The TiNw-AINp/Al composite has been successfully fabricated by gas-liquid reaction method in an intensive electromagnetic mixing and casting in an appropriate cooling condition. The as-cast samples of the composite ex...The TiNw-AINp/Al composite has been successfully fabricated by gas-liquid reaction method in an intensive electromagnetic mixing and casting in an appropriate cooling condition. The as-cast samples of the composite exhibit a homogeneous distribution of TiNw and AINp, and the in situ formed TiN whisker has a mean diameter of 0.5 μm and mean aspect ratio of 5.8~7.5, and the diameter of the AIN particulates is less than 5 μm. TEM observation indicates that there exist some submicron and nanometer sized in situ formed TiNw-AINp in α-Al matrix. The formation mechanism of in situ formed TiNw and AINp is also discussed展开更多
This paper deals with a series of novel processing techniques based on the in situ production of metal matrix composites (MMCs). In situ techniques involve a chemical reaction resulting in the formation of a very fine...This paper deals with a series of novel processing techniques based on the in situ production of metal matrix composites (MMCs). In situ techniques involve a chemical reaction resulting in the formation of a very fine and thermodynamically stable reinforcing ceramic phase within a metal matrix. As a result, this provides thermodynamic compatibility at the matrix-reinforcement interface. The reinforcement surfaces are also likely to be free of contamination and, therefore, a stronger matrix-dispersion bond can be achieved. Some of these technologies including DIMOX^? XD, PRIMEX^? reactive gas infiltration, high-temperature self-propagating synthesis (SHS), and liquid-solid, or solid-gas-liquid reactions as well as plasma in situ MMCs are expressed in this paper.展开更多
In order to calculate 3-dimensional Ising model,we develop a method to build a much smaller transfer matrix containing the largest eigenvalue from the original 2^(N_1N_2) × 2^(N_1N_2) matrix V_1. Firstly,the tran...In order to calculate 3-dimensional Ising model,we develop a method to build a much smaller transfer matrix containing the largest eigenvalue from the original 2^(N_1N_2) × 2^(N_1N_2) matrix V_1. Firstly,the transfer matrix V_1 is written as the linear combination of several basic vectors. Secondly,we divide the basic vectors into several subgroups. The multiplication of a basic vector and V_1 can be written as the linear combination of basic vectors from the same subgroup. Finally,we use a new transfer matrix V_2 to describe the relationship between basic vectors of the same subgroup.V_2 is much smaller than the original transfer matrix and contains the largest eigenvalue of V_1.We use this method to calculate the specific heat per atom Cpaand the magnetic momentum per atom Mpa. The results show that there exists a pair of temperature and magnetic field intensity where the specific heat gets to its maximum value. When N_1N_2 increases,the maximum value of specific heat becomes larger.展开更多
Highly ordered Tb_(x)Fe_(7)Co_(3)(x=0,0.6,0.8)nanowires were synthesized in alumina templates by electrochemical deposition method.Here,the effects of Tb content and annealing treatment on the phase composition,morpho...Highly ordered Tb_(x)Fe_(7)Co_(3)(x=0,0.6,0.8)nanowires were synthesized in alumina templates by electrochemical deposition method.Here,the effects of Tb content and annealing treatment on the phase composition,morphology,crystalline structure and magnetic properties were investigated.The asdeposited Tb_0 Fe_(7)Co_(3)nanowires comprise Fe_(7)Co_(3)phase.While after adding Tb,the diffraction peaks slightly shift left,indicating the infiltration of Tb atoms into Fe_(7)Co_(3)phase.After annealing,Tb_0 Fe_(7)Co_(3)nanowires still consist of Fe_(7)Co_(3)phase with a slight enhancement on coercivity.While the annealed nanowires with Tb doped present a complex phase composition containing Fe3 Tb,Fe_(2)Tb,Co_(3)Tb,Co_(17)Tb_(2),TbFeO_(3)and Fe_(2)O_(3)phases distribute in the central portion,and Co_(0.72)Fe_(0.28)at the nanowire outer walls.The annealed Tb_(x)Fe_(7)Co_(3)(x=0.6,0.8)nanowires show higher magnetic performance owing to the formation of hard magnetic phases,the interfacial elastic coupling between hard and soft phases and the coherent Fe3 Tb/Co_(3)Tb interface which restrain the domain wall motion.To be specific,the coercivity and remanence ratio of TbxFe_(7)Co_(3)(x=0.6,0.8)nanowires significantly enhance with increasing Tb content.展开更多
