Zirconium doped mesoporous KIT-6 samples with different Si/Zr ratios were synthesized by the direct hydrothermal method.Various characterization techniques confirm that highly distributed ZrO_2 nanoparticles and multi...Zirconium doped mesoporous KIT-6 samples with different Si/Zr ratios were synthesized by the direct hydrothermal method.Various characterization techniques confirm that highly distributed ZrO_2 nanoparticles and multicoordinated Zr^(4+) species are incorporated in the mesoporous composites.One-pot synthesis of 5-hydroxymethylfurfura(HMF) from glucose was examined in the presence of Zr-KIT-6(20) the molar ratio of Si to Zr is 20 under aqueous system.The effects of temperature,reaction time,catalyst dosage and biphasic solvent system on the conversion of glucose and the HMF yield were investigated.It was found that the glucose conversion and the HMF yield have been improved from 54.8% to 79.0% and from 19.5% to 34.5% in the biphasic MIBK-water system,respectively.Both the acidity of Zr-KIT-6(20) and the biphasic MIBK-water system are responsible for the improved performance of glucose dehydration to HMF.展开更多
Hollow glass microspheres(HGMs)have great potential in building energy-saving and industrial insulation.Anatase TiO2-modified HGMs were prepared by a sol-gel method in acetic acid-ethanol solution.Scanning electron mi...Hollow glass microspheres(HGMs)have great potential in building energy-saving and industrial insulation.Anatase TiO2-modified HGMs were prepared by a sol-gel method in acetic acid-ethanol solution.Scanning electron microscopy,X-ray diffraction,zeta-potential measurements,nitrogen-sorption measurements,and Fourier-transform infrared and ultraviolet-visible-near-infrared diffuse reflectance spectroscopies showed that the alkali modification of the HGMs greatly influenced the loading and microstructure of the TiO2 film.The TiO2 loading could be accurately controlled by ethanol addition and the TiO2 coating time.A mechanism for the TiO2 coating of the HGM surface is proposed.The synergistic action of hydrogen bonding and electrostatic forces resulted in close contact between the HGMs and TiO2 sol at pH 3.5.The effects of different TiO2 loading rates on the reflective and thermal insulation properties were studied.The near-infrared reflectance of 15.9%TiO2 coated on HGMs was 96.27%,and the inner surface temperature of the composite pigment coated on aluminum board was reduced by 22.4℃.The TiO2/HGM composite pigments exhibited excellent solar reflective and thermal insulation properties,so have potential in the construction of exterior walls and roofs.展开更多
A wave rotor is suitable for compact and efficient pressure-exchange between gas flows.This work measured the circumferential pressure distribution of the rotor/stator interfaces and utilized a CFD method to simulate ...A wave rotor is suitable for compact and efficient pressure-exchange between gas flows.This work measured the circumferential pressure distribution of the rotor/stator interfaces and utilized a CFD method to simulate the unsteady pressure waves.The experimental and CFD results showed some slopes in the circumferential pressure distributions,and the slopes indicated the traces of specific unsteady pressure waves.Such traces varied regularly if the rotational speed varied within a range from-11%to+11%off the baseline value,but they were seriously disturbed if the rotational speed varied by-45%from the baseline value.It verified that a pressure wave in a wave rotor tended to keep its pressure ratio and propagation velocity unchanged if the rotational speed varied by a small extent,and that the pressure wave could not keep its propagation patterns if the rotational speed varied by a large extent.Because of the pressure wave behaviors,the wave rotor demonstrated specific regulations of the rotational speed effects on its operational states.展开更多
基金Supported by the National Natural Science Foundation of China(21476267)the China–Japan International Cooperation Project(2013DFG50150)the Hunan Provincial Science and Technology Department Plan Project(2016TP1007)
文摘Zirconium doped mesoporous KIT-6 samples with different Si/Zr ratios were synthesized by the direct hydrothermal method.Various characterization techniques confirm that highly distributed ZrO_2 nanoparticles and multicoordinated Zr^(4+) species are incorporated in the mesoporous composites.One-pot synthesis of 5-hydroxymethylfurfura(HMF) from glucose was examined in the presence of Zr-KIT-6(20) the molar ratio of Si to Zr is 20 under aqueous system.The effects of temperature,reaction time,catalyst dosage and biphasic solvent system on the conversion of glucose and the HMF yield were investigated.It was found that the glucose conversion and the HMF yield have been improved from 54.8% to 79.0% and from 19.5% to 34.5% in the biphasic MIBK-water system,respectively.Both the acidity of Zr-KIT-6(20) and the biphasic MIBK-water system are responsible for the improved performance of glucose dehydration to HMF.
基金This study was financially supported by the National Natural Science Foundation of China(Grant No.21476267)the Hunan Natural Science foundation(Grant No.2018JJ2482).
文摘Hollow glass microspheres(HGMs)have great potential in building energy-saving and industrial insulation.Anatase TiO2-modified HGMs were prepared by a sol-gel method in acetic acid-ethanol solution.Scanning electron microscopy,X-ray diffraction,zeta-potential measurements,nitrogen-sorption measurements,and Fourier-transform infrared and ultraviolet-visible-near-infrared diffuse reflectance spectroscopies showed that the alkali modification of the HGMs greatly influenced the loading and microstructure of the TiO2 film.The TiO2 loading could be accurately controlled by ethanol addition and the TiO2 coating time.A mechanism for the TiO2 coating of the HGM surface is proposed.The synergistic action of hydrogen bonding and electrostatic forces resulted in close contact between the HGMs and TiO2 sol at pH 3.5.The effects of different TiO2 loading rates on the reflective and thermal insulation properties were studied.The near-infrared reflectance of 15.9%TiO2 coated on HGMs was 96.27%,and the inner surface temperature of the composite pigment coated on aluminum board was reduced by 22.4℃.The TiO2/HGM composite pigments exhibited excellent solar reflective and thermal insulation properties,so have potential in the construction of exterior walls and roofs.
基金co-supported by the National Natural Science Foundation of China(No.51906007)the National Key Laboratory Foundation of China(No.6142702190204)。
文摘A wave rotor is suitable for compact and efficient pressure-exchange between gas flows.This work measured the circumferential pressure distribution of the rotor/stator interfaces and utilized a CFD method to simulate the unsteady pressure waves.The experimental and CFD results showed some slopes in the circumferential pressure distributions,and the slopes indicated the traces of specific unsteady pressure waves.Such traces varied regularly if the rotational speed varied within a range from-11%to+11%off the baseline value,but they were seriously disturbed if the rotational speed varied by-45%from the baseline value.It verified that a pressure wave in a wave rotor tended to keep its pressure ratio and propagation velocity unchanged if the rotational speed varied by a small extent,and that the pressure wave could not keep its propagation patterns if the rotational speed varied by a large extent.Because of the pressure wave behaviors,the wave rotor demonstrated specific regulations of the rotational speed effects on its operational states.