Development of p-type transparent conducting thin films is tireless due to the trade-off issue between optical transparency and conductivity. The rarely concerned low normal state resistance makes Bi-based superconduc...Development of p-type transparent conducting thin films is tireless due to the trade-off issue between optical transparency and conductivity. The rarely concerned low normal state resistance makes Bi-based superconducting cuprates the potential hole-type transparent conductors, which have been realized in Bi_(2)Sr_(2)CaCu_(2)O_(y) thin films. In this study, epitaxial superconducting Bi_(2)Sr_(2)CuO_(y) and Bi_(2)Sr_(1.8)Nd_(0.2)CuO_(y) thin films with superior normal state conductivity are proposed as ptype transparent conductors. It is found that the Bi_(2)Sr_(1.8)Nd_(0.2)CuO_(y) thin film with thickness 15 nm shows an average visible transmittance of 65% and room-temperature sheet resistance of 650 Ω/sq. The results further demonstrate that Bi-based cuprate superconductors can be regarded as potential p-type transparent conductors for future optoelectronic applications.展开更多
Several types of REBa2Cu3O7-x (REBCO, RE=Y, Ho etc.) films are prepared on single crystal substrate LaAIO3 by TFA-MOD method. The phase transformation and optimized growth conditions in the crystallization are studi...Several types of REBa2Cu3O7-x (REBCO, RE=Y, Ho etc.) films are prepared on single crystal substrate LaAIO3 by TFA-MOD method. The phase transformation and optimized growth conditions in the crystallization are studied. Compared with SmBCO and GdBCO, high quality YBCO and HoBCO films are relatively easy to produce. It is revealed that the YBCO grains can form at low temperatures such as 730 ℃ during the initial heating ramp. With a high heating rate of 20 K/min and a low oxygen pressure of 100 ppm, the optimum growth temperature is around 780℃, at which the films show a Jc value of 2.88 MMcm2. Further decrease of the heating rate may produce the highquality YBCO Film with a higher Jc of 3.65 MA/cm2. The temperature dependence of resistances in various magnetic fields up to 9 T shows that the present TFAMOD YBCO and HoBCO films have similar superonducting transition temperature and magnetotransport properties.展开更多
The second-generation high-temperature superconductor tape(2G-HTS,also known as a coated conductor)based on REBaCuO(REBa_(2)Cu_(3)O_(7-δ))exhibits high current density and potential cost-effective price/performance,c...The second-generation high-temperature superconductor tape(2G-HTS,also known as a coated conductor)based on REBaCuO(REBa_(2)Cu_(3)O_(7-δ))exhibits high current density and potential cost-effective price/performance,compared with conventional superconducting materials.Using commercial 2G-HTS tapes,more than a dozen cable vendors had been manufacturing REBCO cables,such as the latest kilometer-class REBCO cable,which was incorporated into a civil grid on December 2021,as part of the recordbreaking 35-kV-voltage superconductor cable demonstration project in downtown Shanghai.This paper describes the development of HTS-coated conductors,then outlines the various technological routes for their preparation,reviews the artificial flux pinning of coated conductors,and finally summarizes the technological breakthroughs,the latest research advances,and provides an outlook on their application prospects.展开更多
The research and development of high temperature superconducting (HTS) films, especially ReBa2Cu3- O7-δ (REBCO or RE123; RE=Y, Gd, or other rare earths) yttrium-based coated conductors, has generated widespread i...The research and development of high temperature superconducting (HTS) films, especially ReBa2Cu3- O7-δ (REBCO or RE123; RE=Y, Gd, or other rare earths) yttrium-based coated conductors, has generated widespread interest for the potential applications of the second generation superconducting films. In view of commercialization, however, the maximum superconducting currents for coated conductors should be increased further. Unfortunately, it has been frequently observed that the average critical current density Jc decreases with an increase in film thickness. The thickness effect is still a hurdle for largescale production, especially in pulsed laser deposition and metal organic deposition processes. An engineering current of more than 1 000 A/cm is desired owing to the high cost of 2G superconducting materials. The present work attempts to review the evolution of various issues subject to the thickness effect, including the microstructure, epitaxial texture, surface roughness, pinning force, oxygen deficiency, residual stress, copper-rich layers, and segregation of elements. Furthermore, recent progress in enhancing the performance of superconductors especially in terms of critical current density is illustrated, such as the use of heavy doping. Further understanding of the thickness effect is extremely important for large-scale commercial development of the second generation high temperature superconductors.展开更多
We present a systematic study of the impurity scattering effect induced by Pd dopants in the super- conductor SrPt3P. Using a solid-state reaction method, we fabricated the Pd-doped superconductor Sr(Pt1-xPdx)3P. We...We present a systematic study of the impurity scattering effect induced by Pd dopants in the super- conductor SrPt3P. Using a solid-state reaction method, we fabricated the Pd-doped superconductor Sr(Pt1-xPdx)3P. We found that the residual resistivity P0 increases quickly with Pd doping, whereas the residual resistance ratio (RRR) displays a dramatic reduction. In addition, both the nonlinear field-dependent behavior of the Hall resistivity Pxy and the strong temperature dependence of the Hall coefficient RH at low temperature are suppressed by Pd doping. All the experimental results can be explained by an increase in scattering by impurities induced by doping. Our results suggest that the Pt position is very crucial to the carrier conduction in the present system.展开更多
基金Project supported by the National Natural Science Foundation of China (Grant No. 11604337)。
文摘Development of p-type transparent conducting thin films is tireless due to the trade-off issue between optical transparency and conductivity. The rarely concerned low normal state resistance makes Bi-based superconducting cuprates the potential hole-type transparent conductors, which have been realized in Bi_(2)Sr_(2)CaCu_(2)O_(y) thin films. In this study, epitaxial superconducting Bi_(2)Sr_(2)CuO_(y) and Bi_(2)Sr_(1.8)Nd_(0.2)CuO_(y) thin films with superior normal state conductivity are proposed as ptype transparent conductors. It is found that the Bi_(2)Sr_(1.8)Nd_(0.2)CuO_(y) thin film with thickness 15 nm shows an average visible transmittance of 65% and room-temperature sheet resistance of 650 Ω/sq. The results further demonstrate that Bi-based cuprate superconductors can be regarded as potential p-type transparent conductors for future optoelectronic applications.