文摘The TiNw-AINp/Al composite has been successfully fabricated by gas-liquid reaction method in an intensive electromagnetic mixing and casting in an appropriate cooling condition. The as-cast samples of the composite exhibit a homogeneous distribution of TiNw and AINp, and the in situ formed TiN whisker has a mean diameter of 0.5 μm and mean aspect ratio of 5.8~7.5, and the diameter of the AIN particulates is less than 5 μm. TEM observation indicates that there exist some submicron and nanometer sized in situ formed TiNw-AINp in α-Al matrix. The formation mechanism of in situ formed TiNw and AINp is also discussed
文摘This paper deals with a series of novel processing techniques based on the in situ production of metal matrix composites (MMCs). In situ techniques involve a chemical reaction resulting in the formation of a very fine and thermodynamically stable reinforcing ceramic phase within a metal matrix. As a result, this provides thermodynamic compatibility at the matrix-reinforcement interface. The reinforcement surfaces are also likely to be free of contamination and, therefore, a stronger matrix-dispersion bond can be achieved. Some of these technologies including DIMOX^? XD, PRIMEX^? reactive gas infiltration, high-temperature self-propagating synthesis (SHS), and liquid-solid, or solid-gas-liquid reactions as well as plasma in situ MMCs are expressed in this paper.
基金Sponsored by the National Natural Science Foundation of China(Grant No.51271070)the Natural Science Foundation of Hebei Province(Grant No.E2014202008,E2016202406)+2 种基金the National Science and Technology Program-International Collaborative Research Project(Grant No.2010DFA51920)the Key Program from the science and Technology Research for Colleges and Universities in Hebei Province(Grant No.ZH2011202)the Key Lab.for New Type of Functional Materials in Hebei Province
文摘In order to calculate 3-dimensional Ising model,we develop a method to build a much smaller transfer matrix containing the largest eigenvalue from the original 2^(N_1N_2) × 2^(N_1N_2) matrix V_1. Firstly,the transfer matrix V_1 is written as the linear combination of several basic vectors. Secondly,we divide the basic vectors into several subgroups. The multiplication of a basic vector and V_1 can be written as the linear combination of basic vectors from the same subgroup. Finally,we use a new transfer matrix V_2 to describe the relationship between basic vectors of the same subgroup.V_2 is much smaller than the original transfer matrix and contains the largest eigenvalue of V_1.We use this method to calculate the specific heat per atom Cpaand the magnetic momentum per atom Mpa. The results show that there exists a pair of temperature and magnetic field intensity where the specific heat gets to its maximum value. When N_1N_2 increases,the maximum value of specific heat becomes larger.
基金Project supported by National Natural Science Foundation of China(51271070,51871087)the Natural Science Foundation of Hebei Province(E2016202406)。
文摘Highly ordered Tb_(x)Fe_(7)Co_(3)(x=0,0.6,0.8)nanowires were synthesized in alumina templates by electrochemical deposition method.Here,the effects of Tb content and annealing treatment on the phase composition,morphology,crystalline structure and magnetic properties were investigated.The asdeposited Tb_0 Fe_(7)Co_(3)nanowires comprise Fe_(7)Co_(3)phase.While after adding Tb,the diffraction peaks slightly shift left,indicating the infiltration of Tb atoms into Fe_(7)Co_(3)phase.After annealing,Tb_0 Fe_(7)Co_(3)nanowires still consist of Fe_(7)Co_(3)phase with a slight enhancement on coercivity.While the annealed nanowires with Tb doped present a complex phase composition containing Fe3 Tb,Fe_(2)Tb,Co_(3)Tb,Co_(17)Tb_(2),TbFeO_(3)and Fe_(2)O_(3)phases distribute in the central portion,and Co_(0.72)Fe_(0.28)at the nanowire outer walls.The annealed Tb_(x)Fe_(7)Co_(3)(x=0.6,0.8)nanowires show higher magnetic performance owing to the formation of hard magnetic phases,the interfacial elastic coupling between hard and soft phases and the coherent Fe3 Tb/Co_(3)Tb interface which restrain the domain wall motion.To be specific,the coercivity and remanence ratio of TbxFe_(7)Co_(3)(x=0.6,0.8)nanowires significantly enhance with increasing Tb content.