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酚醛树脂-CarboresP结合镁碳材料的性能与应用 被引量:12
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作者 柳军 christoph jacob 《耐火材料》 EI CAS 北大核心 2006年第4期256-259,264,共5页
研究了环境友好型含碳材料CarboresP在镁碳砖中的应用。采用MT14A镁碳砖生产工艺,改变CarboresP的加入量,对试样180℃处理后的体积密度、高温抗折强度(1400℃),以及1000℃埋炭处理后的显气孔率、耐压强度等指标进行了研究和对比,确定镁... 研究了环境友好型含碳材料CarboresP在镁碳砖中的应用。采用MT14A镁碳砖生产工艺,改变CarboresP的加入量,对试样180℃处理后的体积密度、高温抗折强度(1400℃),以及1000℃埋炭处理后的显气孔率、耐压强度等指标进行了研究和对比,确定镁碳砖中合适的CarboresP添加量为1%,并且可适量降低金属防氧化剂的加入量;分析了酚醛树脂-CarboresP结合炭的显微结构,表明其为均质炭和非均质石墨化炭的混合结构,这将有助于改善炭化结构的抗氧化性能;采用尖劈试验绘制镁碳砖试样的应力-应变曲线,表明添加CarboresP的镁碳砖的特征长度LCH值得到明显提高,说明它具有很好的韧性和吸收应力的能力;与传统工艺生产的MT14A镁碳砖相比较,采用酚醛树脂-CarboresP“软性结合”工艺生产的MT14A镁碳砖,成型性能及热处理后各项性能指标均得到改善,在国内某40tLF-VD精炼钢包渣线上进行现场使用证明,平均使用寿命比现用渣线镁碳砖提高18.4%。 展开更多
关键词 镁碳砖 炭结构 CarboresP 环境友好 软性结合 尖劈试验 应力-应变
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Properties of Phenolic Resins——CarboresP Binders for Magnesite Carbon Refractories
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作者 LIU Jun christoph jacob 《China's Refractories》 CAS 2006年第4期20-24,共5页
An environmental friendly carbonaceous material- carboresP (one of the Carbores series materials) was investigated for the production of MgO-C refractories in laboratory scale and field tests. The MgO-C specimens we... An environmental friendly carbonaceous material- carboresP (one of the Carbores series materials) was investigated for the production of MgO-C refractories in laboratory scale and field tests. The MgO-C specimens were produced with different CarboresP contents. The bulk density (180℃ × 48h), CCS, apparent porosity (1000℃ ×3h ) and hot modulus of rupture (1400℃ ×0. 5h ) were tested and contrasted. The appropriate amount of carboresP was 1.0%. The amount of metallic additions can be partially substituted (reduced to 1.5% ). The microstructure of resin-carboresP binder is anisotropic structure with high oxidation resistance and good thermal-shock stability. The Stress/strain curve indicates that the characteristic length, (LCH) of MgO-C brick with resin/CarboresP bonding has been improved, which means the MgO-C bricks have good mechanical flexibility and stresses absorbability. Field tests were done in slag line of a 40t LF-VD refining steel ladle using Resin/CarboresP bonded " MT-14A MgO-C bricks. The result shows that the MgO-C bricks by "soft bonding" have good physical properties and excellent workability during production of the bricks . In contrast with traditional MgO-C brick used for secondary refining furnaces, the spalling tendency of the bricks could be reduced significantly. The average lining life of the resin/ CarboresP bricks has increased by 18. 4% comparing with the pure resin-bonded types. 展开更多
关键词 Magnesia carbon bricks Coke structure Environmental friendly CarboresP Soft bonding Wedge splitting test Stress/strain curve
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