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Oxidation mechanism of high-volume fraction SiCp/Al composite under laser irradiation and subsequent machining
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作者 Hanliang liu Guolong Zhao +5 位作者 Zhiwen Nian Zhipeng Huang Kai Yang conghua liu Peng Wang Zhenkuan Diao 《Nanotechnology and Precision Engineering》 EI CAS CSCD 2023年第3期34-47,共14页
Conventional mechanical machining of a composite material comprising an aluminum matrix reinforced with a high volume fraction of SiC particles(hereinafter referred to as an SiCp/Al composite)faces problems such as ra... Conventional mechanical machining of a composite material comprising an aluminum matrix reinforced with a high volume fraction of SiC particles(hereinafter referred to as an SiCp/Al composite)faces problems such as rapid tool wear,high specific cutting force,and poor surface integrity.Instead,a promising method for solving these problems is laser-induced oxidation-assisted milling(LOAM):under laser irradiation,the local workpiece material reacts with oxygen,thus forming loose and porous oxides that are easily removed.In the present work,the oxidation mechanism of SiCp/Al irradiated by a nanosecond pulsed laser is studied to better understand the laser-induced oxidation behavior and control the characteristics of the oxides,with laser irradiation experiments performed on a 65%SiCp/Al composite with various laser parameters and auxiliary gases(oxygen,nitrogen,and argon).With increasing laser pulse energy density,both the ablated groove depth and the width of the heat-affected zone increase.When oxygen is used as the auxiliary gas,an oxide layer composed of SiO_(2)and Al2O3 forms,and CO_(2)is produced and escapes from the material,thereby forming pores in the oxides.However,when nitrogen or argon is used as the auxiliary gas,a recast layer is produced that is relatively difficult to remove.Under laser irradiation,the sputtered material reacts with oxygen to form oxides on both sides of the ablated groove,and as the laser scanning path advances,the produced oxides accumulate to form an oxide layer.LOAM and conventional milling are compared using the same milling parameters,and LOAM is found to be better for reduced milling force and tool wear and improved machined surface quality. 展开更多
关键词 SiCp/Al composite Oxidation mechanism Nanosecond pulsed laser Laser-induced oxidation Heat-affected zone
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3种中分子量蛋白对镍钛和不锈钢弓丝抗腐蚀能力的影响
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作者 崔野 黄梓濡 +2 位作者 王春林 刘从华 张超 《口腔疾病防治》 2019年第2期83-89,共7页
目的探索不同类型的蛋白对合金抗腐蚀能力的影响及其机制,以期为镍钛和不锈钢弓丝在临床上的安全应用及表面改性提供参考。方法采用动电位极化法测试纤维蛋白原、IgG或黏蛋白对镍钛和不锈钢弓丝抗电化学腐蚀能力的影响,并用循环极化法... 目的探索不同类型的蛋白对合金抗腐蚀能力的影响及其机制,以期为镍钛和不锈钢弓丝在临床上的安全应用及表面改性提供参考。方法采用动电位极化法测试纤维蛋白原、IgG或黏蛋白对镍钛和不锈钢弓丝抗电化学腐蚀能力的影响,并用循环极化法检测三种蛋白处理后表面钝化膜的修复能力。电感耦合等离子体发射光谱法(inductively coupled plasma optical emission spectrometer, ICP-OES)测定腐蚀产物的类型,并对腐蚀后表面形貌进行扫描电镜和原子显微镜分析。结果添加纤维蛋白原、IgG或黏蛋白对同一合金的抗腐蚀能力影响不同。添加蛋白能够降低不锈钢合金的抗腐蚀能力,可减缓镍钛合金的腐蚀进程。添加黏蛋白能够提高镍钛合金抗腐蚀性和表面钝化膜的修复能力。与黏蛋白及IgG相比,纤维蛋白原能够降低镍钛和不锈钢合金的抗点蚀能力。结论不同类型的蛋白能与弓丝发生作用,在表面形成不同的沉积形貌,并参与合金的腐蚀过程。 展开更多
关键词 腐蚀 镍钛合金 不锈钢合金 蛋白吸附 纤维蛋白原 黏蛋白 免疫球蛋白G
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