期刊文献+
共找到2篇文章
< 1 >
每页显示 20 50 100
一种交联点可“滑动”的滑动轮凝胶的制备进展及思考
1
作者 王文哲 周英芳 +7 位作者 田尧 张春权 刘灿 张鹏 于海洋 纪文娟 陈世兰 冯建 《高分子材料科学与工程》 EI CAS CSCD 北大核心 2019年第2期175-182,共8页
滑动轮凝胶具有"8"字型双环结构的交联点,这种交联点可以沿聚合物链发生滑移,受外力作用时,应力不仅集中在某一条链段,而可以通过滑轮效应分散到由双环结构交联的邻近链段。独特的结构赋予其普通化学或物理凝胶所不具备的性... 滑动轮凝胶具有"8"字型双环结构的交联点,这种交联点可以沿聚合物链发生滑移,受外力作用时,应力不仅集中在某一条链段,而可以通过滑轮效应分散到由双环结构交联的邻近链段。独特的结构赋予其普通化学或物理凝胶所不具备的性质。文中综述了这类凝胶的制备方法,通常首先制备出聚轮烷,再将聚轮烷上的环状分子桥连得到。后来又有先制备出聚轮烷,再将聚轮烷上的环糊精双键化改性作为一种通用型交联剂,将滑动效应引入更多的凝胶材料。还有先将环糊精引入双键,再将其制备成聚轮烷,目前已有成功实例。文中还介绍了其他多种将环糊精引入双键的改性实例,为制备具有滑动效应的聚轮烷交联剂提供一些思路。指出基于成本更低的β-环糊精制备的滑动轮凝胶也许更具备商业应用价值。 展开更多
关键词 滑动轮凝胶 环糊精 聚轮烷 滑动效应
下载PDF
Engineered tunneling layer with enhaneed impact ionization for detection improvement in graphene/silicon heterojunction photodetectors 被引量:6
2
作者 Jun Yin Lian Liu +8 位作者 Yashu Zang Anni Ying Wenjie Hui Shusen Jiang chunquan zhang Tzuyi Yang Yu-Lun Chueh Jing Li Junyong Kang 《Light(Science & Applications)》 SCIE EI CAS CSCD 2021年第6期1133-1142,共10页
Here,an engineered tunneling layer enhanced photocurrent multiplication through the impact ionization effect was proposed and experimentally demonstrated on the graphene/silic on heterojunction photodetectors.With con... Here,an engineered tunneling layer enhanced photocurrent multiplication through the impact ionization effect was proposed and experimentally demonstrated on the graphene/silic on heterojunction photodetectors.With con sidering the suitable band structure of the insulation material and their special defect states,an atomic layer deposition(ALD)prepared wide-bandgap insulating(WBI)layer of AIN was introduced into the interface of graphene/silicon heterojunction.The promoted tunneling process from this designed structure dem on strated that can effectively help the impact ionization with photogain not only for the regular minority carriers from silicon,but also for the novel hot carries from graphene.As a result,significantly enhanced photocurrent as well as simultaneously decreased dark current about one order were accomplished in this graphene/insulation/silicon(GIS)heterojunction devices with the optimized AIN thickness of〜15 nm compared to the conventional graphene/silicon(GS)devices.Specifically,at the reverse bias of-10 V,a 3.96-A W_1 responsivity with the photogain of~5.8 for the peak response under 850-nm light illumination,and a 1.03-A W_1 responsivity with~3.5 photogain under the 365 nm ultraviolet(UV)illumination were realized,which are even remarkably higher than those in GIS devices with either AI2O3 or the commonly employed SiO2 insulation layers.This work dem on strates a universal strategy to fabricate broad ba nd,low-cost and high-performance photo-detecting devices towards the graphene-silicon optoelectronic integration. 展开更多
关键词 HETEROJUNCTION ENGINE TUNNELING
原文传递
上一页 1 下一页 到第
使用帮助 返回顶部