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Nickel-catalyzed reductive coupling of glucosyl halides with aryl/vinyl halides enabling β-selective preparation of C-aryl/vinyl glucosides
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作者 JiANDong Liu chuanhu lei Hegui Gong 《Science China Chemistry》 SCIE EI CAS CSCD 2019年第11期1492-1496,共5页
This work describes stereoselective preparation ofβ-C-aryl/vinyl glucosides via mild Ni-catalyzed reductive arylation and vinylation of C1-glucosyl halides with aryl and vinyl halides.A broad range of aryl halides an... This work describes stereoselective preparation ofβ-C-aryl/vinyl glucosides via mild Ni-catalyzed reductive arylation and vinylation of C1-glucosyl halides with aryl and vinyl halides.A broad range of aryl halides and vinyl halides were employed to yield C-aryl/vinyl glucosides in 42%–93%yields.Good to excellentβ-selectivities were obtained for C-glucosides by using tridentate ligand. 展开更多
关键词 NICKEL-CATALYZED reductive coupling β-selective PREPARATION C-aryl/vinyl GLUCOSIDES
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