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准二维钙钛矿超快动力学的研究进展
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作者 江玉海 孙鹏云 +1 位作者 崔明焕 秦朝朝 《河南师范大学学报(自然科学版)》 CAS 北大核心 2023年第4期1-10,F0002,共11页
基于三维有机-无机杂化钙钛矿光电转换材料制备的光电器件的环境稳定性较差,严重阻碍了其大规模商业应用,准二维钙钛矿有望解决这一问题.准二维钙钛矿打破了三维钙钛矿结构上的对称性,突破了容忍因子的限制.此外,材料的激子结合能较大,... 基于三维有机-无机杂化钙钛矿光电转换材料制备的光电器件的环境稳定性较差,严重阻碍了其大规模商业应用,准二维钙钛矿有望解决这一问题.准二维钙钛矿打破了三维钙钛矿结构上的对称性,突破了容忍因子的限制.此外,材料的激子结合能较大,表现出较强的量子和介电限域效应,拥有特殊的载流子动力学和光物理特性.目前准二维钙钛矿光电转换器件的效率仍然与三维钙钛矿相差较大,因此必须对其内部的超快动力学和物理机制进行深入研究,为进一步优化器件性能提供指导.总结了准二维钙钛矿光电转换器件的研究进展,归纳了准二维钙钛矿的俄歇复合、能量转移和电荷转移等超快动力学特性,分析了准二维钙钛矿光电转换器件目前面临的问题并对其未来的研究趋势进行了展望. 展开更多
关键词 准二维钙钛矿 俄歇复合 能量转移 电荷转移 超快动力学
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加速器驱动次临界系统装置部件用材发展战略研究 被引量:6
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作者 王志光 姚存峰 +6 位作者 秦芝 孙建荣 庞立龙 申铁龙 朱亚滨 崔明焕 魏孔芳 《中国工程科学》 CSCD 北大核心 2019年第1期39-48,共10页
加速器驱动次临界系统(ADS)由强流高能离子加速器、高功率散裂靶和次临界反应堆三大分系统组成。作为未来先进核裂变能——加速器驱动先进核能系统(ADANES)的重要组成部分,ADS装置的研发对推动我国能源革命、促进能源转型以及刺激核能... 加速器驱动次临界系统(ADS)由强流高能离子加速器、高功率散裂靶和次临界反应堆三大分系统组成。作为未来先进核裂变能——加速器驱动先进核能系统(ADANES)的重要组成部分,ADS装置的研发对推动我国能源革命、促进能源转型以及刺激核能行业创新发展具有重大作用。本文以ADANES研发为背景,阐述了ADS装置的研发现状、可能的发展趋势以及ADS部件对材料的需求,重点探讨了ADS装置中高功率散裂靶和次临界反应堆部件用关键材料的研发进展与存在问题,面临的发展机遇和挑战;最后提出了几点发展对策,力求助力我国ADS装置的建设与先进核裂变能技术创新,推动未来先进核裂变能的安全高效和可持续发展。 展开更多
关键词 加速器驱动次临界系统(ADS) 加速器驱动先进核能系统(ADANES) 关键材料 次临界反应堆 高功率散裂靶
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SiC含量对ZTA和ATZ复相陶瓷力学及热学性能的影响 被引量:4
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作者 柴建龙 郭亚威 +5 位作者 朱亚滨 李淑芬 申铁龙 姚存峰 崔明焕 王志光 《陶瓷学报》 CAS 北大核心 2019年第2期228-233,共6页
以α-Al_2O_3、ZrO_2和β-SiC粉体为原料,通过放电等离子烧结(SPS)制备了氧化物/碳化物复相陶瓷材料,研究了SiC掺杂对氧化锆增韧氧化铝(ZTA)和氧化铝增强氧化锆(ATZ)基两种复相陶瓷微观结构以及力学、热学性能的影响。XRD衍射谱显示样... 以α-Al_2O_3、ZrO_2和β-SiC粉体为原料,通过放电等离子烧结(SPS)制备了氧化物/碳化物复相陶瓷材料,研究了SiC掺杂对氧化锆增韧氧化铝(ZTA)和氧化铝增强氧化锆(ATZ)基两种复相陶瓷微观结构以及力学、热学性能的影响。XRD衍射谱显示样品中成分为α-Al_2O_3、ZrO_2和β-SiC,无其他杂质相存在。随着SiC含量的增加,ZTA-SiC复相陶瓷的断裂韧性先增大至7.6 MPa·m^(1/2)后下降为6.6 MPa·m^(1/2),而ATZ-SiC复相陶瓷的断裂韧性未发生明显变化,恒定为约11 MPa·m^(1/2)。SEM图像显示韧性较大的复合陶瓷中的穿晶断裂作用机制明显。相同温度下,复相陶瓷的热导率随SiC添加量的增加而增加,当温度为1200℃时,ZTA-SiC和ATZ-SiC复相陶瓷的热导率随SiC含量的增加分别由4.31 W/m·K增加至5.50 W/m·K,5.39 W/m·K增加至8.10 W/m·K。 展开更多
关键词 SiC ZTA/ATZ复相陶瓷 断裂韧性 弯曲强度 热导率
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Al2O3/ZrO2/MgAl2O4复相陶瓷的SPS烧结及性能表征 被引量:3
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作者 郭亚威 柴建龙 +6 位作者 朱亚滨 魏孔芳 李淑芬 申铁龙 姚存峰 崔明焕 王志光 《陶瓷学报》 CAS 北大核心 2019年第3期289-294,共6页
本文以Al2O3、3Y-ZrO2和MgO为原料,采用机械球磨法对粉末进行混合处理,通过放电等离子体烧结技术(SPS:Spark Plasma Sintering)制备了Al2O3/ZrO2/MgAl2O4(AZM)复相陶瓷,研究了MgAl2O4添加量对AZM复相陶瓷微观结构,力学、热学及电学性能... 本文以Al2O3、3Y-ZrO2和MgO为原料,采用机械球磨法对粉末进行混合处理,通过放电等离子体烧结技术(SPS:Spark Plasma Sintering)制备了Al2O3/ZrO2/MgAl2O4(AZM)复相陶瓷,研究了MgAl2O4添加量对AZM复相陶瓷微观结构,力学、热学及电学性能的影响。X射线衍射分析表明复相陶瓷物相由α-Al2O3、t-ZrO2和MgAl2O4组成,无其余杂相。SEM断面形貌图显示复相陶瓷的断裂为沿晶断裂和穿晶断裂相结合的复合断裂模式。随MgAl2O4含量增加,复相陶瓷断裂韧性由12 MPa m1/2(MgAl 2O 4体积比: 0v.%)增加至17.48 MPa m 1/2(20v.%)后逐渐减小为14.46 MPa m 1/2(40v.%);维氏硬度由21 GPa(0v.%)逐渐降低至15.3 GPa(40v.%);同时,常温热导率由9.3 W/(m K)(20v.%)逐渐降低到7.6 W/(m K)(35v.%);热膨胀系数无明显变化。此外,200 ℃下AZM30(MgAl2O4体积比30v.%)和ZTA复相陶瓷电阻率分别为6.6 × 10^8 Ω cm和3.3 × 10^9 Ω cm。 展开更多
关键词 MGAL2O4 Al2O3/ZrO2 SPS 显微结构 物理性能
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光强可调的变温荧光测试系统在准二维钙钛矿中的应用
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作者 张博 郭秀文 +4 位作者 崔明焕 孙铭泽 李高强 周静 秦朝朝(导师) 《量子电子学报》 CAS CSCD 北大核心 2021年第4期420-427,共8页
