Carbyne delivers various excellent properties for the existence of the larger number of sp-hybridized carbon atoms.Here,a 3D well-defined porous carbon material germanium-carbdiyne(Ge-CDY)which is comprised of only sp...Carbyne delivers various excellent properties for the existence of the larger number of sp-hybridized carbon atoms.Here,a 3D well-defined porous carbon material germanium-carbdiyne(Ge-CDY)which is comprised of only sp-hybridized carbon atoms bridging by Ge atoms has been developed and investigated.The unique diamond-like structure constructed by linear butadiyne bonds and sp 3-hybridized Ge atoms ensures the stability of Ge-CDY.The large percentage of conjugated alkyne bonds composed of sp-C guarantees the good conductivity and the low band gap,which were further confirmed experimentally and theoretically,endowing Ge-CDY with the potential in electrochemical applications.The well-defined 3D carbon skeleton of Ge-CDY provides abundant uniform nanopores,which is suitable for metal ions storage and diffusion.Further half-cell evaluation also demonstrated Ge-CDY exhibited an excellent performance in lithium storage.All those indicating sp-hybridized carbon-based materials can exhibit great potential to possess excellent properties and be applied in the field of energy,electronic,and so on.展开更多
Topochemical reactions are a promising method to obtain crystalline polymeric materials with distance-determined regio-or stereoselectivity.It has been concluded on an empirical basis that the closest intermolecular C...Topochemical reactions are a promising method to obtain crystalline polymeric materials with distance-determined regio-or stereoselectivity.It has been concluded on an empirical basis that the closest intermolecular C⋅⋅⋅C distance in crystals of alkynes,d(C⋅⋅⋅C)min,should reach a threshold of∼3Åfor bonding to occur at room temperature.To understand this empirical threshold,we study here the polymerization of acetylene in the crystalline state under high pressure by calculating the structural geometry,vibrational modes,and reaction profile.We find d(C⋅⋅⋅C)min to be the sum of an intrinsic threshold of 2.3Åand a thermal displacement of 0.8Å(at room temperature).Molecules at the empirical threshold move via several phonon modes to reach the intrinsic threshold,at which the intermolecular electronic interaction is sharply enhanced and bonding commences.A distance–vibration-based reaction picture is thus demonstrated,which provides a basis for the prediction and design of topochemical reactions,as well as an enhanced understanding of the bonding process in solids.展开更多
In karst areas,the drainage pipes of aging tunnels are prone to be clogged by precipitated carbonates,resulting in lining cracking and tunnel leaking.As a result,not only the driving safety will be deteriorated,but al...In karst areas,the drainage pipes of aging tunnels are prone to be clogged by precipitated carbonates,resulting in lining cracking and tunnel leaking.As a result,not only the driving safety will be deteriorated,but also the water pressure on the lining might also be elevated significantly.For the structural stability and service lifespan of old tunnels,it is of great importance to remove these precipitated carbonates in time.Traditional treatment methods are often destructive to some extent or not efficient enough.This study aims to experimentally develop an eco-friendly acid-based chemical cleaning method to remove carbonate precipitations efficiently.The proposed chemical cleaning agent is an aqueous solution with strong acidity,consisting of sulfamic acid,water,and additives.The factors affecting the cleaning efficiency include the acid solubility,temperature and flow rate of the cleaning agent,as well as additives.Elevating the solution temperature to 50C or a flow rate of no less than 0.2 m/s can improve cleaning efficiency.Although the salt effect cannot work,1 wt%of polymaleic acid as a surfactant could further promote the cleaning rate.The cleaning efficiency will increase with the flow rate in a power function.The relatively low flow rate that improves the cleaning rate considerably can avoid highpressure-induced mechanical damage to tunnel drainpipes.The waste could be easily treated to acceptable levels using commercial sewage treatment products and can also be recycled in agriculture.With the chemical cleaning,the water pressure at the arch springing of the lining will reduce with the increased radius of transverse drainpipes in a power function.The proposed acid-based cleaning method,which is highly efficient,non-or low-destructive to aging tunnels,sufficiently safe for humans,and friendly enough to the environment,will offer a promising alternative to remove the precipitated carbonates in tunnel drainpipes efficiently.展开更多
Bronchogenic cyst occurring in the diaphragm is rare and thoracoscopic cyst resection is mainly effective treatment. The coronary artery bleeding after video-assisted thoracoscopic surgery(VATS) has never been describ...Bronchogenic cyst occurring in the diaphragm is rare and thoracoscopic cyst resection is mainly effective treatment. The coronary artery bleeding after video-assisted thoracoscopic surgery(VATS) has never been described; here we report a case of left coronary artery injury after thoracoscopic itradiaphragmatic bronchogenic cyst resection, which may be caused by metallic troca or chest tube.展开更多
