Organometallic halide perovskite materials make great achievements in optoelectronic fields,especially in solar cells,in which the organic cations contain amine components.However,the amine with NàH bonds is easi...Organometallic halide perovskite materials make great achievements in optoelectronic fields,especially in solar cells,in which the organic cations contain amine components.However,the amine with NàH bonds is easily hydrolyzed with moisture in the air,weakening the perovskite materials stability.It is desirable to develop other non-amine stable perovskite materials.In this work,sulfur-based perovskite-like(CH_(3))_(3)SPbI_(3) nanorod arrays were fabricated by a solution-processed method,which can be indexed hexagonal crystal structure in the space group P63 mc.The binding force is exceptionally strong between the non-amine(CH_(3))_(3) S+and[PbI_(6)]_(4)-octahedral,leading to high stability of(CH_(3))_(3)SPbI_(3).The(CH_(3))_(3)SPbI_(3) nanorod arrays can keep the morphology and crystal structure in an ambient atmosphere over 60 days.In addition,the(CH_(3))_(3)SPbI_(3) nanorod arrays can offer direct charge transfer channels,which show excellent optoelectronic properties.The(CH_(3))_(3)SPbI_(3) nanorod arrays-based solar cells with VOx hole transfer layers achieved a power conversion efficiency of 2.07%with negligible hysteresis.And the(CH_(3))_(3)SPbI_(3) nanorod arrays were also effectively applied in photodetectors with interdigitated gold electrodes.This work demonstrates that sulfur-based perovskite-like(CH_(3))_(3)SPbI_(3) is a novel promising stable compound with great potential for practical optoelectronic applications.展开更多
Mixed-dimensional engineering of perovskite material has been demonstrated as a facile and promising strategy to improve both photovoltaic performance and long-term stability of perovskite solar cells(PSCs).In this st...Mixed-dimensional engineering of perovskite material has been demonstrated as a facile and promising strategy to improve both photovoltaic performance and long-term stability of perovskite solar cells(PSCs).In this study,we report an in-plane preferred orientation of 1D perovskite induced by an ionic liquid(IL)of 1-(3-cyanopropyl)-3-methylimidazolium chloride(CPMIMCl)for the first time via sequential deposition approach,leading to a mixed dimensional perovskite thin films.The generated one-dimensional(1D)CPMIMPbI3 with in-plane orientation resides at the grain boundaries of three-dimensional(3D)perovskite can be appreciably observed from the morphology level,leading to creation of high-quality films with large grain size with more efficient defect passivation.Moreover,the dispersion of IL in the bulk phase of perovskite material allows for the formation of 1D perovskite for multiple level passivation to inhibit non-radiative recombination and optimize carrier transport.This IL engineering strategy not only yields a mixed-dimensional perovskite heterostructure with in-plane orientation 1D perovskite nano-rods but also significantly improves the opto-electronic property with suppressed trap states.As a result,the CPMIMCl-treated PSCs show an enhanced photovoltaic performance with a champion power conversion efficiency(PCE)up to 24.13%.More importantly,benefiting from the hydrophobicity of formed 1D perovskite and defects suppression,the corresponding PSC demonstrates an excellent longterm stability and maintain 97.1%of its pristine PCE at 25C under 50%RH condition over 1000 h.This research provides an innovative perspective for employing the low dimensional engineering to optimize the performance and stability of photovoltaic devices.展开更多
The rapid development of perovskite solar cells(PSCs)over the past decade makes it the most promising next generation photovoltaic technology.Splendid progress in efficiency and stability has been demonstrated in labo...The rapid development of perovskite solar cells(PSCs)over the past decade makes it the most promising next generation photovoltaic technology.Splendid progress in efficiency and stability has been demonstrated in laboratory level,while endeavours are extremely required to enable successful transfer of the printable PSC technology to industry scale toward commercialization.In this work,recent progresses on upscaling of PSCs are systematically reviewed.Starting with the traditional PSC structure,we have analyzed the specially designed configuration for perovskite solar modules(PSMs).The comprehensive overview and assessment are provided for the technologies engineering in large-scale preparation,including both solution processing and vapor-phase deposition methods.Considering the promoting effect of material engineering to scale up PSMs,the application of additive engineering,solvent engineering and interface engineering on the stability and efficiency of PSMs is systematacially discussed.Moreover,the effect of current packaging technology of PSMs on device lifetime and environmental friendliness is emphasized.At last,we propose the prospects and challenges of PSMs commercialization in the future to meet the requirements for next generation photovoltaic industry.展开更多
基金the financial support from the National Natural Science Foundation of China(U1732126,11804166,51602161,51372119)the Natural Science Foundation of Jiangsu Province(BK20150860)the Postgraduate Research&Practice Innovation Program of Jiangsu Province(KYCX180846,KYCX180869)。
文摘Organometallic halide perovskite materials make great achievements in optoelectronic fields,especially in solar cells,in which the organic cations contain amine components.However,the amine with NàH bonds is easily hydrolyzed with moisture in the air,weakening the perovskite materials stability.It is desirable to develop other non-amine stable perovskite materials.In this work,sulfur-based perovskite-like(CH_(3))_(3)SPbI_(3) nanorod arrays were fabricated by a solution-processed method,which can be indexed hexagonal crystal structure in the space group P63 mc.The binding force is exceptionally strong between the non-amine(CH_(3))_(3) S+and[PbI_(6)]_(4)-octahedral,leading to high stability of(CH_(3))_(3)SPbI_(3).The(CH_(3))_(3)SPbI_(3) nanorod arrays can keep the morphology and crystal structure in an ambient atmosphere over 60 days.In addition,the(CH_(3))_(3)SPbI_(3) nanorod arrays can offer direct charge transfer channels,which show excellent optoelectronic properties.The(CH_(3))_(3)SPbI_(3) nanorod arrays-based solar cells with VOx hole transfer layers achieved a power conversion efficiency of 2.07%with negligible hysteresis.And the(CH_(3))_(3)SPbI_(3) nanorod arrays were also effectively applied in photodetectors with interdigitated gold electrodes.This work demonstrates that sulfur-based perovskite-like(CH_(3))_(3)SPbI_(3) is a novel promising stable compound with great potential for practical optoelectronic applications.
