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SERS技术结合PLS模型定量检测牛奶中二元污染物 被引量:1
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作者 崔月娴 朱利 《激光杂志》 CAS 北大核心 2022年第8期49-54,共6页
为实现牛奶等复杂体系下多元污染物的快速定量检测,提出了表面增强拉曼散射(SERS)光谱技术结合偏最小二乘(PLS)回归模型的定量分析方案。SERS的高灵敏性和丰富的指纹信息有利于多元分析物的检测和识别,但多元分析物在金属纳米颗粒上的... 为实现牛奶等复杂体系下多元污染物的快速定量检测,提出了表面增强拉曼散射(SERS)光谱技术结合偏最小二乘(PLS)回归模型的定量分析方案。SERS的高灵敏性和丰富的指纹信息有利于多元分析物的检测和识别,但多元分析物在金属纳米颗粒上的竞争吸附导致的光谱强度改变使准确定量成为困难。以存在竞争吸附条件下获得的多组混合光谱数据作为训练集建立PLS模型,极大地提高了真实体系下多元分析物浓度的预测准确度。基于上述方法,进行了牛奶中噻菌灵(TBZ)和环丙沙星(CIP)残留的检测,预测结果中TBZ和CIP浓度的相关系数(R^(2))分别为0.9722和0.9719,测试集均方误差(RMSEP)分别为4.0592 mg/L和0.4032 mg/L。实验结果表明,该方法在复杂体系多元检测应用中具有可行性。结合便携式拉曼光谱仪,该方案有望在食品安全等领域现场快速检测中得到实际应用。 展开更多
关键词 表面增强拉曼散射 偏最小二乘法 双组分定量 竞争吸附 食品安全
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OBSERVATION OF DISLOCATION CONFIGURATIONS IN AGED & DEFORMED NiAl ALLOY AFTER HOT ISOSTATIC PRESSING (HIP)
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作者 cui yuexian Dong Shangli +3 位作者 Liu Bo Li Daoming Yang Dezhuang(Schwa of Materials Sccience and Engineering, Harbin instituteOf Technology, Harbin, China, 150001 )Bi Geping Wang Qin(Central iron and Steel Research institute, Beijing China, 100081 ) 《Chinese Journal of Aeronautics》 SCIE EI CAS CSCD 1996年第4期278-283,共6页
OBSERVATION OF DISLOCATION CONFIGURATIONS IN AGED & DEFORMED NiAl ALLOY AFTER HOT ISOSTATIC PRESSING (HIP)Cu... OBSERVATION OF DISLOCATION CONFIGURATIONS IN AGED & DEFORMED NiAl ALLOY AFTER HOT ISOSTATIC PRESSING (HIP)CuiYuexian;DongShan... 展开更多
关键词 NIAL HOT isostatic press compressive deformation dislocations(materials) aging (metallurgy)
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IN-SITU OBSERVATION OF S'PHASE IN Al-Li BASE ALLOY USING TEM SERIAL ROTATION TECHNIQUE
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作者 Zhen Liang cui yuexian +1 位作者 Sun Dongli Yang Dezhuang 《Transactions of Nonferrous Metals Society of China》 SCIE EI CAS CSCD 1992年第2期82-87,共6页
An in situ observation of the s'phase morphology and its orientation with the matrix in an Al-Li base alloy was carried out by means of double-tilt rotating around[220]a in a transmission electron microscope(TEM).... An in situ observation of the s'phase morphology and its orientation with the matrix in an Al-Li base alloy was carried out by means of double-tilt rotating around[220]a in a transmission electron microscope(TEM).The results show that the s'phase precipitates in the form of bundles.The units of s'phase are lath-shaped,grow along the<100>,orientation,and have habit planes of{210}*.Many units of the s'phase grow in the same orientation and get together to form a plate-shaped bundle of s'phase laths which lie on the{110}a planes. 展开更多
关键词 Al-Li base alloy s'phase in-situ observation TEM
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