We present a case of two-year old boy with solitary atypical adenomatous hyperplasia(AAH)in extralobar sequestration(ELS),which was misdiagnosed as diaphragmatic hernia before surgery.Review of AAH and pulmonary seque...We present a case of two-year old boy with solitary atypical adenomatous hyperplasia(AAH)in extralobar sequestration(ELS),which was misdiagnosed as diaphragmatic hernia before surgery.Review of AAH and pulmonary sequestration(PS)revealed that the present case is the youngest of solitary AAH and also the first report of solitary AAH arising in ELS without a primary lung cancer.In a sense,the present case firstly supports the hypothesis that ELS may be an underlying cancer predisposition syndrome,so aggressive surgical therapy should be recommended for ELS.展开更多
Understanding interspecies interactions is essential to predict the response of microbial communities to exogenous perturbation.Herein,rhizospheric and bulk soils were collected from five developmental stages of soybe...Understanding interspecies interactions is essential to predict the response of microbial communities to exogenous perturbation.Herein,rhizospheric and bulk soils were collected from five developmental stages of soybean,which grew in soils receiving 16-year nitrogen inputs.Bacterial communities and functional profiles were examined using high-throughput sequencing and quantitative PCR,respectively.The objective of this study was to identify the key bacterial interactions that influenced community dynamics and functions.We found that the stages of soybean development outcompeted nitrogen fertilization management in shaping bacterial community structure,while fertilization treatments significantly shaped the abundance distribution of nitrogen functional genes.Temporal variations in bacterial abundances increased in bulk soils,especially at the stage of soybean branching,which helps to infer underlying negative interspecies interactions.Members of Cyanobacteria and Actinobacteria actively engaged in inter-phylum negative interactions in bulk soils and soybean rhizosphere,respectively.Furthermore,the negative interactions between nitrogen-fixing functional groups and the reduction of nifH gene abundance were coupled during soybean development,which may help to explain the linkages between population dynamics and functions.Overall,these findings highlight the importance of inter-phylum negative interactions in shaping the correlation patterns of bacterial communities and in determining soil functional potential.展开更多
基金This study was supported by the National Natural Science Foundation of China (21701182,51822208,21771187,21790050,and 21790051)the Frontier Science Research Project (QYZDB-SSW-JSC052)+1 种基金the Chinese Academy of Sciences,the Taishan Scholars Program of Shandong Province (tsqn201812111)Institute Research Project (QIBEBT ZZBS 201809).
文摘Carbyne delivers various excellent properties for the existence of the larger number of sp-hybridized carbon atoms.Here,a 3D well-defined porous carbon material germanium-carbdiyne(Ge-CDY)which is comprised of only sp-hybridized carbon atoms bridging by Ge atoms has been developed and investigated.The unique diamond-like structure constructed by linear butadiyne bonds and sp 3-hybridized Ge atoms ensures the stability of Ge-CDY.The large percentage of conjugated alkyne bonds composed of sp-C guarantees the good conductivity and the low band gap,which were further confirmed experimentally and theoretically,endowing Ge-CDY with the potential in electrochemical applications.The well-defined 3D carbon skeleton of Ge-CDY provides abundant uniform nanopores,which is suitable for metal ions storage and diffusion.Further half-cell evaluation also demonstrated Ge-CDY exhibited an excellent performance in lithium storage.All those indicating sp-hybridized carbon-based materials can exhibit great potential to possess excellent properties and be applied in the field of energy,electronic,and so on.
基金support of the National Natural Science Foundation of China(NSFC)(Grant Nos.22022101,21875006,11704024,and 12174200)The authors also acknowledge support from the National Key Research and Development Program of China(Grant No.2019YFA0708502)from the Nature Science Foundation of Tianjin(Grant No.20JCYBJC01530).
文摘Topochemical reactions are a promising method to obtain crystalline polymeric materials with distance-determined regio-or stereoselectivity.It has been concluded on an empirical basis that the closest intermolecular C⋅⋅⋅C distance in crystals of alkynes,d(C⋅⋅⋅C)min,should reach a threshold of∼3Åfor bonding to occur at room temperature.To understand this empirical threshold,we study here the polymerization of acetylene in the crystalline state under high pressure by calculating the structural geometry,vibrational modes,and reaction profile.We find d(C⋅⋅⋅C)min to be the sum of an intrinsic threshold of 2.3Åand a thermal displacement of 0.8Å(at room temperature).Molecules at the empirical threshold move via several phonon modes to reach the intrinsic threshold,at which the intermolecular electronic interaction is sharply enhanced and bonding commences.A distance–vibration-based reaction picture is thus demonstrated,which provides a basis for the prediction and design of topochemical reactions,as well as an enhanced understanding of the bonding process in solids.
