In this paper, a fourth-order viscoelastic plate vibration equation is transformed into a set of two second-order differential equations by introducing an intermediate variable. A three-layer compact difference scheme...In this paper, a fourth-order viscoelastic plate vibration equation is transformed into a set of two second-order differential equations by introducing an intermediate variable. A three-layer compact difference scheme for the initial-boundary value problem of the viscoelastic plate vibration equation is established. Then the stability and convergence of the difference scheme are analyzed by the energy method, and the convergence order is <img src="Edit_0a250b60-7c3c-4caf-8013-5e302d6477ab.png" alt="" />. Finally, some numerical examples are given of which results verify the accuracy and validity of the scheme.展开更多
The understanding of reaction mechanisms of electrode materials is of significant importance for the development of advanced batteries.The LiMn2O4 cathode has a voltage plateau around 2.8 V(vs.Li^+/Li),which can provi...The understanding of reaction mechanisms of electrode materials is of significant importance for the development of advanced batteries.The LiMn2O4 cathode has a voltage plateau around 2.8 V(vs.Li^+/Li),which can provide an additional capacity for Li storage,but it suffers from a severe capacity degradation.In this study,operando X-ray diffraction is carried out to investigate the structural evolutions and degradation mechanisms of LiMn2O4 in different voltage ranges.In the range of 3.0-4.3 V(vs.Li^+/Li),the LiMn2O4 cathode exhibits a low capacity but good cycling stability with cycles up to 100 cycles and the charge/discharge processes are associated with the reversible extraction/insertion of Li^+from/into LixMn2O4(0≤x≤1).In the range of 1.4-4.4 V(vs.Li^+/Li),a capacity higher than 200 mAh/g is achieved,but it rapidly decays during the cycling.The voltage plateau around 2.8 V(vs.Li^+/Li)is related to the transformation of the cubic LiMn2O4 phase to the tetragonal Li2Mn2O4 phase,which leads to the formation of cracks as well as the performance degradation.展开更多
文摘In this paper, a fourth-order viscoelastic plate vibration equation is transformed into a set of two second-order differential equations by introducing an intermediate variable. A three-layer compact difference scheme for the initial-boundary value problem of the viscoelastic plate vibration equation is established. Then the stability and convergence of the difference scheme are analyzed by the energy method, and the convergence order is <img src="Edit_0a250b60-7c3c-4caf-8013-5e302d6477ab.png" alt="" />. Finally, some numerical examples are given of which results verify the accuracy and validity of the scheme.
基金the financial support by the National Natural Science Foundation of China (51871133, 51671115)support by the Department of Science and Technology of the Shandong Province for the Young Tip-Top Talent Support Project.
文摘The understanding of reaction mechanisms of electrode materials is of significant importance for the development of advanced batteries.The LiMn2O4 cathode has a voltage plateau around 2.8 V(vs.Li^+/Li),which can provide an additional capacity for Li storage,but it suffers from a severe capacity degradation.In this study,operando X-ray diffraction is carried out to investigate the structural evolutions and degradation mechanisms of LiMn2O4 in different voltage ranges.In the range of 3.0-4.3 V(vs.Li^+/Li),the LiMn2O4 cathode exhibits a low capacity but good cycling stability with cycles up to 100 cycles and the charge/discharge processes are associated with the reversible extraction/insertion of Li^+from/into LixMn2O4(0≤x≤1).In the range of 1.4-4.4 V(vs.Li^+/Li),a capacity higher than 200 mAh/g is achieved,but it rapidly decays during the cycling.The voltage plateau around 2.8 V(vs.Li^+/Li)is related to the transformation of the cubic LiMn2O4 phase to the tetragonal Li2Mn2O4 phase,which leads to the formation of cracks as well as the performance degradation.
