Ladderlike polyhydroxypropylsilsesquioxane (HO-T) was synthesized by alcoholysis of ladderlike poly(3-propionyloxy-propyl)silsesquioxane. The HO-T was characterized by GPC, IR, NMR, DSC, TGA and X-ray diffraction meth...Ladderlike polyhydroxypropylsilsesquioxane (HO-T) was synthesized by alcoholysis of ladderlike poly(3-propionyloxy-propyl)silsesquioxane. The HO-T was characterized by GPC, IR, NMR, DSC, TGA and X-ray diffraction methods. Through hydrogen-bonding interaction, ladderlike polymer (HO-T) can form a supramolecular complex with somewhat regular structure.展开更多
基金This project is financially supported by National Natural Science Foundation of China (No. 29874034).
文摘Ladderlike polyhydroxypropylsilsesquioxane (HO-T) was synthesized by alcoholysis of ladderlike poly(3-propionyloxy-propyl)silsesquioxane. The HO-T was characterized by GPC, IR, NMR, DSC, TGA and X-ray diffraction methods. Through hydrogen-bonding interaction, ladderlike polymer (HO-T) can form a supramolecular complex with somewhat regular structure.