激子性质对准二维钙钛矿材料的发光机理具有决定性影响。测量激子-声子耦合强度和激子结合能是研究准二维钙钛矿材料激子特性的有力手段,可以为揭示其内部光发射机制和进一步提高荧光量子产率提供关键的科学依据。将变光强荧光测试系统... 激子性质对准二维钙钛矿材料的发光机理具有决定性影响。测量激子-声子耦合强度和激子结合能是研究准二维钙钛矿材料激子特性的有力手段,可以为揭示其内部光发射机制和进一步提高荧光量子产率提供关键的科学依据。将变光强荧光测试系统和液氮恒温装置相结合,利用LABVIEW程序进行系统控制,搭建了一套光强可调的变温荧光测试系统,并以准二维钙钛矿薄膜样品为研究对象,开展了对准二维钙钛矿的激子及其发光性质的研究。研究结果表明:随着准二维钙钛矿材料值的增加,激子-纵向光学声子耦合强度和激子结合能均逐渐降低。此外,利用该测试系统进行了室温下变光强荧光测量,探究了准二维钙钛矿薄膜的光学增益,得到其放大的自发辐射阈值为3.2 μJ/cm^(2)。 展开更多
关键词 光谱学 激子性质 变温荧光 准二维钙钛矿 放大的自发辐射
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4-8 A Study of Precipitation in Martensite Steels Induced by Fe-Ion Irradiation at 300℃
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作者 Fang Xuesong Shen Tielong +17 位作者 Wang Zhiguang Wei Kongfang Zhu Yabin Sun Jianrong Yao Cunfeng Li Bingsheng Pang Lilong cui minghuan Chang Hailong Wang dong He Wenhao Han Yi Zhao Sixiang Tai Pengfei Liu Chao Ma Zhiwei Gao Xing Gao Ning 《IMP & HIRFL Annual Report》 2016年第1期118-119,共2页
The martensite steels are accepted material used in nuclear power plant.In this study,self-ion irradiation was used to simulate the damage caused by fast neutrons in two kinds of martensite steels,SIMP and T91,under t... The martensite steels are accepted material used in nuclear power plant.In this study,self-ion irradiation was used to simulate the damage caused by fast neutrons in two kinds of martensite steels,SIMP and T91,under the temperature of 300℃.The contrast experiment on the steel samples was carried out with 352.8 MeV Fe-ions.S parameter is a statistical conclusion about vacancy damage caused by irradiation,and it is positively related to the density of vacancy defects Figs.1 and 2 show the change of the S parameter with the irradiation dose.Whereas Figs.3 and 4 show the different S parameters for two kind of steels. 展开更多
关键词 simulate FAST SIMP was T91 MEV is
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3 - 2 Effects of He2+ Ions Irradiation on Structural Properties for MAX Phase Ti3AIC2
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作者 Sun Jianrong Song Peng +14 位作者 Wang Zhiguang Li Yuanfei cui minghuan Shen Tielong Zhu Yabin Pang Lilong Zhang Hongpeng Chang Hailong Sheng Yanbin Luo Peng Yao Cunfeng Wei Kongfang Wang Ji Zhu Huiping Wang Dong 《IMP & HIRFL Annual Report》 2013年第1期62-63,共2页
关键词 英语 阅读 理解 物理研究
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3 - 9 Study of Irradiation-induced Hardening in T91 Steel Irradiated with Helium
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作者 Wang Ji Wang Zhiguang +13 位作者 Wei Kongfang Yao Cunfeng Li Bingsheng Shun Jianrong cui minghuan Luo Peng Chang Hailong Zhu Yabing Pang Lilong Shen Yanbing Zhang Hongpeng Zhu Huiping Wang Dong Du Yangyang 《IMP & HIRFL Annual Report》 2013年第1期72-73,共2页
关键词 英语 阅读 理解 物理研究
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3 - 10 Helium Bubbles Distribution in Coarsening Grain Ferritic/Martensitic Steel and Nano-size Grain Steel
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作者 Wang Ji Wang Zhiguang +13 位作者 Wei Kongfang Yao Cunfeng Li Bingsheng Shun Jianrong cui minghuan Luo Peng Chang Hailong Zhu Yabing Pang Lilong Shen Yanbing Zhang Hongpeng Zhu Huiping Wang Dong Du Yangyang 《IMP & HIRFL Annual Report》 2013年第1期73-74,共2页
关键词 英语 阅读 理解 物理研究
