Poly(3,4-ethylenedioxythiophene)(PEDOT)has proved its quite competitive thermoelectric properties in flexible electronics with its excellent electrical and mechanical properties.Since the early discovery of PEDOT,cons...Poly(3,4-ethylenedioxythiophene)(PEDOT)has proved its quite competitive thermoelectric properties in flexible electronics with its excellent electrical and mechanical properties.Since the early discovery of PEDOT,considerable experimental progress has been achieved in optimizing and improving the thermoelectric properties as a promising organic thermoelectric material(OTE).Among them,theoretical research has made significant contributions to its development.Here the basic physics of conductive PEDOT are reviewed based on the combination of theory and experiment.The purpose is to provide a new insight into the development of PEDOT,so as to effectively design and preparation of advanced thermoelectric PEDOT material in the future.展开更多
Summary:The corona virus disease 2019(COVID-19)is an emerging respiratory infectious disease caused by SARS-CoV-2,which first occurred in December 2019 in Wuhan,China.These days,in China,chest CT is used for diagnosis...Summary:The corona virus disease 2019(COVID-19)is an emerging respiratory infectious disease caused by SARS-CoV-2,which first occurred in December 2019 in Wuhan,China.These days,in China,chest CT is used for diagnosis of COVID-19,as an important complement to the reverse-transcription polymerase chain reaction(RT-PCR)test.Because of contacting with a large number of suspected or probable cases closely during chest CT examination,radiographers are easily infected with COVID-19.This article included the rearrangement of CT examination room in fever clinic,the rearrangement of human resources in radiology department,and the drafting of new operating procedures for radiologists who carry out CT examination on COVID-19 patients.This article also introduced the emergency management procedures of the department of radiology during the outbreak,and the experience of infection prevention for the staff of the department of radiology.展开更多
The reduced graphene oxide/silver selenide nanowire(rGO/Ag;Se NW)composite powders were fabricated via a wet chemical approach,and then flexible rGO/Ag;Se NW composite film was prepared by a facile vacuum filtration m...The reduced graphene oxide/silver selenide nanowire(rGO/Ag;Se NW)composite powders were fabricated via a wet chemical approach,and then flexible rGO/Ag;Se NW composite film was prepared by a facile vacuum filtration method combined with cold-pressing treatment.A highest power factor of 228.88μW·m;·K;was obtained at 331 K for the cold-pressed rGO/Ag;Se NW composite film with 0.01 wt%r GO.The rGO/Ag;Se NW composite film revealed superior flexibility as the power factor retained 94.62%after bending for 500 times with a bending radius of 4 mm,which might be due to the interwoven network structures of Ag;Se NWs and pliability of r GO as well as nylon membrane.These results demonstrated that the GO/Ag;Se NW composite film has a potential for preparation of flexible thermoelectric devices.展开更多
Self-healing poly(urea-urethane)s (PUUs) showing a tolerance to mechanical damage are particularly desirable for high-performance elastomeric biomaterials. In this study a kind of biodegradable PUUs was synthesize...Self-healing poly(urea-urethane)s (PUUs) showing a tolerance to mechanical damage are particularly desirable for high-performance elastomeric biomaterials. In this study a kind of biodegradable PUUs was synthesized from poly(e-caprolactone) diol with L-lysine ethyl ester diisocyanate (LDI) extended with L-lysine ethyl ester dihydrochloride (LEED) in DMF and characterized by using 1H-NMR, FTIR, DSC, XRD, SEM and tensile tests. Interestingly, they exhibited a self-healing characteristic upon exposure to 37℃ for as short as 30 min with the tensile strength keeping at 4.23 MPa and the elongation at break reaching to 627%. It is revealed that increasing the hard segment content in PUUs benefits the self-healing performance, and on the opposite increasing the soft segment content contributes to the biodegradability.展开更多
基金supported by the National Natural Science Foundation of China(Grant Nos.51762018,52073128,and 22065013)the Natural Science Foundation of Jiangxi Province,China(Grant Nos.20202ACBL204005,20202ACBL214005,and 20203AEI003)。
文摘Poly(3,4-ethylenedioxythiophene)(PEDOT)has proved its quite competitive thermoelectric properties in flexible electronics with its excellent electrical and mechanical properties.Since the early discovery of PEDOT,considerable experimental progress has been achieved in optimizing and improving the thermoelectric properties as a promising organic thermoelectric material(OTE).Among them,theoretical research has made significant contributions to its development.Here the basic physics of conductive PEDOT are reviewed based on the combination of theory and experiment.The purpose is to provide a new insight into the development of PEDOT,so as to effectively design and preparation of advanced thermoelectric PEDOT material in the future.
文摘Summary:The corona virus disease 2019(COVID-19)is an emerging respiratory infectious disease caused by SARS-CoV-2,which first occurred in December 2019 in Wuhan,China.These days,in China,chest CT is used for diagnosis of COVID-19,as an important complement to the reverse-transcription polymerase chain reaction(RT-PCR)test.Because of contacting with a large number of suspected or probable cases closely during chest CT examination,radiographers are easily infected with COVID-19.This article included the rearrangement of CT examination room in fever clinic,the rearrangement of human resources in radiology department,and the drafting of new operating procedures for radiologists who carry out CT examination on COVID-19 patients.This article also introduced the emergency management procedures of the department of radiology during the outbreak,and the experience of infection prevention for the staff of the department of radiology.
基金supported by the Program for Professor of Special Appointment at Shanghai Institutions of Higher Learning(Grant No.TP2020068)Shanghai Innovation Action Plan Project(Grant No.17090503600)Shanghai Sailing Program(Grant No.20YF1447300)。
文摘The reduced graphene oxide/silver selenide nanowire(rGO/Ag;Se NW)composite powders were fabricated via a wet chemical approach,and then flexible rGO/Ag;Se NW composite film was prepared by a facile vacuum filtration method combined with cold-pressing treatment.A highest power factor of 228.88μW·m;·K;was obtained at 331 K for the cold-pressed rGO/Ag;Se NW composite film with 0.01 wt%r GO.The rGO/Ag;Se NW composite film revealed superior flexibility as the power factor retained 94.62%after bending for 500 times with a bending radius of 4 mm,which might be due to the interwoven network structures of Ag;Se NWs and pliability of r GO as well as nylon membrane.These results demonstrated that the GO/Ag;Se NW composite film has a potential for preparation of flexible thermoelectric devices.
基金financially supported by the "863" Project of Minister of Science and Technology of China(No. 2007AA021905)
文摘Self-healing poly(urea-urethane)s (PUUs) showing a tolerance to mechanical damage are particularly desirable for high-performance elastomeric biomaterials. In this study a kind of biodegradable PUUs was synthesized from poly(e-caprolactone) diol with L-lysine ethyl ester diisocyanate (LDI) extended with L-lysine ethyl ester dihydrochloride (LEED) in DMF and characterized by using 1H-NMR, FTIR, DSC, XRD, SEM and tensile tests. Interestingly, they exhibited a self-healing characteristic upon exposure to 37℃ for as short as 30 min with the tensile strength keeping at 4.23 MPa and the elongation at break reaching to 627%. It is revealed that increasing the hard segment content in PUUs benefits the self-healing performance, and on the opposite increasing the soft segment content contributes to the biodegradability.