Influences of oscillation on the physical stability and explosion characteristics of solid-liquid mixed fuel

The stratification phenomenon resulting from differences in the physical properties of solid-liquid components seriously affect the final combustion and explosion characteristics of mixed fuel under the action of oscillation.The effects of oscillation on the physical stability of mixed fuel with two solid-liquid ratios and three liquid component distribution ratios have been investigated using a self-designed experimental system at oscillation frequencies of 60-300 r/min.The explosion characteristics of mixed fuel before and after oscillation are gained from a 20 L spherical explosion container system.When the mass ratio of liquid components is controlled at 66.9%,64.7%,62.6%the final explosion characteristics are stable,with a maximum difference of only 0.71%.The volume of liquid fuel precipitation increases with increasing oscillation frequency when the mass ratio of liquid components reaches 71.7%,69.6%,67.7%.The fuel explosion overpressure after oscillation decreases with increasing liquid precipitation volume,and the repeatability is poor,with a maximum standard deviation of 82.736,which is much higher than the ratio without stratification.Properly controlling the mass ratio of liquid components of the mixed fuel can effectively combat the impact of oscillation on the physical state and maintain the stability of the final explosion characteristics.

NMR和TOF-SIMS研究烷基双膦酸与CaCO3表面Ca2+的键合模式

双膦酸与含钙矿物表/界面作用的键合模式仍需深入探索.本文分别选择CaCO3与具有线性长链的十五烷基双膦酸作为双膦酸与钙离子反应的模型,使烷基双膦酸在CaCO3表面自组装形成单分子层,通过13C CP/MAS NMR、31P MAS NMR和TOF-SIMS等手段表征了双膦酸与Ca CO3表面Ca^2+作用的键合模式.结果表明,一个双膦酸头基[–CH(PO3H2)2]能与三个钙离子以双三齿键合模式螯合形成6个P–O–Ca键,导致碳酸钙表面被全部活化,这为理解双膦酸与含钙矿物的作用机理提供了科学依据,并为碳酸钙的表面改性提供了一条潜在途径.

高压水射流对白云鄂博矿单体解离度的影响

矿物的单体解离是其能被高效选别的关键因素之一,粉碎方法对矿物单体解离度有很大的影响。白云鄂博稀土矿含十几种稀土矿物,矿物共生密切,嵌布类型复杂,其中稀土主要富集在氟碳铈矿与独居石矿中。分析表明矿物因相互包裹穿插和交代而形成毗连、网脉、溶蚀和环状嵌布。为提高矿物的单体解离度,通过自主研发水射流矿物解离装置,探究了水射流速度对白云鄂博矿稀土单体解离度的影响。在同等粒度分布下,对高压水射流粉碎与常规球磨(铁介质)实验结果进行了对比,分析了两种粉碎方式对稀土矿物解离状态及颗粒界面的影响。激光共聚焦显微镜、矿物特征自动定量分析系统(AMICS)分析表明,高压水射流粉碎白云鄂博稀土矿物单体解离度优于球磨,具有解离度高、粒度相对均匀等特点;矿物颗粒天然界面保持较好、表面较光洁,稀土矿物集中在0.038 mm以下颗粒中,有益于稀土的浮选分离,对白云鄂博矿的矿石粉碎具有一定的指导意义。