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3 - 3 A Brief Research Related to Fluidized Metals Particles, Particularly as Spallation Target Materials
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作者 Sun Jianrong Wang Zhiguang +6 位作者 Pang Lilong cui minghuan Du Yangyang Zhu Yabin Zhang Xueying Wang Fei Li long 《IMP & HIRFL Annual Report》 2013年第1期63-65,共3页
关键词 英语 阅读 理解 物理研究
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3 - 7 Temperature Dependent Defects Evolution in Tungsten Induced by 200 keV He-ions
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作者 cui minghuan Wang Zhiguang +7 位作者 Pang Lilong Shen Tielong Yao Cunfeng Li Bingsheng Sun Jianrong Zhu Yabin Li Yuanfei Sheng Yanbin 《IMP & HIRFL Annual Report》 2013年第1期69-70,共2页
关键词 英语 阅读 理解 物理研究
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3 - 4 Microstructural and Nano-hardness Changes in He Irradiated 6H-SiC
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作者 Li Bingsheng Wang Zhiguang +4 位作者 Du Yangyang Sun Jianrong cui minghuan Wei Kongfang Yao Cunfeng 《IMP & HIRFL Annual Report》 2013年第1期65-66,共2页
关键词 英语 阅读 理解 物理研究
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3 - 8 Temperature Effect of Irradiation Damage of T91 and SIMP Steels under Self-ion Irradiation
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作者 Zhu Huiping Wang Zhiguang +14 位作者 Li Bingsheng Yao Cunfeng Sun Jianrong Wei Kongfang Shen Tielong Pang Lilong Zhu Yabin cui minghuan Li Yuanfei Wang Ji Song Peng Wang Dong Chang Hailong Sheng Yanbin Zhang Hongpeng 《IMP & HIRFL Annual Report》 2013年第1期70-72,共3页
关键词 英语 阅读 理解 物理研究
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3 - 11 Helium Implantation Induced Damage in NHS Steel Investigated by Slow-positron Annihilation Spectroscopy
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作者 Li Yuanfei Wang Zhiguang +16 位作者 Shen Tielong Gao Xing Gao Ning Yao Cunfeng Wei Kongfang Sun Jianrong Li Bingsheng Zhu Yabin Pang Lilong cui minghuan Chang Hailong Wang Ji Zhu Huiping Wang Dong Song Peng Sheng Yanbin Zhang Hongpeng 《IMP & HIRFL Annual Report》 2013年第1期74-76,共3页
关键词 英语 阅读 理解 物理研究
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3-6 Molecular Dynamics Simulation of Displacement Cascade under Strain Field in Tungsten
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作者 Wang Dong Gao Ning +3 位作者 Wang Zhiguang Gao Xing He Wenhao cui minghuan 《IMP & HIRFL Annual Report》 2015年第1期96-98,共3页
Due to its unique properties, e:g: high melting temperature, high thermal conductivity and low sputtering erosion, tungsten has been selected as one of the most promising candidate materials for the divertor in ITER a... Due to its unique properties, e:g: high melting temperature, high thermal conductivity and low sputtering erosion, tungsten has been selected as one of the most promising candidate materials for the divertor in ITER and future fusion devices. In the extreme environment of fusion reactors, tungsten will not only be exposed to high energy particles such as hydrogen, helium and neutrons, which lead to heavy radiation damages, but also suffer from the combined high thermal fluxes and high mechanical stresses. 展开更多
关键词 MOLECULAR DYNAMICS SIMULATION
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3-7 Molecular Dynamics Simulation of Threshold Displacement Energy under Strain Field in Tungsten