基金This work was supported by the National Natural Science Foundation of China under Grant No. 50672057, 50702033 and 10774098the National Science Foundation of China (973 Projects) under Grant No. 2006CB601005+1 种基金the Science and Technology Commission of Shanghai Municipality under Grant No. 0752nm017the Project Based Personnel Exchange Program between China and Germany under Grant No. [2006] 3139.
文摘Several types of REBa2Cu3O7-x (REBCO, RE=Y, Ho etc.) films are prepared on single crystal substrate LaAIO3 by TFA-MOD method. The phase transformation and optimized growth conditions in the crystallization are studied. Compared with SmBCO and GdBCO, high quality YBCO and HoBCO films are relatively easy to produce. It is revealed that the YBCO grains can form at low temperatures such as 730 ℃ during the initial heating ramp. With a high heating rate of 20 K/min and a low oxygen pressure of 100 ppm, the optimum growth temperature is around 780℃, at which the films show a Jc value of 2.88 MMcm2. Further decrease of the heating rate may produce the highquality YBCO Film with a higher Jc of 3.65 MA/cm2. The temperature dependence of resistances in various magnetic fields up to 9 T shows that the present TFAMOD YBCO and HoBCO films have similar superonducting transition temperature and magnetotransport properties.
基金supported in part by the Strategic Priority Research Program of the Chinese Academy of Sciences(Grant No.XDB25000000)by the National Natural Science Foundation(Grant No.52172271)by the National Key R&D Program of China(Grant No.2022YFE03150200)。
文摘The second-generation high-temperature superconductor tape(2G-HTS,also known as a coated conductor)based on REBaCuO(REBa_(2)Cu_(3)O_(7-δ))exhibits high current density and potential cost-effective price/performance,compared with conventional superconducting materials.Using commercial 2G-HTS tapes,more than a dozen cable vendors had been manufacturing REBCO cables,such as the latest kilometer-class REBCO cable,which was incorporated into a civil grid on December 2021,as part of the recordbreaking 35-kV-voltage superconductor cable demonstration project in downtown Shanghai.This paper describes the development of HTS-coated conductors,then outlines the various technological routes for their preparation,reviews the artificial flux pinning of coated conductors,and finally summarizes the technological breakthroughs,the latest research advances,and provides an outlook on their application prospects.
基金This work was supported in part by Shanghai Key Laboratory of High Temperature Superconductors (Grant No. 14DZ2260700), the Science and Technology Commission of Shanghai Municipality (Grant Nos. 13111102300 and 14521102800), and the National Natural Science Foundation of China (Grant Nos. 51572165, 11174193 and 51202141).
文摘The research and development of high temperature superconducting (HTS) films, especially ReBa2Cu3- O7-δ (REBCO or RE123; RE=Y, Gd, or other rare earths) yttrium-based coated conductors, has generated widespread interest for the potential applications of the second generation superconducting films. In view of commercialization, however, the maximum superconducting currents for coated conductors should be increased further. Unfortunately, it has been frequently observed that the average critical current density Jc decreases with an increase in film thickness. The thickness effect is still a hurdle for largescale production, especially in pulsed laser deposition and metal organic deposition processes. An engineering current of more than 1 000 A/cm is desired owing to the high cost of 2G superconducting materials. The present work attempts to review the evolution of various issues subject to the thickness effect, including the microstructure, epitaxial texture, surface roughness, pinning force, oxygen deficiency, residual stress, copper-rich layers, and segregation of elements. Furthermore, recent progress in enhancing the performance of superconductors especially in terms of critical current density is illustrated, such as the use of heavy doping. Further understanding of the thickness effect is extremely important for large-scale commercial development of the second generation high temperature superconductors.
基金This work was supported by the National Natural Science Foundation of China (Grant No. 11204338), the "Strategic Priority Research Program (B)" of the Chinese Academy of Sciences (Grant No. XDB04040300), and the Youth Innovation Promotion Association of the Chinese Academy of Sciences (Grant No. 2015187). This work was partly sponsored by the Science and Technology Commission of Shanghai Municipality (Grant Nos. 14DZ2260700 and 14521102800).
文摘We present a systematic study of the impurity scattering effect induced by Pd dopants in the super- conductor SrPt3P. Using a solid-state reaction method, we fabricated the Pd-doped superconductor Sr(Pt1-xPdx)3P. We found that the residual resistivity P0 increases quickly with Pd doping, whereas the residual resistance ratio (RRR) displays a dramatic reduction. In addition, both the nonlinear field-dependent behavior of the Hall resistivity Pxy and the strong temperature dependence of the Hall coefficient RH at low temperature are suppressed by Pd doping. All the experimental results can be explained by an increase in scattering by impurities induced by doping. Our results suggest that the Pt position is very crucial to the carrier conduction in the present system.