan,in 1993 and 1996,respectively.After two years of industrial experience,Dr.Zhai moved to Wakayama University,Japan,in 1998,and then to Osaka Prefecture University,Japan,in 2004.He held visiting professor positions at University of Notre Dame from August 2001 to July 2002,and at Purdue University from March 2016 through February 2017.In April 2010,he joined the faculty board of Shibaura Institute of Technology,Japan,where he currently is a full Professor of Mathematical Sciences.His research interests include large scale and decentralised control systems,robust control,switched systems and switching control,networked control and multi-agent systems,neural networks and signal processing,etc.Dr.Zhai is on the editorial board of several academic journals including IET Control Theory&Applications,International Journal of Applied Mathematics and Computer Science,Journal of Control and Decision,and Frontiers of Mechanical Engineering.He is a Senior Member of IEEE,a member of ISCIE,SICE,JSST and JSME.
基金Project supported by the National Natural Science Foundation of China(Nos.61603268 and 61773319)the Fundamental Research Funds for the Central Universities,China(No.JBK190502)。
文摘This study is concerned with probabilistic Boolean control networks(PBCNs)with state feedback control.A novel definition of bisimilar PBCNs is proposed to lower computational complexity.To understand more on bisimulation relations between PBCNs,we resort to a powerful matrix manipulation called semi-tensor product(STP).Because stabilization of networks is of critical importance,the propagation of stabilization with probability one between bisimilar PBCNs is then considered and proved to be attainable.Additionally,the transient periods(the maximum number of steps to implement stabilization)of two PBCNs are certified to be identical if these two networks are paired with a bisimulation relation.The results are then extended to the probabilistic Boolean networks.
基金partially supported by the National Natural Science Foundation of China(Nos.21771030 and 51572201)the Natural Science Foundation of Liaoning Province(No.2020-MS113)the Fundamental Research Funds for the Central Universities(No.DUT18RC(6)008)。
文摘Low-cost,high safety and environment-friendly aqueous energy storage systems(ESSs)are huge potential for grid-level energy storage,but the(de)intercalation of metal ions in the electrode materials(e.g.vanadium oxides)to obtain superior long-term cycling stability is a significant challenge.Herein,we demonstrate that polyvinyl alcohol(PVA)-assisted hydrated vanadium pentoxide/reduced graphene oxide(V_(2)O_(5)·n H_(2)O/r GO/PVA,denoted as the VGP)films enable long cycle stability and high capacity for the Li^(+)and Zn^(2+)storages in both the VGP//Li Cl(aq)//VGP and the VGP//Zn SO4(aq)//Zn cells.The binderfree VGP films are synthesized by a one-step hydrothermal method combination with the filtration.The extensive hydrogen bonds are formed among PVA,GO and H_(2)O,and they act as structural pillars and connect the adjacent layers as glue,which contributes to the ultrahigh specific capacitance and ultralong cyclic performance of Li^(+)and Zn^(2+)storage properties.As for Li^(+)storage,the binder-free VGP4 film(4mg PVA)electrode achieves the highest specific capacitance up to 1381 F g^(-1)at 1.0 A g^(-1)in the three-electrode system and 962 F g^(-1)at 1.0 A g^(-1)in the symmetric two-electrode system.It also behaves the outstanding cyclic performance with the capacitance retention of 96.5%after 15000 cycles in the three-electrode system and 99.7%after 25000 cycles in the symmetric two-electrode system.As for Zn^(2+)storage,the binder-free VGP4 film electrode exhibits the high specific capacity of 184 m A h g^(-1)at 0.5A g^(-1)in the VGP4//Zn SO4(aq)//Zn cell and the superb cycle performance of 98.5%after 25000 cycles.This work not only provides a new strategy for the construction of vanadium oxides composites and demonstrates the potential application of PVA-assisted binder-free film with excellent electrochemical properties,but also extends to construct other potential electrode materials for metal ion storage cells.
