Mg2Ni0.7M0.3(M=Al,Mn and Ti)alloys were prepared by solid phase sintering process.The phases and microstructure of the alloys were systematically characterized by XRD,SEM and STEM.It was found that Mg3MNi2intermetalli...Mg2Ni0.7M0.3(M=Al,Mn and Ti)alloys were prepared by solid phase sintering process.The phases and microstructure of the alloys were systematically characterized by XRD,SEM and STEM.It was found that Mg3MNi2intermetallic compounds formed in Mg2Ni0.7M0.3alloys and coexisted with Mg and Mg2Ni,and that radius of M atoms closer to that of Mg atom was more beneficial to the formation of Mg3MNi2.The hydrogen storage properties and corrosion resistance of Mg2Ni0.7M0.3alloys were investigated through Sievert and Tafel methods.Mg2Ni0.7M0.3alloys exhibited remarkably improved hydrogen absorption and desorption properties.Significantly reduced apparent dehydriding activation energy values of-46.12,-59.16and-73.15kJ/mol were achieved for Mg2Ni0.7Al0.3,Mg2Ni0.7Mn0.3and Mg2Ni0.7Ti0.3alloys,respectively.The corrosion potential of Mg2Ni0.7M0.3alloys shifted to the positive position compared with Mg2Ni alloy,e.g.there was a corrosion potential difference of0.110V between Mg2Ni0.7Al0.3alloy(-0.529V)and Mg2Ni(-0.639V),showing improved anti-corrosion properties by the addition of Al,Mn and Ti.展开更多
Surface modification of graphite anode with electroactive matters has been proven of a more practical strategy in enhancing the performance of Li-ion batteries than exploring alternative novel anode materials.Herein,r...Surface modification of graphite anode with electroactive matters has been proven of a more practical strategy in enhancing the performance of Li-ion batteries than exploring alternative novel anode materials.Herein,rutile TiNbO_(4-x) nanoparticles with a tunnel structure are employed as multifunctional decoration substances in combination with a carbon coating layer to improve the rate and cycle properties of mesocarbon microbeads(MCMBs).As compared to pristine MCMB,the Li^(+)diffusion coefficients of the composite anodes are enhanced due to the synergistic effect of TiNbO_(4-x)@C.Meanwhile,the overcharge and voltage polarization of the composite anodes at high rate are obviously minimized due to the current sharing effect of the high-potential TiNbO_(4-x).Moreover,the amorphous Li_(y)TiNbO_(4-x) converted from TiNbO_(4-x) in the initial lithiation process can deliver pseudocapacitive capacity to the composite anodes from the second cycle.All of these functions of TiNbO_(4-x)@Ccoating layer have directly contributed to the improved rate and cycle performance of the MCMB/TiNbO_(4-x)@C composite anodes.The one containing 12.0 wt%TiNbO_(4-x) exhibits a high reversible specific capacity of 118 m Ah·g^(-1)at 10C(1C=372 m A·g^(-1)),together with a high capacity retention of 90.9%after 300 cycles at 3C,which are all much superior to those of pristine MCMB.展开更多
基金Project (2016J01266) supported by the Natural Science Foundation of Fujian Province,ChinaProject (JZ160474) supported by the Science and Technology Project of Education Department of Fujian Province,China
文摘Mg2Ni0.7M0.3(M=Al,Mn and Ti)alloys were prepared by solid phase sintering process.The phases and microstructure of the alloys were systematically characterized by XRD,SEM and STEM.It was found that Mg3MNi2intermetallic compounds formed in Mg2Ni0.7M0.3alloys and coexisted with Mg and Mg2Ni,and that radius of M atoms closer to that of Mg atom was more beneficial to the formation of Mg3MNi2.The hydrogen storage properties and corrosion resistance of Mg2Ni0.7M0.3alloys were investigated through Sievert and Tafel methods.Mg2Ni0.7M0.3alloys exhibited remarkably improved hydrogen absorption and desorption properties.Significantly reduced apparent dehydriding activation energy values of-46.12,-59.16and-73.15kJ/mol were achieved for Mg2Ni0.7Al0.3,Mg2Ni0.7Mn0.3and Mg2Ni0.7Ti0.3alloys,respectively.The corrosion potential of Mg2Ni0.7M0.3alloys shifted to the positive position compared with Mg2Ni alloy,e.g.there was a corrosion potential difference of0.110V between Mg2Ni0.7Al0.3alloy(-0.529V)and Mg2Ni(-0.639V),showing improved anti-corrosion properties by the addition of Al,Mn and Ti.
基金supported by the Natural Science Foundation Project of Fujian Province(Nos.2020J01287 and 2020H0024)。
文摘Surface modification of graphite anode with electroactive matters has been proven of a more practical strategy in enhancing the performance of Li-ion batteries than exploring alternative novel anode materials.Herein,rutile TiNbO_(4-x) nanoparticles with a tunnel structure are employed as multifunctional decoration substances in combination with a carbon coating layer to improve the rate and cycle properties of mesocarbon microbeads(MCMBs).As compared to pristine MCMB,the Li^(+)diffusion coefficients of the composite anodes are enhanced due to the synergistic effect of TiNbO_(4-x)@C.Meanwhile,the overcharge and voltage polarization of the composite anodes at high rate are obviously minimized due to the current sharing effect of the high-potential TiNbO_(4-x).Moreover,the amorphous Li_(y)TiNbO_(4-x) converted from TiNbO_(4-x) in the initial lithiation process can deliver pseudocapacitive capacity to the composite anodes from the second cycle.All of these functions of TiNbO_(4-x)@Ccoating layer have directly contributed to the improved rate and cycle performance of the MCMB/TiNbO_(4-x)@C composite anodes.The one containing 12.0 wt%TiNbO_(4-x) exhibits a high reversible specific capacity of 118 m Ah·g^(-1)at 10C(1C=372 m A·g^(-1)),together with a high capacity retention of 90.9%after 300 cycles at 3C,which are all much superior to those of pristine MCMB.