基金supported by the Scientific Research Startup Fund for Shenzhen High-Caliber Personnel of Shenzhen Polytechnic,No.6022310038k and 6022310049kThe financial support from the National Natural Science Foundation of China(No.62004129)+4 种基金Guangdong Basic and Applied Basic Research Foundation(No.2023A1515011677)Shenzhen Science and Technology Innovation Commission(Project No.JCYJ20200109105003940,Project No.20220811205532001,Project NO.20220813171052002)Research Grants Council of Hong Kong(GRF grant 15221320,CRF C5037-18G,C7018-20G)the Hong Kong Polytechnic University funds(Sir Sze-yuen Chung Endowed Professorship Fund(8-8480)RISE(Q-CDA5))is gratefully acknowledged.The authors thank the AFM technical support from Oxford Instrument.
文摘Mixed-dimensional engineering of perovskite material has been demonstrated as a facile and promising strategy to improve both photovoltaic performance and long-term stability of perovskite solar cells(PSCs).In this study,we report an in-plane preferred orientation of 1D perovskite induced by an ionic liquid(IL)of 1-(3-cyanopropyl)-3-methylimidazolium chloride(CPMIMCl)for the first time via sequential deposition approach,leading to a mixed dimensional perovskite thin films.The generated one-dimensional(1D)CPMIMPbI3 with in-plane orientation resides at the grain boundaries of three-dimensional(3D)perovskite can be appreciably observed from the morphology level,leading to creation of high-quality films with large grain size with more efficient defect passivation.Moreover,the dispersion of IL in the bulk phase of perovskite material allows for the formation of 1D perovskite for multiple level passivation to inhibit non-radiative recombination and optimize carrier transport.This IL engineering strategy not only yields a mixed-dimensional perovskite heterostructure with in-plane orientation 1D perovskite nano-rods but also significantly improves the opto-electronic property with suppressed trap states.As a result,the CPMIMCl-treated PSCs show an enhanced photovoltaic performance with a champion power conversion efficiency(PCE)up to 24.13%.More importantly,benefiting from the hydrophobicity of formed 1D perovskite and defects suppression,the corresponding PSC demonstrates an excellent longterm stability and maintain 97.1%of its pristine PCE at 25C under 50%RH condition over 1000 h.This research provides an innovative perspective for employing the low dimensional engineering to optimize the performance and stability of photovoltaic devices.
基金supported by the Scientific Research Start-up Fund for Shenzhen High-Caliber Personnel of Shenzhen Polytechnic,No.6022310038kThe financial support from the Research Grants Council of Hong Kong(CRF C7018-20G,C5037-18G)+2 种基金the Hong Kong Polytechnic University funds(Sir Sze-yuen Chung Endowed Professorship Fund(8-8480),and RISE(Q-CDA5))National Natural Science Foundation of China(62004129)Shenzhen Science and Technology Innovation Commission(Project No.JCYJ20200109105003940)are gratefully acknowledged.
文摘The rapid development of perovskite solar cells(PSCs)over the past decade makes it the most promising next generation photovoltaic technology.Splendid progress in efficiency and stability has been demonstrated in laboratory level,while endeavours are extremely required to enable successful transfer of the printable PSC technology to industry scale toward commercialization.In this work,recent progresses on upscaling of PSCs are systematically reviewed.Starting with the traditional PSC structure,we have analyzed the specially designed configuration for perovskite solar modules(PSMs).The comprehensive overview and assessment are provided for the technologies engineering in large-scale preparation,including both solution processing and vapor-phase deposition methods.Considering the promoting effect of material engineering to scale up PSMs,the application of additive engineering,solvent engineering and interface engineering on the stability and efficiency of PSMs is systematacially discussed.Moreover,the effect of current packaging technology of PSMs on device lifetime and environmental friendliness is emphasized.At last,we propose the prospects and challenges of PSMs commercialization in the future to meet the requirements for next generation photovoltaic industry.