In order to characterize the organic properties of waste activated sludge in a wastewater treatment plant,organic matter within sludge was extracted with NH 3 ·H 2 O preferentially,and subsequently fractionated i...In order to characterize the organic properties of waste activated sludge in a wastewater treatment plant,organic matter within sludge was extracted with NH 3 ·H 2 O preferentially,and subsequently fractionated into five fractions using XAD-8/XAD-4 resins.Up to a 63.8%-71.1% of organic matter within the sludge could be efficiently extracted by NH 3 ·H 2 O.Fractionation results showed that hydrophobic acid and hydrophilic fraction were two main components among the sludge organic matter （accounting for 32.2% and 48.0% of the bulk organic matter,respectively）,whereas transphilic acid,hydrophobic neutral and transphilic neutral were quite low （accounting for 9.2%,5.8% and 4.8%,respectively）.Despite that the extractant of NH 3 ·H 2 O showed a relatively higher extraction efficiency of the aromatic components,the relatively low aromaticity of the organic fractions implied that those non-aromatic components could also be effectively extracted,especially for neutral and hydrophilic fractions.In addition,acidic fractions contained more aromatic humic-like components,whereas the neutral fractions had a greater content of aromatic proteins and soluble microbial byproduct-like components.Extraction of sludge organics with NH3·H2O and subsequential fractionation using XAD resins could be a novel method for further characterization of sludge organics.展开更多
Fly ash was used as a low-cost adsorbent for removing dissolved organic matter （DOM） in secondary effluent. Batch experiments were conducted under various adsorbent dosages, pH, contact time, temperatures and DOM fr...Fly ash was used as a low-cost adsorbent for removing dissolved organic matter （DOM） in secondary effluent. Batch experiments were conducted under various adsorbent dosages, pH, contact time, temperatures and DOM fractional characteristics. Under the optimum conditions of fly ash dosage of 15 g/L, temperature of 303 K and contact time of 180 min, a removal of 22.5% of the dissolved organic carbon （DOC）, 23.7% of UV-254, 25.9% of the trihalomethanes precursors in secondary effluent was obtained. The adsorption of DOM fractions onto fly ash all followed the pseudo second-order kinetic model, and the hydrophilic fraction adsorption by fly ash also fitted the intraparticle diffusion model quite well. Freundlich and Langmuir models were applicable to the fly ash adsorption and their constants were evaluated. The maximum adsorption capacities of the adsorptions revealed that fly ash was more effective in adsorbing hydrophilic fraction than the acidic fractions. Structure changes of the DOM fractions after fly ash adsorption were also characterized via spectrum analyzing. Those mechanisms presented critical step toward improved efficiencies of fly ash adsorption via further surface-modification.展开更多
In this paper,we present a new stabilized finite element method for transient Navier-Stokes equations with high Reynolds number based on the projection of the velocity and pressure.We use Taylor-Hood elements and the ...In this paper,we present a new stabilized finite element method for transient Navier-Stokes equations with high Reynolds number based on the projection of the velocity and pressure.We use Taylor-Hood elements and the equal order elements in space and second order difference in time to get the fully discrete scheme.The scheme is proven to possess the absolute stability and the optimal error estimates.Numerical experiments show that our method is effective for transient Navier-Stokes equations with high Reynolds number and the results are in good agreement with the value of subgrid-scale eddy viscosity methods,Pet ro-Galerkin finite element method and st reamline diffusion method.展开更多
基金supported by the National Nature Science Foundation of China (National Creative Research Groups) (No. 50821002)the State Key Laboratory of Urban Water Resource and Environment,Harbin Instituteof Technology (No. 2008DX05)+2 种基金the Key Projects in the National Science and Technology Pillar Program during the Eleventh Five-year Plan Period (No. 2006BAC19B04)the Heilongjiang Province Science Foundation for Youths(No. QC2009C113/E0804)the Shanghai Tongji GaoTingyao Environmental Science & Technology Development Foundation
文摘In order to characterize the organic properties of waste activated sludge in a wastewater treatment plant,organic matter within sludge was extracted with NH 3 ·H 2 O preferentially,and subsequently fractionated into five fractions using XAD-8/XAD-4 resins.Up to a 63.8%-71.1% of organic matter within the sludge could be efficiently extracted by NH 3 ·H 2 O.Fractionation results showed that hydrophobic acid and hydrophilic fraction were two main components among the sludge organic matter （accounting for 32.2% and 48.0% of the bulk organic matter,respectively）,whereas transphilic acid,hydrophobic neutral and transphilic neutral were quite low （accounting for 9.2%,5.8% and 4.8%,respectively）.Despite that the extractant of NH 3 ·H 2 O showed a relatively higher extraction efficiency of the aromatic components,the relatively low aromaticity of the organic fractions implied that those non-aromatic components could also be effectively extracted,especially for neutral and hydrophilic fractions.In addition,acidic fractions contained more aromatic humic-like components,whereas the neutral fractions had a greater content of aromatic proteins and soluble microbial byproduct-like components.Extraction of sludge organics with NH3·H2O and subsequential fractionation using XAD resins could be a novel method for further characterization of sludge organics.
基金supported by the National Nature Science Foundation of China (National Creative Research Groups)(No. 50821002)the Key Scientific and Technological Project of National Water Pollution Control and Management (No. 2009ZX07317-008)the Scientific and Technological Innovation Research Fund of Harbin (No.2010RFQXN111)
文摘Fly ash was used as a low-cost adsorbent for removing dissolved organic matter （DOM） in secondary effluent. Batch experiments were conducted under various adsorbent dosages, pH, contact time, temperatures and DOM fractional characteristics. Under the optimum conditions of fly ash dosage of 15 g/L, temperature of 303 K and contact time of 180 min, a removal of 22.5% of the dissolved organic carbon （DOC）, 23.7% of UV-254, 25.9% of the trihalomethanes precursors in secondary effluent was obtained. The adsorption of DOM fractions onto fly ash all followed the pseudo second-order kinetic model, and the hydrophilic fraction adsorption by fly ash also fitted the intraparticle diffusion model quite well. Freundlich and Langmuir models were applicable to the fly ash adsorption and their constants were evaluated. The maximum adsorption capacities of the adsorptions revealed that fly ash was more effective in adsorbing hydrophilic fraction than the acidic fractions. Structure changes of the DOM fractions after fly ash adsorption were also characterized via spectrum analyzing. Those mechanisms presented critical step toward improved efficiencies of fly ash adsorption via further surface-modification.
基金We thank Dr.Chen Gang for the great help to the numerical part of this paper.This research was supported by the Natural Science Foundation of China(No.11271273)Major Project of Education Department in Sichan(No.18ZA0276).
文摘In this paper,we present a new stabilized finite element method for transient Navier-Stokes equations with high Reynolds number based on the projection of the velocity and pressure.We use Taylor-Hood elements and the equal order elements in space and second order difference in time to get the fully discrete scheme.The scheme is proven to possess the absolute stability and the optimal error estimates.Numerical experiments show that our method is effective for transient Navier-Stokes equations with high Reynolds number and the results are in good agreement with the value of subgrid-scale eddy viscosity methods,Pet ro-Galerkin finite element method and st reamline diffusion method.
