Since the fouling-releasing ability of silicone elastomers increased as their modulus decreases, we designed and prepared composites with embedded tiny NaC1 crytals that were soluble after their immersion in water, re...Since the fouling-releasing ability of silicone elastomers increased as their modulus decreases, we designed and prepared composites with embedded tiny NaC1 crytals that were soluble after their immersion in water, resulting in water-filled porous elastomers. The scanning electron microscope images confirmed such a designed water-filling porous structure. The existence of many micro-drops of water in these specially designed elastomers decreased the shear storage modulus and increased the loss factors. The decrease of shear modulus plays a leading role here and is directly related to a lower critical peeling-off stress of a pseudo-barnacle on them. Therefore, such a novel preparation with cheap salts instead of an expensive silicone provides a better way to make fouling-release paints with a lower modulus, a lower critical peeling-off stress and a better fouling-release property without a significant decrease of the cross-linking density.展开更多
It had very long been a dream in polymer science to synthesize long multi-block polymer chains with an orderedchain sequence and controllable block lengths. Using ionic or living free radical polymerization or furnish...It had very long been a dream in polymer science to synthesize long multi-block polymer chains with an orderedchain sequence and controllable block lengths. Using ionic or living free radical polymerization or furnishing each end ofpolymer blocks with a reactive functional group, one can only prepare heteropolymer chains with few long blocks, such asdiblock and triblock copolymers. The most plausible result so far was a pentablock copolymer. Recently, using a combinationof polymer physics and synthetic chemistry, we have invented self-assembly assisted polycondensation (SAAP). Thiscommunication reports the results of using this novel. method to connect 10-100 triblock polymer chains together to formlong multi-block heteropolymer chains with an ordered sequence and controllable block lengths.展开更多
Electro-optic modulator is a key component for on-chip optical signal processing.An electro-optic phase modulator based on multilayer graphene embedded in silicon nitride waveguide is demonstrated to fulfill low-power...Electro-optic modulator is a key component for on-chip optical signal processing.An electro-optic phase modulator based on multilayer graphene embedded in silicon nitride waveguide is demonstrated to fulfill low-power operation.Finite element method is adopted to investigate the interaction enhancement between the graphene flake and the optical mode.The impact of multilayer graphene on the performance of phase modulator is studied comprehensively.Simulation results show that the modulation efficiency improves with the increment of graphene layer number,as well as the modulation length.The 3-dB bandwidth of around 48 GHz is independent of graphene layer number and length.Compared to modulator with two-or four-layer graphene,the six-layer graphene/silicon nitride waveguide modulator can realizeπphase shift at a low-power consumption of 14 fJ/bit when the modulation length is 240μm.展开更多
A waveguide coupled surface plasmon sensor for detection of liquid with high refractive index(RI)is designed based on polymer materials.The effects of variation of the thickness of the Au film,polymethyl methacrylate(...A waveguide coupled surface plasmon sensor for detection of liquid with high refractive index(RI)is designed based on polymer materials.The effects of variation of the thickness of the Au film,polymethyl methacrylate(PMMA)buffer,and waveguide layer on the sensing performance of the waveguide are comprehensively investigated by using the finite difference method.Numerical simulations show that a thinner gold film gives rise to a more sensitive structure,while the variation of the thickness of the PMMA buffer and waveguide layer has a little effect on the sensitivity.For liquid with high RI,the sensitivity of the sensor increases significantly.When RI of liquid to be measured increases from 1.45 to 1.52,the sensitivity is as high as 4518.14 nm/RIU,and a high figure of merit of 114.07 is obtained.The waveguide coupled surface plasmon RI sensor shows potential applications in the fields of environment,industry,and agriculture sensing with the merits of compact size,low cost,and high integration density.展开更多