基金The financial support from the Fundamental Research Funds for the Central Universities,China(Grant No.YJ2021148)is gratefully acknowledged.The authors are also grateful to Prof.Ming Lü,a member of the Norwegian Academy of Technological Sciences from Norway,for his valuable suggestions.
文摘In karst areas,the drainage pipes of aging tunnels are prone to be clogged by precipitated carbonates,resulting in lining cracking and tunnel leaking.As a result,not only the driving safety will be deteriorated,but also the water pressure on the lining might also be elevated significantly.For the structural stability and service lifespan of old tunnels,it is of great importance to remove these precipitated carbonates in time.Traditional treatment methods are often destructive to some extent or not efficient enough.This study aims to experimentally develop an eco-friendly acid-based chemical cleaning method to remove carbonate precipitations efficiently.The proposed chemical cleaning agent is an aqueous solution with strong acidity,consisting of sulfamic acid,water,and additives.The factors affecting the cleaning efficiency include the acid solubility,temperature and flow rate of the cleaning agent,as well as additives.Elevating the solution temperature to 50C or a flow rate of no less than 0.2 m/s can improve cleaning efficiency.Although the salt effect cannot work,1 wt%of polymaleic acid as a surfactant could further promote the cleaning rate.The cleaning efficiency will increase with the flow rate in a power function.The relatively low flow rate that improves the cleaning rate considerably can avoid highpressure-induced mechanical damage to tunnel drainpipes.The waste could be easily treated to acceptable levels using commercial sewage treatment products and can also be recycled in agriculture.With the chemical cleaning,the water pressure at the arch springing of the lining will reduce with the increased radius of transverse drainpipes in a power function.The proposed acid-based cleaning method,which is highly efficient,non-or low-destructive to aging tunnels,sufficiently safe for humans,and friendly enough to the environment,will offer a promising alternative to remove the precipitated carbonates in tunnel drainpipes efficiently.
文摘Bronchogenic cyst occurring in the diaphragm is rare and thoracoscopic cyst resection is mainly effective treatment. The coronary artery bleeding after video-assisted thoracoscopic surgery(VATS) has never been described; here we report a case of left coronary artery injury after thoracoscopic itradiaphragmatic bronchogenic cyst resection, which may be caused by metallic troca or chest tube.
基金supported by the National Natural Science Foundation of China(7157114471401134+1 种基金71171164)the International Cooperation and Exchanges in Science and Technology Program of Shaanxi Province(2016KW-033)
基金supported by the grant from National Natural Science Foundation of China(to Yuanda CHENG)(No.81401901)
文摘We present a case of two-year old boy with solitary atypical adenomatous hyperplasia(AAH)in extralobar sequestration(ELS),which was misdiagnosed as diaphragmatic hernia before surgery.Review of AAH and pulmonary sequestration(PS)revealed that the present case is the youngest of solitary AAH and also the first report of solitary AAH arising in ELS without a primary lung cancer.In a sense,the present case firstly supports the hypothesis that ELS may be an underlying cancer predisposition syndrome,so aggressive surgical therapy should be recommended for ELS.
基金supported by the National Natural Science Foundation of China[41830755,41701291,and 42077049].
文摘Understanding interspecies interactions is essential to predict the response of microbial communities to exogenous perturbation.Herein,rhizospheric and bulk soils were collected from five developmental stages of soybean,which grew in soils receiving 16-year nitrogen inputs.Bacterial communities and functional profiles were examined using high-throughput sequencing and quantitative PCR,respectively.The objective of this study was to identify the key bacterial interactions that influenced community dynamics and functions.We found that the stages of soybean development outcompeted nitrogen fertilization management in shaping bacterial community structure,while fertilization treatments significantly shaped the abundance distribution of nitrogen functional genes.Temporal variations in bacterial abundances increased in bulk soils,especially at the stage of soybean branching,which helps to infer underlying negative interspecies interactions.Members of Cyanobacteria and Actinobacteria actively engaged in inter-phylum negative interactions in bulk soils and soybean rhizosphere,respectively.Furthermore,the negative interactions between nitrogen-fixing functional groups and the reduction of nifH gene abundance were coupled during soybean development,which may help to explain the linkages between population dynamics and functions.Overall,these findings highlight the importance of inter-phylum negative interactions in shaping the correlation patterns of bacterial communities and in determining soil functional potential.