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作者 Wang Dong Gao Ning +3 位作者 Wang Zhiguang Gao Xing He Wenhao cui minghuan 《IMP & HIRFL Annual Report》 2015年第1期98-99,共2页
Tungsten has been selected as one of the most promising candidate materials for the divertor in the International Thermonuclear Experimental Reactor (ITER) and future fusion devices due to its unique properties, e:g: ... Tungsten has been selected as one of the most promising candidate materials for the divertor in the International Thermonuclear Experimental Reactor (ITER) and future fusion devices due to its unique properties, e:g: high melting temperature, high thermal conductivity and low sputtering erosion. In fusion reactors, tungsten will be exposed to high-energy particles, which result in microstructure and property changes[1], affecting the lifetime of divertor and reactor. 展开更多
关键词 STRAIN FIELD TUNGSTEN
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3-3 A Study on Irradiation Damage of T91 and SIMP Steels under Self-Ion Irradiation by Slow-positron Annihilation Spectroscopy
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作者 Fang Xuesong Shen Tielong +16 位作者 Wang Zhiguang Wei Kongfang Gao Xing Gao Ning Sun Jianrong Li Bingsheng Zhu Yabin Pang Lilong cui minghuan Chang Hailong Wang Dong He Wenhao Han Yi Zhao Sixiang Tai Pengfei Liu Chao Ma Zhiwei 《IMP & HIRFL Annual Report》 2015年第1期92-93,共2页
Due to its good physical properties such as low coefficient, high thermal conductivity, high resistance of irradiation swelling, and good geometric stability, the F/M steel T91 and SIMP are two kinds of accepted mater... Due to its good physical properties such as low coefficient, high thermal conductivity, high resistance of irradiation swelling, and good geometric stability, the F/M steel T91 and SIMP are two kinds of accepted material used in nuclear reactor. So it’s necessary for us to make some research on them. 展开更多
关键词 Slow-positron ANNIHILATION SPECTROSCOPY
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3-9 Mechanical Properties Studies on High-energy Kr-ion Irradiated Corrosion Layer Fe3O4
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作者 Sun Jianrong Song Peng +8 位作者 Zhang Hongpeng Chang Hailong Yao Cunfeng Pang Lilong Zhu Yabin cui minghuan Wang Ji Zhu Huiping Wang Zhiguang 《IMP & HIRFL Annual Report》 2014年第1期97-98,共2页
The RAFM (Reduced Activation Ferritic/Martensitic) steel is considered as one of the promising candidatestructural materials for LFRs (Lead alloy-cooled Fast Reactors) and ADS (Accelerator Driven Sub-critical system),... The RAFM (Reduced Activation Ferritic/Martensitic) steel is considered as one of the promising candidatestructural materials for LFRs (Lead alloy-cooled Fast Reactors) and ADS (Accelerator Driven Sub-critical system),and its compatibility with liquid metal and radiation-resistant properties have been extensively studied because ofthe requirements of reliability and safety of the blanket[1]. A number of corrosion experiments of RAFMs (Eurofer97, T91 and 316L, etc.) in liquid LiPb alloy have been investigated, and the corrosion results show that these Febasedsteels suffered more serious corrosion attack from 480 to 550 ?C, and the corrosion layer is made of the oxidelayer (Fe3O4 and CrxFe3?xO4) at steels' surface. Generally speaking, during the