A metal-clad planar polymer waveguide refractive index sensor based on epoxy(EPO)polymer materials by using light intensity interrogation at 850 nm is designed.The polymethyl methacrylate(PMMA)material is deployed as ...A metal-clad planar polymer waveguide refractive index sensor based on epoxy(EPO)polymer materials by using light intensity interrogation at 850 nm is designed.The polymethyl methacrylate(PMMA)material is deployed as the low refractive index(RI)buffer layer in order to better couple the optical guided mode and the surface plasmon polaritons(SPP)mode for working in water environment.The effects of the gold film thickness,PMMA buffer layer thickness,waveguide layer thickness,waveguide width,and gold length on the sensor sensing characteristics have been comprehensively studied.Simulation results demonstrate that the normalized transmission increases quasi-linearly with the increment of RI of the analyte from 1.33 to 1.46.The sensitivity is 491.5 dB/RIU,corresponding to a high RI resolution of 2.6×10^(9)RIU.The designed SPP-based optical waveguide sensor is low-cost,wide-range,and high-precision,and has a broad application prospect in biochemical sensing with merits of miniaturization,flexibility,and multiplexing.展开更多
Composite biomaterials made of biodegradable polylactic acid （PLA） and bioactive magnesium （Mg） salt are developed for orthopaedic implants or metal implant coatings. The releasing of Mg salt into the biological e...Composite biomaterials made of biodegradable polylactic acid （PLA） and bioactive magnesium （Mg） salt are developed for orthopaedic implants or metal implant coatings. The releasing of Mg salt into the biological environment benefits the bone growth, while with the releasing of Mg salt and degradation of PLA there forms a porous scaffold for tissue engineering. The size and morphology of the salt and voids are adjustable with such preparation conditions as salt content, pH of casting solution, and the solidification rate, so that we can control the salt releasing and degradation rate of PLA. Dielectric spectroscopy is used to investigate the dispersive structures of Mg salt and voids in the polymer matrix and to monitor the in situ releasing of Mg salts in the simulated body fluid （SBF）. The current study provides us with an orthopedic biomaterial with controllable multi-phase structures, and a tool to investigate the in vivo behaviors of biomaterials.展开更多
文摘Since the fouling-releasing ability of silicone elastomers increased as their modulus decreases, we designed and prepared composites with embedded tiny NaC1 crytals that were soluble after their immersion in water, resulting in water-filled porous elastomers. The scanning electron microscope images confirmed such a designed water-filling porous structure. The existence of many micro-drops of water in these specially designed elastomers decreased the shear storage modulus and increased the loss factors. The decrease of shear modulus plays a leading role here and is directly related to a lower critical peeling-off stress of a pseudo-barnacle on them. Therefore, such a novel preparation with cheap salts instead of an expensive silicone provides a better way to make fouling-release paints with a lower modulus, a lower critical peeling-off stress and a better fouling-release property without a significant decrease of the cross-linking density.
基金Financial support of the Research Grants Council of the Hong Kong Special Administration Region Earmarked Grant (CUHK4267/00P, CUHK 4209/99P, 2160122) and NNSFC 29974027 is gratefully acknowledged.
文摘It had very long been a dream in polymer science to synthesize long multi-block polymer chains with an orderedchain sequence and controllable block lengths. Using ionic or living free radical polymerization or furnishing each end ofpolymer blocks with a reactive functional group, one can only prepare heteropolymer chains with few long blocks, such asdiblock and triblock copolymers. The most plausible result so far was a pentablock copolymer. Recently, using a combinationof polymer physics and synthetic chemistry, we have invented self-assembly assisted polycondensation (SAAP). Thiscommunication reports the results of using this novel. method to connect 10-100 triblock polymer chains together to formlong multi-block heteropolymer chains with an ordered sequence and controllable block lengths.
基金the National Key Research and Development Program of China(Grant No.2019YFB2203001)the National Natural Science Foundation of China(Grant Nos.61675087,61875069,and 61605057)the Science and Technology Development Plan of Jilin Province,China(Grant No.JJKH20190118KJ).
