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滨海湿地环境中微塑料表面性质及形貌变化 被引量:11
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作者 周倩 涂晨 +7 位作者 张晨捷 章海波 付传城 李远 李连祯 熊宽旭 徐笠 骆永明 《科学通报》 EI CAS CSCD 北大核心 2021年第13期1580-1591,共12页
海岸带湿地是微塑料的重要聚集区.目前,对海岸带真实湿地土壤环境中微塑料表面形貌和性质变化研究甚少.本研究选取我国北方温带的黄河口盐沼湿地和南方亚热带的北部湾红树林湿地,以聚苯乙烯发泡和聚乙烯薄膜为受试微塑料对象,通过原位... 海岸带湿地是微塑料的重要聚集区.目前,对海岸带真实湿地土壤环境中微塑料表面形貌和性质变化研究甚少.本研究选取我国北方温带的黄河口盐沼湿地和南方亚热带的北部湾红树林湿地,以聚苯乙烯发泡和聚乙烯薄膜为受试微塑料对象,通过原位土壤掩埋(地下暴露)和非掩埋(地上暴露)定位试验和定期采样,观察和分析微塑料表面形貌、官能团、比表面积和疏水性等变化,以揭示南北典型生物地理海岸带湿地环境微塑料表面性质及形貌变化特征.在形貌上,南方北部湾红树林湿地中发泡微塑料表面出现更多的凹坑和孔洞,地上暴露的发泡18个月后,表面发生脆化和易脱落现象,而地下暴露的未出现此现象;对于比表面积,黄河口盐沼湿地原位土壤掩埋发泡和薄膜的更高;对于羰基指数,黄河口盐沼湿地土壤环境中发泡和薄膜表面的增长速率更快,地上暴露的微塑料更容易老化;对于表面疏水性,南北两类湿地土壤中掩埋薄膜表面疏水性均降低.对于微塑料类型,发泡和薄膜型微塑料均以大孔和介孔为主,发泡表面形貌更易发生变化,但薄膜比表面积变化更大.可见,滨海土壤环境微塑料表面性质及形貌变化与湿地类型及条件、微塑料种类及其暴露方式和时间等多因素有关,但对这些变化的机理有待深入研究.综上,本研究可为我国海岸带环境微塑料表面微界面化学过程和环境行为研究及其风险管控提供科学依据. 展开更多
关键词 微塑料 盐沼 红树林 海岸带湿地 定位试验 表面变化
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Spatial interpolation of orchard soil pH using soil type and planting duration as auxiliary information 被引量:1
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作者 chuancheng fu Haibo ZHANG +3 位作者 Chen TU Lianzhen LI Xinghua LIU Yongming LUO 《Pedosphere》 SCIE CAS CSCD 2020年第5期628-637,共10页
Intensified field management in orcahrds has resulted in significant and widespread acidification in the soils.However,effectively mapping the spatial patterns of soil pH aiming to support ecological management is imp... Intensified field management in orcahrds has resulted in significant and widespread acidification in the soils.However,effectively mapping the spatial patterns of soil pH aiming to support ecological management is impeded by its large variotions across soil types and planting durations.Kriging methods were used to integrate soil type and planting duration information for effective mapping of orchard soil pH in a case study in orchards of the Northeast Jiaodong Peninsula,East China.A total o f 1472 surface soil samples were collected,and the planting duration o f each sampled orchard was acquired to generate a planting duration map via Voronoi tessellations.The performance of five kriging methods was compared,namely,ordinary kriging(OK),OK combined with soil type(OK_ST),OK combined with planting duration(OK_PD),cokriging combined with soil type and planting duration(OCK_STPD),and OK combined with soil type and planting duration(OK_STPD).Results showed that soil pH declined significantly with increasing planting duration and exhibited moderate spatial variability over the study area.Soil type and planting duration both had significant influence on the spatial distribution of soil pH.The OCK_STPD and OK_STPD methods showed better prediction efficiency than OK,OK_ST,or OK_PD.With regard to the predicted maps of soil pH,the OCK_STPD and OK_STPD methods highly reflected local variations associated with soil type and planting duration,but the OK method was poorly representative.Categorical soil type and planting duration information may be used as ancillary information to improve the mapping quality o f orchard soil pH.The OCK_STPD and OK_STPD methods were practical and efficient methods for interpolating orchard soil pH in the study area.The resultant high-quality soil pH maps can contribute to improved site-specific management in the orchards. 展开更多
关键词 Jiaodong Peninsula COKRIGING KRIGING orchard soil properties soil acidification soil map
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