stage degeneration of material, theformation of corrosion layer is one of the important features of the process[2]. Cracking, blistering, embrittlementand other changes in materials may be induced by corrosion layers, and the corrosion layers have independentcompositions, structures and radiation-resistant properties with distinguished from the alloy matrix. In a word, inorder to further clarify the applicability of Fe-based structural materials in nuclear facilities, we should study notonly the RAFM steel itself but also its corrosion layer (Fe3O4, mainly). So we report on modifications of mechanicalproperties of Fe3O4 corrosion layer irradiated with high-energy ion. 展开更多
关键词 HIGH-ENERGY Kr-ion IRRADIATED
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3-10 Swift Heavy Ion Induced Modification of Fe/Cu Multilayers
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作者 Wei Kongfang Li Bingsheng +14 位作者 Zhu Yabin Zhu Huiping Gao Ning Shen Tielong Yao Cunfeng Sun Jianrong Pang Lilong cui minghuan Chang Hailong Wang Ji Wang Dong Sheng Yanbin Zhang Hongpeng Wang Zhiguang Gao Xing 《IMP & HIRFL Annual Report》 2014年第1期98-99,共2页
When swift heavy ion (SHI) passes through metallic multilayers, the kinetic energy of the ion is mainly depositedto target electron subsystem (electronic energy loss, Se) by the inelastic collisions involving excitati... When swift heavy ion (SHI) passes through metallic multilayers, the kinetic energy of the ion is mainly depositedto target electron subsystem (electronic energy loss, Se) by the inelastic collisions involving excitation and ionizationof the target atoms, which could induce atomic displacements and modify the interfacial structure [1?6]. Therefore,through the study of the process of the interfacial atoms diffusion induced by SHI irradiation, we could explore thepossible mechanism of atomic displacement induced by swift heavy ion irradiation. 展开更多
关键词 ION INDUCED MODIFICATION
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3-8 Thermal Desorption and Surface Modification Induced by Helium Implantation in Tungsten
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作者 cui minghuan Wang Zhiguang +8 位作者 Yao Cunfeng Pang Lilong Shen Tielong Sun Jianrong Zhu Yabin Sheng Yanbin Zhu Huiping Wang Ji Zhang Hongpeng 《IMP & HIRFL Annual Report》 2014年第1期96-97,共2页
Plasma-facing materials (PFMs) for a fusion reactor suffer hydrogen/helium plasma bombardment, neutronirradiation and high temperature, etc. Tungsten is a promising candidate PFM due to its low sputtering yield forthe... Plasma-facing materials (PFMs) for a fusion reactor suffer hydrogen/helium plasma bombardment, neutronirradiation and high temperature, etc. Tungsten is a promising candidate PFM due to its low sputtering yield forthe light elements, high thermal conductivity, high mechanical strength, and high melting point. Helium couldbe introduced by helium bombardment and neutron irradiation and trapped in tungsten at different sinks. It ispossible that the trapped helium atoms re-emit to the core plasma due to thermal desorption which affects thesafety. In this work, the thermal desorption behavior of helium implanted into tungsten at different temperatureswas investigated. 展开更多
关键词 Surface MODIFICATION INDUCED
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