文摘Electro-optic modulator is a key component for on-chip optical signal processing.An electro-optic phase modulator based on multilayer graphene embedded in silicon nitride waveguide is demonstrated to fulfill low-power operation.Finite element method is adopted to investigate the interaction enhancement between the graphene flake and the optical mode.The impact of multilayer graphene on the performance of phase modulator is studied comprehensively.Simulation results show that the modulation efficiency improves with the increment of graphene layer number,as well as the modulation length.The 3-dB bandwidth of around 48 GHz is independent of graphene layer number and length.Compared to modulator with two-or four-layer graphene,the six-layer graphene/silicon nitride waveguide modulator can realizeπphase shift at a low-power consumption of 14 fJ/bit when the modulation length is 240μm.
基金Development Program(Grant Nos.2018YFJH0702 and 2019JZZY020711)Qingdao Postdoctoral Applied Research Project(Grant No.6242007311086).
文摘A waveguide coupled surface plasmon sensor for detection of liquid with high refractive index(RI)is designed based on polymer materials.The effects of variation of the thickness of the Au film,polymethyl methacrylate(PMMA)buffer,and waveguide layer on the sensing performance of the waveguide are comprehensively investigated by using the finite difference method.Numerical simulations show that a thinner gold film gives rise to a more sensitive structure,while the variation of the thickness of the PMMA buffer and waveguide layer has a little effect on the sensitivity.For liquid with high RI,the sensitivity of the sensor increases significantly.When RI of liquid to be measured increases from 1.45 to 1.52,the sensitivity is as high as 4518.14 nm/RIU,and a high figure of merit of 114.07 is obtained.The waveguide coupled surface plasmon RI sensor shows potential applications in the fields of environment,industry,and agriculture sensing with the merits of compact size,low cost,and high integration density.
基金The authors gratefully acknowledge the financial support from the Shandong Provincial Key Research and Development Program(Grant Nos.2018YFJH0702 and 2019JZZY020711)Shandong Postdoctoral Innovation Project,and Qingdao Postdoctoral Applied Research Project.
文摘A metal-clad planar polymer waveguide refractive index sensor based on epoxy(EPO)polymer materials by using light intensity interrogation at 850 nm is designed.The polymethyl methacrylate(PMMA)material is deployed as the low refractive index(RI)buffer layer in order to better couple the optical guided mode and the surface plasmon polaritons(SPP)mode for working in water environment.The effects of the gold film thickness,PMMA buffer layer thickness,waveguide layer thickness,waveguide width,and gold length on the sensor sensing characteristics have been comprehensively studied.Simulation results demonstrate that the normalized transmission increases quasi-linearly with the increment of RI of the analyte from 1.33 to 1.46.The sensitivity is 491.5 dB/RIU,corresponding to a high RI resolution of 2.6×10^(9)RIU.The designed SPP-based optical waveguide sensor is low-cost,wide-range,and high-precision,and has a broad application prospect in biochemical sensing with merits of miniaturization,flexibility,and multiplexing.
基金financially supported by the National Natural Scientific Foundation of China(Nos.50773077,20934005 and 51273091)the Hong Kong Special Administration Region Earmarked Projects(CUHK4042/09P,2160396)
文摘Composite biomaterials made of biodegradable polylactic acid （PLA） and bioactive magnesium （Mg） salt are developed for orthopaedic implants or metal implant coatings. The releasing of Mg salt into the biological environment benefits the bone growth, while with the releasing of Mg salt and degradation of PLA there forms a porous scaffold for tissue engineering. The size and morphology of the salt and voids are adjustable with such preparation conditions as salt content, pH of casting solution, and the solidification rate, so that we can control the salt releasing and degradation rate of PLA. Dielectric spectroscopy is used to investigate the dispersive structures of Mg salt and voids in the polymer matrix and to monitor the in situ releasing of Mg salts in the simulated body fluid （SBF）. The current study provides us with an orthopedic biomaterial with controllable multi-phase structures, and a tool to investigate the in vivo behaviors of biomaterials.
